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Showing papers by "Universiti Teknologi Malaysia published in 2011"


Journal ArticleDOI
TL;DR: The role of processing conditions including final liquefaction temperature, residence times, rate of biomass heating, size of biomass particles, type of solvent media and hydrogen donor solvents is discussed in this paper.
Abstract: Hydrothermal liquefaction is a technique for obtaining clean biofuel from biomass in the presence of a solvent at moderate to high temperature (250–550 °C) and pressure (5–25 MPa). Hydrothermal decomposition of biomass leads to the formation of various compounds depending upon operating parameters. The role of processing conditions including final liquefaction temperature, residence times, rate of biomass heating, size of biomass particles, type of solvent media and hydrogen donor solvents is important for the bio-oil yield and quality of the product. The effect of these parameters on the yield and composition of the liquid products is reviewed in the paper. A brief description about the decomposition mechanism is also included to highlight the product types during hydrothermal liquefaction.

840 citations


Journal ArticleDOI
TL;DR: The main contribution of this work is the simplification of the current equation, in which only four parameters are required, compared to six or more in the previously developed two-diode models.

571 citations


Journal ArticleDOI
TL;DR: In this paper, a review of the recent efforts to tackle the underlying problems and the effects of various kinds of modification that would eventually heighten the performance of membrane applications in gas separations were discussed.

538 citations


Journal ArticleDOI
TL;DR: In this article, a thermodynamic equilibrium analysis on the multi-reaction system for carbon dioxide reforming of methane in view of carbon formation was performed with Aspen plus based on direct minimization of Gibbs free energy method.

455 citations


Journal ArticleDOI
TL;DR: In this article, the potential of renewable and sustain- able energy resources in the country, the government must pay more attention on how to utilize it and the public should take a more proactive step to promote and use renewable energy in order to achieve the secure and environmentally sustainable energy resources.
Abstract: a b s t r a c t The global energy consumption is likely to grow faster than the population growth. The fuel consumption was growing from 6630 million tons of oil equivalents (Mtoe) in 1980 to 11,163 Mtoe in 2009. This pro- jected consumption will increase 1.5% per year until 2030 and reach 16,900 Mtoe and the main drivers of this growth are mostly developing countries in Asia. Indonesia is one of the developing countries and energy supply is an important factor for all-around development. The country's energy consumption still depends on non-renewable energy such as crude oil, coal and natural gas as sources of energy. Utiliza- tion of fossil fuel continuously contributes to huge amount of greenhouse gases emission that leads to climate change. Facing such an unfavorable situation, the government of Indonesia prioritizes on energy supply securities by diversification of energy resources. The energy mixes in Indonesia based on five main resources; these are crude oil, natural gas, coal, hydropower, and renewable energy. Although the country encourages utilizing renewable energy, the contribution is only around 3%. Considering natural condition and geography, this country is blessed with great potential of renewable energy such as solar energy, wind energy, micro hydro and biomass energy. Noting the potential of renewable and sustain- able energy resources in the country, the government must pay more attention on how to utilize it. Many efforts have been done to promote renewable energy such as to create energy policy and regulations, yet it still did not give any satisfactory result. Government, non-government agencies and the public should take a more proactive step to promote and use renewable energy in order to achieve the secure and environmentally sustainable energy resources.

