Institution
University of Extremadura
Education•Badajoz, Spain•
About: University of Extremadura is a education organization based out in Badajoz, Spain. It is known for research contribution in the topics: Population & Hyperspectral imaging. The organization has 7856 authors who have published 18299 publications receiving 396126 citations. The organization is also known as: Universidad de Extremadura.
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TL;DR: In this article, the photodecomposition of chloro-phenolic derivative pollutants was investigated using a single photodegromposition produced by polychromatic UV irradiation and a photo-Fenton system.
Abstract: The oxidation of some chlorophenols: 4-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, tetrachlorocatechol (3,4,5,6-tetrachloro-2-hydroxy phenol) and 4-chloroguaiacol (4-chloro-2-methoxy phenol) has been studied via single photodecomposition produced by polychromatic UV irradiation, oxidation by hydroxyl radicals generated by Fenton's reagent (hydrogen peroxide plus ferrous ions), and degradation by hydroxyl radicals produced by combinations of UV irradiation plus hydrogen peroxide, and UV irradiation plus hydrogen peroxide and ferrous ions (photo-Fenton system). These organics have been selected as models of chloro-phenolic derivative pollutants present in wastewaters and groundwaters. The degradation levels obtained in each process are reported. The quantum yields in the single photodecomposition reaction and the rate constants between the chlorophenols and the hydroxyl radicals in the reaction with Fenton's reagent are determined. Finally, the additional contributions to the photodecomposition promoted by the radical reaction in the combined UV/H2O2 and photo-Fenton systems are also evaluated.
© 2001 Society of Chemical Industry
85 citations
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TL;DR: A general formalism for calculating translational and rotational transport properties, as well as intrinsic viscosities, of rigid macromolecules with an arbitrary shape is proposed in this paper, which can be regarded as a generalization of the one proposed by Nakajima and Wada.
Abstract: A general formalism, which includes translation–rotation coupling, is proposed for calculating translational and rotational transport properties, as well as intrinsic viscosities, of rigid macromolecules with an arbitrary shape. This formalism is based on Brenner's theory of translational–rotational dynamics and on methods for the calculation of hydrodynamic properties that have been already presented, and can be regarded as a generalization of the one proposed by Nakajima and Wada. The calculated transport properties depend on the origin as predicted by Brenner's theory, but in a disagreement with him, the center of resistance and the center of diffusion do not coincide. As one can define several hydrodynamic centers, which in practice turn out to be located at different points, the influence of the choice of the center on the calculated transport properties is discussed. An analysis of the translation–rotation coupling effects in translational diffusion reveals that they arise exclusively from hydrodynamic interactions and are rather small in some cases of interest. Finally, we present a study of the rotational diffusion of rigid bent rods with a fixed length-to-diameter ratio. The diffusion coefficients obtained can be useful to estimate changes with respect to a straight rod.
85 citations
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TL;DR: The feasibility of the treatment of a complex industrial wastewater by aerobic biodegradation in a sequential batch reactor (SBR) followed by ozone-based advanced oxidation processes (AOPs) has been studied as mentioned in this paper.
85 citations
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TL;DR: In this paper, the authors examined the elements that may influence client loyalty in the e-marketplace context, investigating the influence of image, quality, satisfaction, and value on client loyalty.
85 citations
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TL;DR: In this paper, the degradation of the pollutant organic matter present in olive oil mill wastewaters (OMW) is carried out by a single ozonation, a single aerobic degradation, and the combination of two successives steps.
Abstract: The degradation of the pollutant organic matter present in olive oil mill wastewaters (OMW) is carried out by a single ozonation, a single aerobic degradation, and the combination of two successives steps: an ozonation followed by an aerobic degradation, and an aerobic degradation followed by an ozonation. In both single processes, the removal of this contaminant load is followed by means of global parameters which are directly related to the concentration of organic compounds in those effluents: chemical oxygen demand and total aromatic and phenolic contents. In the ozonation, an approximate kinetic study is performed which leads to the evaluation of the apparent kinetic constants for the aromatic reduction, kA. In the aerobic degradation, the kinetic study is conducted by using the Grau model, which is applied to the experimental data, and leads to the determination of the kinetic parameters of this model, K2 and n. In the combined processes, a higher COD global reduction is obtained by the successive stages, and an improvement in the removal of the organic material during the second treatment of both processes due to the pretreatment conducted is also observed. This enhancement is shown by an increase of the kinetic parameters (K2 and n in the aerobic degradation of the pre-ozonated wastewaters; the apparent constant kA in the ozonation of the wastewaters preliminary fermented aerobically), in relation to the values obtained for them in the single processes carried out at the same operating conditions.
© 1999 Society of Chemical Industry
85 citations
Authors
Showing all 8001 results
Name | H-index | Papers | Citations |
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Russel J. Reiter | 169 | 1646 | 121010 |
Donald G. Truhlar | 165 | 1518 | 157965 |
Manel Esteller | 146 | 713 | 96429 |
David J. Williams | 107 | 2060 | 62440 |
Keijo Häkkinen | 99 | 421 | 31355 |
Robert H. Anderson | 97 | 1237 | 41250 |
Leif Bertilsson | 87 | 321 | 23933 |
Mario F. Fraga | 84 | 267 | 32957 |
YangQuan Chen | 84 | 1048 | 36543 |
Antonio Plaza | 79 | 631 | 29775 |
Robert D. Gibbons | 75 | 349 | 26330 |
Jocelyn Chanussot | 73 | 614 | 27949 |
Naresh Magan | 72 | 400 | 17511 |
Luis Puelles | 71 | 269 | 19858 |
Jun Li | 70 | 799 | 19510 |