University of Electro-Communications

About: University of Electro-Communications is a education organization based out in Tokyo, Japan. It is known for research contribution in the topics: Laser & Robot. The organization has 8041 authors who have published 16950 publications receiving 235832 citations. The organization is also known as: UEC & Denki-Tsūshin Daigaku.

Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions.

Abstract: Catalytic transformation of CH4 under a mild condition is significant for efficient utilization of shale gas under the circumstance of switching raw materials of chemical industries to shale gas. Here, we report the transformation of CH4 to acetic acid and methanol through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in solution at ≤150 °C. The activity of these singly dispersed precious metal sites for production of organic oxygenates can reach about 0.10 acetic acid molecules on a Rh1O5 site per second at 150 °C with a selectivity of ~70% for production of acetic acid. It is higher than the activity of free Rh cations by >1000 times. Computational studies suggest that the first C–H bond of CH4 is activated by Rh1O5 anchored on the wall of micropores of ZSM-5; the formed CH3 then couples with CO and OH, to produce acetic acid over a low activation barrier. Catalytic transformation of CH4 under mild conditions has implications to shale gas utilization. Here, the authors report the transformation of CH4 to acetic acid through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in liquid phase.

Polarized raman study of single-wall semiconducting carbon nanotubes

Abstract: Polarized Raman spectra were obtained from a rope of aligned semiconducting single-wall nanotubes (SWNTs) in the vicinity of the D band and the G band. Based on group theory analysis and related theoretical predictions, the G-band profile was deconvolved into four intrinsic SWNT components with the following symmetry assignments: 1549 cm(-1) [E-2(E-2g)], 1567 cm(-1) [A(A(1g)) + E-1(E-1g)], 1590 cm(-1) [A(A(1g)) + E-1(E-1g)] and 1607 cm(-1) [E-2(E-2g)]. The frequency shifts of the tangential G modes from the 2D graphitelike E-2g2 frequency are discussed in terms of the nanotube geometry.

Text segmentation based on similarity between words

Abstract: This paper proposes a new indicator of text structure, called the lexical cohesion profile (LCP), which locates segment boundaries in a text. A text segment is a coherent scene; the words in a segment are linked together via lexical cohesion relations. LCP records mutual similarity of words in a sequence of text. The similarity of words, which represents their cohesiveness, is computed using a semantic network. Comparison with the text segments marked by a number of subjects shows that LCP closely correlates with the human judgments. LCP may provide valuable information for resolving anaphora and ellipsis.

Text Segmentation Based on Similarity between Words

Abstract: This paper proposes a new indicator of text structure, called the lexical cohesion profile (LCP), which locates segment boundaries in a text. A text segment is a coherent scene; the words in a segment are linked together via lexical cohesion relations. LCP records mutual similarity of words in a sequence of text. The similarity of words, which represents their cohesiveness, is computed using a semantic network. Comparison with the text segments marked by a number of subjects shows that LCP closely correlates with the human judgments. LCP may provide valuable information for resolving anaphora and ellipsis.