449 citations


Journal ArticleDOI
TL;DR: A review of the literature on power and supply sector developments and analyzes the role of modeling and optimization in this sector as well as the future prospective of optimization modeling as a tool for sustainable energy systems is presented in this paper.
Abstract: Electricity is conceivably the most multipurpose energy carrier in modern global economy, and therefore primarily linked to human and economic development. Energy sector reform is critical to sustainable energy development and includes reviewing and reforming subsidies, establishing credible regulatory frameworks, developing policy environments through regulatory interventions, and creating market-based approaches. Energy security has recently become an important policy driver and privatization of the electricity sector has secured energy supply and provided cheaper energy services in some countries in the short term, but has led to contrary effects elsewhere due to increasing competition, resulting in deferred investments in plant and infrastructure due to longer-term uncertainties. On the other hand global dependence on fossil fuels has led to the release of over 1100 GtCO2 into the atmosphere since the mid-19th century. Currently, energy-related GHG emissions, mainly from fossil fuel combustion for heat supply, electricity generation and transport, account for around 70% of total emissions including carbon dioxide, methane and some traces of nitrous oxide. This multitude of aspects play a role in societal debate in comparing electricity generating and supply options, such as cost, GHG emissions, radiological and toxicological exposure, occupational health and safety, employment, domestic energy security, and social impressions. Energy systems engineering provides a methodological scientific framework to arrive at realistic integrated solutions to complex energy problems, by adopting a holistic, systems-based approach, especially at decision making and planning stage. Modeling and optimization found widespread applications in the study of physical and chemical systems, production planning and scheduling systems, location and transportation problems, resource allocation in financial systems, and engineering design. This article reviews the literature on power and supply sector developments and analyzes the role of modeling and optimization in this sector as well as the future prospective of optimization modeling as a tool for sustainable energy systems.

361 citations


Journal ArticleDOI
TL;DR: A new two-diode model is utilized to represent the PV cell in a comprehensive MATLAB Simulink simulator for photovoltaic (PV) system that supports a large array combination that can be interfaced to MPPT algorithms and power electronic converters.

353 citations


Journal ArticleDOI
TL;DR: An improved modeling approach using differential evolution (DE) method, which enables the computation of model parameters at any irradiance and temperature point using only the information provided by the manufacturer’s data sheet is proposed.

348 citations


Journal ArticleDOI
TL;DR: In this article, the authors investigated the relation between fast pyrolysis of wheat straw at different reactor temperatures and the short-term degradability of biochar in soil, and found that 90% of the total biochar-C loss occurred within the first 20 days of the experiment, emphasizing the importance of knowing the biochar labile fraction when evaluating a specific biochars C sequestration potential.
Abstract: Production of bio-oil, gas and biochar from pyrolysis of biomass is considered a promising technology for combined production of bioenergy and recalcitrant carbon (C) suitable for sequestration in soil. Using a fast pyrolysis centrifuge reactor (PCR) the present study investigated the relation between fast pyrolysis of wheat straw at different reactor temperatures and the short-term degradability of biochar in soil. After 115 days incubation 3–12% of the added biochar-C had been emitted as CO2. On average, 90% of the total biochar-C loss occurred within the first 20 days of the experiment, emphasizing the importance of knowing the biochar labile fraction when evaluating a specific biochars C sequestration potential. The pyrolysis temperature influenced the outputs of biochar, bio-oil and syngas significantly, as well as the stability of the biochar produced. Contrary to slow pyrolysis a fast pyrolysis process may result in incomplete conversion of biomass due to limitations to heat transfer and kinetics. In our case chemical analysis of the biochars revealed unconverted cellulosic and hemicellulosic fractions, which in turn were found to be proportional with the short-term biochar degradation in soil. As these labile carbohydrates are rapidly mineralized, their presence lowers the biochar-C sequestration potential. By raising the pyrolysis temperature, biochar with none or low contents of these fractions can be produced, but this will be on the expense of the biochar quantity. The yield of CO2 neutral bio-oil is the other factor to optimize when adjusting the pyrolysis temperature settings to give the overall greatest climate change mitigation effect.

318 citations


Journal ArticleDOI
TL;DR: In this paper, the effect of different parameters such as temperature (40, 50 and 60 °C), pressure (100, 200 and 300 bar) and dynamic extraction time (30, 60 and 90 min) on the supercritical carbon dioxide (SC-CO2) extraction of spearmint flavonoids was investigated using full factorial arrangement in a completely randomized design (CRD).

