University of Crete

About: University of Crete is a education organization based out in Rethymno, Greece. It is known for research contribution in the topics: Population & Galaxy. The organization has 8681 authors who have published 21684 publications receiving 709078 citations. The organization is also known as: Panepistimio Kritis.

The mitochondrial genome of the mediterranean fruit fly, Ceratitis capitata.

Abstract: The complete sequence of the mitochondrial genome of Ceratitis capitata has been determined. The circular genome is 15 980 bp long and contains a standard gene complement, i.e. the large and small ribosomal RNA subunits, twenty-two transfer RNA (tRNA) genes and thirteen genes encoding mitochondrial proteins. When comparing the sequence to fragments previously sequenced from other isolates it becomes apparent that interstrain polymorphisms are not rare. These differences are potentially useful for the development of diagnostic tools for population analysis applications, such as determining the source of recent introductions. Moreover, they could help obtain a solution to the long-lasting controversy on the possible eradication of the Medfly from certain locations.

Holographic Models for QCD in the Veneziano Limit

Abstract: We construct a class of bottom-up holographic models with physics comparable to the one expected from QCD in the Veneziano limit of large N_f and N_c with fixed x = N_f/N_c. The models capture the holographic dynamics of the dilaton (dual to the YM coupling) and a tachyon (dual to the chiral condensate), and are parametrized by the real parameter x, which can take values within the range 0 = x_c, and the QCD-like phase with chiral symmetry breaking at x x_c as well as Efimov-like saddle points. By calculating the holographic beta-functions, we demonstrate the "walking" behavior of the coupling in the region near and below x_c.

Acyl Radical Reactions in Fullerene Chemistry : Direct Acylation of [60]Fullerene through an Efficient Decatungstate-Photomediated Approach

Abstract: A versatile and highly efficient photochemical methodology for the direct acylation of C(60) has been developed. This approach utilizes a wide variety of acyl radicals derived from aldehydes through a hydrogen atom abstraction process mediated by tetrabutylammonium decatungstate [(n-Bu(4)N)(4)W(10)O(32)]. The single addition reaction of these acyl radicals to [60]fullerene proceeded selectively to afford a novel class of previously unexplored fullerene-based materials. Product analysis of this reaction showed that decarbonylation and acylation pathways compete when a tertiary or phenylacetyl aldehyde is the starting material. However, a decrease of the reaction temperature was found to be effective in overcoming the decarbonylation encountered in certain acyl radical additions to C(60); the carbonyl radical addition precedes decarbonylation even in the cases where the decarbonylation rate constant exceeds 10(6) s(-1) (i.e., phenylacetaldehyde). The regiochemistry of the t-butyl radical addition was also found to be thermally controlled. The present methodology is directly applicable even in the cases of the cyclopropyl-substituted aldehydes, where rapid rearrangement of the cyclopropyl acyl radical intermediate can potentially occur. A mechanistic approach for this new reactivity of C(60) has been also provided, based mainly on intra- and intermolecular deuterium isotope effect studies.