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Institution

University of Delaware

EducationNewark, Delaware, United States
About: University of Delaware is a education organization based out in Newark, Delaware, United States. It is known for research contribution in the topics: Population & Catalysis. The organization has 22223 authors who have published 54810 publications receiving 2049136 citations. The organization is also known as: University of Delaware Emergency Care Unit & UD.


Papers
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Journal ArticleDOI
TL;DR: In this paper, a new method for analysing nonlinear and nonstationary data has been developed, which is the key part of the method is the empirical mode decomposition method with which any complicated data set can be decoded.
Abstract: A new method for analysing nonlinear and non-stationary data has been developed. The key part of the method is the empirical mode decomposition method with which any complicated data set can be dec...

18,956 citations

Journal ArticleDOI
Claude Amsler1, Michael Doser2, Mario Antonelli, D. M. Asner3  +173 moreInstitutions (86)
TL;DR: This biennial Review summarizes much of particle physics, using data from previous editions.

12,798 citations

Journal ArticleDOI
27 Apr 2001-Science
TL;DR: This work focuses primarily on the periodic and anomalous components of variability over the early portion of this era, as constrained by the latest generation of deep-sea isotope records.
Abstract: Since 65 million years ago (Ma), Earth's climate has undergone a significant and complex evolution, the finer details of which are now coming to light through investigations of deep-sea sediment cores. This evolution includes gradual trends of warming and cooling driven by tectonic processes on time scales of 10(5) to 10(7) years, rhythmic or periodic cycles driven by orbital processes with 10(4)- to 10(6)-year cyclicity, and rare rapid aberrant shifts and extreme climate transients with durations of 10(3) to 10(5) years. Here, recent progress in defining the evolution of global climate over the Cenozoic Era is reviewed. We focus primarily on the periodic and anomalous components of variability over the early portion of this era, as constrained by the latest generation of deep-sea isotope records. We also consider how this improved perspective has led to the recognition of previously unforeseen mechanisms for altering climate.

8,903 citations

Journal ArticleDOI
TL;DR: In this paper, an estimation procedure based on adding small positive quantities to the diagonal of X′X was proposed, which is a method for showing in two dimensions the effects of nonorthogonality.
Abstract: In multiple regression it is shown that parameter estimates based on minimum residual sum of squares have a high probability of being unsatisfactory, if not incorrect, if the prediction vectors are not orthogonal. Proposed is an estimation procedure based on adding small positive quantities to the diagonal of X′X. Introduced is the ridge trace, a method for showing in two dimensions the effects of nonorthogonality. It is then shown how to augment X′X to obtain biased estimates with smaller mean square error.

8,091 citations

Journal ArticleDOI
TL;DR: In this paper, the stability of reaction intermediates of electrochemical processes on the basis of electronic structure calculations was analyzed and a detailed description of the free energy landscape of the electrochemical oxygen reduction reaction over Pt(111) as a function of applied bias was presented.
Abstract: We present a method for calculating the stability of reaction intermediates of electrochemical processes on the basis of electronic structure calculations. We used that method in combination with detailed density functional calculations to develop a detailed description of the free-energy landscape of the electrochemical oxygen reduction reaction over Pt(111) as a function of applied bias. This allowed us to identify the origin of the overpotential found for this reaction. Adsorbed oxygen and hydroxyl are found to be very stable intermediates at potentials close to equilibrium, and the calculated rate constant for the activated proton/electron transfer to adsorbed oxygen or hydroxyl can account quantitatively for the observed kinetics. On the basis of a database of calculated oxygen and hydroxyl adsorption energies, the trends in the oxygen reduction rate for a large number of different transition and noble metals can be accounted for. Alternative reaction mechanisms involving proton/electron transfer to ...

7,711 citations


Authors

Showing all 22448 results

NameH-indexPapersCitations
Yushan Yan8938828544
Ali Guermazi8973231590
J. David Sweatt8822429437
Christopher B. Murray8833654410
David R. Bellwood8834235435
Richard B. Ivry8731428536
S. Tilav8639125111
Dionisios G. Vlachos8652224687
Lynn Snyder-Mackler8634024228
D. Seckel8641024036
David L. Kirchman8622424500
Bingqing Wei8634528325
Joseph G. Gleeson8630723345
Gary Bernstein8636427254
Paul Evenson8545725601
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
20241
2023103
2022377
20212,750
20202,712
20192,539