311 citations


Journal ArticleDOI
TL;DR: In this paper, the authors developed a set of measures for evaluating the performance of the automobile green supply chain, including customer perspective, traditional supply chain cost, and management commitment in terms of both importance and applicability.
Abstract: The main purpose of this study was to develop a set of measures for evaluating the performance of the automobile green supply chain This study reviewed various literatures on green supply chain performance measurement, environmental management, traditional supply chain performance measurement, and automobile supply chain management In order to comprehensively and effectively establish the relevant measures, a suitable framework which considered the automobile green supply chain as a two-in-one chain was adopted This two-in-one chain comprised a forward and backward chain for the automobile industry Consequently, 10 measures with 49 metrics and 6 measures with 23 metrics were identified and developed for the forward and backward chains, respectively Sequel to the development of these measures, a survey was conducted using a four-page questionnaire distributed to experts (including academics and practitioners) to establish their importance and applicability The findings of this study suggested that the importance and applicability of all the developed measures have been substantiated For the forward chain, the most crucial measure was customer perspective while the most applicable one was traditional supply chain cost The reverse chain measures were topped by management commitment in terms of both importance and applicability This study contributed to the advancement of knowledge by pioneering the development of a set of holistic measures for evaluating the performance of the automobile green supply chain The study was wrapped up with the proposition of directions for further studies

Journal ArticleDOI
TL;DR: In this article, issues and challenges in biomass utilization for energy in Pakistan in context of sustainable development are discussed. Barriers are examined over the whole biomass energy spectrum and policy issue and institutional roles and responsibilities are discussed; however, there is a need to develop modern bio-energy technologies since renewable resources may serve to supplement the long-term energy needs of Pakistan to a significant level.
Abstract: Diversification of fuel sources is imperative to address the energy security, climate change, and sustainable development issues; therefore, it is essential to address the energy crisis through the extensive utilization of abundant renewable energy resources, such as biomass energy, solar energy, wind energy and geothermal energy. Improving energy services for poor households in developing countries remains one of the most pressing challenges facing the development community. Earlier studies suggest in South Asia the households are likely to follow the energy ladder comprising fuels like dung, crop residue, firewood, kerosene, gobar gas, LPG, and electricity for cooking purposes. Evidence suggests that while it is possible to observe such transition in urban and semi-urban areas, the change is very slow in rural areas. In rural Pakistan, the access to commercial energy resources is limited, the majority of the households still heavily rely on traditional methods of using wood, animal waste and crop waste for domestic fuel needs. Efficiencies of use are very low and most of the potential is wasted because of non-scientific conventional technologies. Consequently there is an obligatory need to develop modern bio-energy technologies since renewable resources may serve to supplement the long-term energy needs of Pakistan to a significant level. Though the bio-resource base of Pakistan is substantial, its contribution to useful energy is low. In this paper we called attention to issues and challenges in biomass utilization for energy in Pakistan in context of sustainable development. This paper has identified areas in Pakistan where there is considerable scope to modernize biomass energy production delivery systems to provide varied energy carriers such as electricity, industrial and domestic fuel and gases. Barriers are examined over the whole biomass energy spectrum and policy issue and institutional roles and responsibilities are discussed.

Journal ArticleDOI
TL;DR: Rapid heating and yield of microwave pyrolysis products such as bio-oil, char, and gas was found to depend on the ratio of biomass to microwave absorber.

Journal ArticleDOI
TL;DR: In this article, polysulfone (PSF) hollow fiber membranes with enhanced performance for humic acid removal were prepared from a dope solution containing PSF/DMAc/PVP/TiO2.

Journal ArticleDOI
TL;DR: The main contribution of this work is the utilization of the two-diode model to represent the PV cell, requiring only four parameters and known to have better accuracy at low irradiance level, allowing for more accurate prediction of PV system performance during partial shading condition.

Journal ArticleDOI
TL;DR: This paper reviews the application of non dominated sorting genetic algorithm II (NSGA-II), classified as one of MoGA techniques, for optimizing process parameters in various machining operations.

Journal ArticleDOI
TL;DR: In this paper, the effect of pore-forming hydrophilic additives on the porous asymmetric polyvinylideneflouride (PVDF) ultrafiltration membrane morphology and transport properties for refinery produced wastewater treatment was investigated.

Journal ArticleDOI
TL;DR: In this article, a polyethersulfone-silver composite membrane was fabricated via a simple phase inversion method by using silver nitrate (AgNO3) as an antibacterial agent and polyvinylpyrollidone (PVP) of molecular weight 10,000, 40,000 and 360,000 Da as dispersant in the dope formulation.

Journal ArticleDOI
TL;DR: In this article, the authors discuss the key policies for renewable energy programs, funding, schemes, and incentives that has been introduced by the government of Malaysia to develop and promote the utilisation of RE.
Abstract: Effective policies and incentive on renewable energy (RE) is critical to promote low carbon economy and society in the future. RE was first introduced in the country's energy mix through the Fifth-Fuel Policy which was formulated under the Eighth Malaysia Plan (2001–2005) to reduce dependency on fossil fuel and to address the rising global concern on climate change. This paper addresses the RE progress and achievement over the past 10 years, and discusses the key policies for RE programmes, funding, schemes, and incentives that has been introduced by the government of Malaysia to develop and promote the utilisation of RE. The recent RE mechanisms under the Tenth Malaysia Plan (2011–2015) will also be highlighted.

Journal ArticleDOI
TL;DR: In this paper, a MATLAB Simulink simulator for photovoltaic (PV) systems is proposed, which uses a two-diode model to represent a PV cell.
Abstract: This paper proposes a MATLAB Simulink simulator for photovoltaic (PV) systems. The main contribution of this work is the utilization of a two-diode model to represent a PV cell. This model is known to have better accuracy at low irradiance levels which allows for a more accurate prediction of PV system performance. To reduce computational time, the input parameters are reduced to four and the values of Rp and Rs are estimated by an efficient iteration method. Furthermore, all of the inputs to the simulator are information available on a standard PV module datasheet. The simulator supports large array simulations that can be interfaced with MPPT algorithms and power electronic converters. The accuracy of the simulator is verified by applying the model to five PV modules of different types (multi-crystalline, mono-crystalline, and thin-film) from various manufacturers. It is envisaged that the proposed work can be very useful for PV professionals who require a simple, fast and accurate PV simulator to design their systems.

Journal ArticleDOI
TL;DR: In this article, the authors investigated the relationship of methanol to oil molar ratio, catalyst loading, reaction time, and reaction temperature on methyl ester yield and free fatty acid conversion.
Abstract: Heterogeneous transesterification of waste cooking palm oil (WCPO) to biodiesel over Sr/ZrO2 catalyst and the optimization of the process have been investigated. Response surface methodology (RSM) was employed to study the relationships of methanol to oil molar ratio, catalyst loading, reaction time, and reaction temperature on methyl ester yield and free fatty acid conversion. The experiments were designed using central composite by applying 24 full factorial designs with two centre points. Transesterification of WCPO produced 79.7% maximum methyl ester yield at the optimum methanol to oil molar ratio = 29:1, catalyst loading = 2.7 wt%, reaction time = 87 min and reaction temperature = 115.5 °C.

Journal ArticleDOI
TL;DR: Critical evaluation of the parameters extraction of two diode PV model using three EA methods, namely Genetic Algorithm, Particle Swarm Optimization and Differential Evolution, is presented.

Journal ArticleDOI
TL;DR: Five factors in the form of professionalism, reliability, hospitality, tangibles, and commitment were uncovered and all the items of perception were perceived as significantly negative as compared to expectations.
Abstract: Purpose – The purpose of this paper is to assess the service quality perceptions and expectations of international postgraduate students studying in selected Malaysian universities.Design/methodology/approach – A gap analysis based on a modified SERVQUAL instrument was used on 522 international postgraduate students who were selected based on stratified sampling of the top five public universities. The analysis started with descriptive analysis followed by factor and reliability analyses. Single mean t‐tests were conducted to assess the significance of the gap analysis based on three methods: item‐by‐item analysis; construct‐by‐construct analysis; and computation of a single measure of service quality.Findings – Five factors in the form of professionalism, reliability, hospitality, tangibles, and commitment were uncovered. The single mean t‐tests for the three methods of gap analysis indicated that all the items of perception were perceived as significantly negative as compared to expectations.Practical i...

Journal ArticleDOI
TL;DR: In this paper, the performance of Principal Component Analysis, band ratio and minimum noise fraction transformation has been evaluated for the visible and near infrared (VNIR) and, shortwave infrared (SWIR) subsystems of ASTER data.

Journal ArticleDOI
TL;DR: Although traditionally aqueous extracts are used, it is determined that ethanol extracts usually achieved better activity in the assays, and exhibited a strong correlation between antioxidant activity and the total phenol contents.
Abstract: Aqueous and ethanol extracts of different traditional Malaysian plants (Polygonum minus, Andrographis paniculata, Curcuma xanthorrhiza, Momordica charantia and Strobilanthes crispus) were evaluated for their antioxidant properties, total phenolic content and cytotoxic activity Antioxidant activity was evaluated by using 1,1-diphenyl-1-picrylhydrazyl (DPPH) and ferric reducing antioxidant power (FRAP) assays The results showed that ethanol extracts contain high antioxidant activities compared to aqueous extracts The findings exhibited a strong correlation between antioxidant activity and the total phenol contents In addition, all the plant extracts showed non-toxic effects against a normal human lung fibroblast cell line (Hs888Lu) Although traditionally aqueous extracts are used, we determined that ethanol extracts usually achieved better activity in the assays

Journal ArticleDOI
TL;DR: In this article, a bio-optical dataset collected during the 1998-2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag440).
Abstract: A bio-optical dataset collected during the 1998–2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag440). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for TChl (regionally tuned Tassan’s Chl-a algorithm) in case-1 waters (TChl2i in case-2 waters), TTSM (regionally tuned Tassan’s TSM algorithm), and Tag440 or Cag440 (regionally tuned Tassan’s or Carder’s ag440 algorithm) were able to retrieve Chl-a, TSM, and ag440 with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, TChl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. TChl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified TChl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw555) > 2 mW cm−2 μm−1 sr−1 (TChl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from TChl2s (for case-2 waters) to MOCChl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag440 using SeaWiFS Rrs, we recommend empirical algorithms for TTSM (pre-SeaWiFS-modified form) and MTag440 or MCag440 (SeaWiFS Rrs-modified forms of Tag440 or Cag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.

Journal ArticleDOI
TL;DR: Physical adsorption and photocatalytic reduction of Cr(VI) in magnetic separable beads and desorption experiments by elution of the loaded gels with sodium hydroxide indicated that the magnetic photocatalyst beads could be reused without significant losses of their initial properties even after 3 adsorptive-desorption cycles.

Proceedings Article
01 Mar 2011
TL;DR: In this paper, a review of the existing web caching and prefetching approaches is presented and some studies that take into consideration the impact of integrating both Web caching and web pre-fetching together.
Abstract: Web caching and prefetching are the most popular techniques that play a key role in improving the Web performance by keeping web objects that are likely to be visited in the near future closer to the client. Web caching can work independently or integrated with the web prefetching. The Web caching and prefetching can complement each other since the web caching exploits the temporal locality for predicting revisiting requested objects, while the web prefetching utilizes the spatial locality for predicting next related web objects of the requested Web objects. This paper reviews principles and some existing web caching and prefetching approaches. The conventional and intelligent web caching techniques are investigated and discussed. Moreover, Web prefetching techniques are summarized and classified with comparison limitations of these approaches. This paper also presents and discusses some studies that take into consideration impact of integrating both web caching and web prefetching together.

Proceedings ArticleDOI
29 Dec 2011
TL;DR: A set of initial key performance indicators (KPIs) for sustainable manufacturing evaluation believed to be appropriate to automotive companies are proposed, consisting of three factors divided into nine dimensions and a total of 41 sub-dimensions.
Abstract: The automotive industry is regarded as one of the most important and strategic industry in manufacturing sector. It is the largest manufacturing enterprise in the world and one of the most resource intensive industries of all major industrial system. However, its products and processes are a significant source of environmental impact. Thus, there is a need to evaluate sustainable manufacturing performance in this industry. This paper proposes a set of initial key performance indicators (KPIs) for sustainable manufacturing evaluation believed to be appropriate to automotive companies, consisting of three factors divided into nine dimensions and a total of 41 sub-dimensions. A survey will be conducted to confirm the adaptability of the initial KPIs with the industry practices. Future research will focus on developing an evaluation tool to assess sustainable manufacturing performance in automotive companies.

Journal ArticleDOI
TL;DR: In this paper, the catalysts were prepared via wet impregnation of alkaline nitrate salts supported on zirconia, and physicochemical characteristics of the catalyst were analyzed by BET surface area, XRD, FESEM and CO2-NH3-TPD.