Showing papers by "University of Lincoln published in 2021"

Alleviation of Dendrite Formation on Zinc Anodes via Electrolyte Additives

Abstract: Zinc-anode-based batteries have been widely studied because of their low cost, high capacity, and high energy density. However, the formation of dendrites on the zinc anode during cycling severely ...

Internet of Things for the Future of Smart Agriculture: A Comprehensive Survey of Emerging Technologies

Abstract: This paper presents a comprehensive review of emerging technologies for the internet of things (IoT)-based smart agriculture. We begin by summarizing the existing surveys and describing emergent technologies for the agricultural IoT, such as unmanned aerial vehicles, wireless technologies, open-source IoT platforms, software defined networking (SDN), network function virtualization (NFV) technologies, cloud/fog computing, and middleware platforms. We also provide a classification of IoT applications for smart agriculture into seven categories: including smart monitoring, smart water management, agrochemicals applications, disease management, smart harvesting, supply chain management, and smart agricultural practices. Moreover, we provide a taxonomy and a side-by-side comparison of the state-of-the-art methods toward supply chain management based on the blockchain technology for agricultural IoTs. Furthermore, we present real projects that use most of the aforementioned technologies, which demonstrate their great performance in the field of smart agriculture. Finally, we highlight open research challenges and discuss possible future research directions for agricultural IoTs.

Extended urbanisation and the spatialities of infectious disease: Demographic change, infrastructure and governance:

Abstract: This paper argues that contemporary processes of extended urbanisation, which include suburbanisation, post-suburbanisation and peri-urbanisation, may result in increased vulnerability to infectiou...

A Survey on Smart Agriculture: Development Modes, Technologies, and Security and Privacy Challenges

Abstract: With the deep combination of both modern information technology and traditional agriculture, the era of agriculture 4.0, which takes the form of smart agriculture, has come. Smart agriculture provides solutions for agricultural intelligence and automation. However, information security issues cannot be ignored with the development of agriculture brought by modern information technology. In this paper, three typical development modes of smart agriculture (precision agriculture, facility agriculture, and order agriculture) are presented. Then, 7 key technologies and 11 key applications are derived from the above modes. Based on the above technologies and applications, 6 security and privacy countermeasures (authentication and access control, privacy-preserving, blockchain-based solutions for data integrity, cryptography and key management, physical countermeasures, and intrusion detection systems) are summarized and discussed. Moreover, the security challenges of smart agriculture are analyzed and organized into two aspects: 1) agricultural production, and 2) information technology. Most current research projects have not taken agricultural equipment as potential security threats. Therefore, we did some additional experiments based on solar insecticidal lamps Internet of Things, and the results indicate that agricultural equipment has an impact on agricultural security. Finally, more technologies (5 G communication, fog computing, Internet of Everything, renewable energy management system, software defined network, virtual reality, augmented reality, and cyber security datasets for smart agriculture) are described as the future research directions of smart agriculture.

Knowledge Management in the Fourth Industrial Revolution: Mapping the Literature and Scoping Future Avenues

Abstract: Due to increased competitive pressure, modern organizations tend to rely on knowledge and its exploitation to sustain a long-term advantage. This calls for a precise understanding of knowledge management (KM) processes and, specifically, how knowledge is created, shared/transferred, acquired, stored/retrieved, and applied throughout an organizational system. However, since the beginning of the new millennium, such KM processes have been deeply affected and molded by the advent of the fourth industrial revolution, also called Industry 4.0, which involves the interconnectedness of machines and their ability to learn and share data autonomously. For this reason, the present article investigates the intellectual structure and trends of KM in Industry 4.0. Bibliometric analysis and a systematic literature review are conducted on a total of 90 relevant articles. The results reveal six clusters of keywords, subsequently explored via a systematic literature review to identify potential stream of this emergent field and future research avenues capable of producing meaningful advances in managerial knowledge of Industry 4.0 and its consequences.

Insights on Flexible Zinc-Ion Batteries from Lab Research to Commercialization

Abstract: Owing to the development of aqueous rechargeable zinc-ion batteries (ZIBs), flexible ZIBs are deemed as potential candidates to power wearable electronics. ZIBs with solid-state polymer electrolytes can not only maintain additional load-bearing properties, but exhibit enhanced electrochemical properties by preventing dendrite formation and inhibiting cathode dissolution. Substantial efforts have been applied to polymer electrolytes by developing solid polymer electrolytes, hydrogel polymer electrolytes, and hybrid polymer electrolytes; however, the research of polymer electrolytes for ZIBs is still immature. Herein, the recent progress in polymer electrolytes is summarized by category for flexible ZIBs, especially hydrogel electrolytes, including their synthesis and characterization. Aiming to provide an insight from lab research to commercialization, the relevant challenges, device configurations, and life cycle analysis are consolidated. As flexible batteries, the majority of polymer electrolytes exploited so far only emphasizes the electrochemical performance but the mechanical behavior and interactions with the electrode materials have hardly been considered. Hence, strategies of combining softness and strength and the integration with electrodes are discussed for flexible ZIBs. A ranking index, combining both electrochemical and mechanical properties, is introduced. Future research directions are also covered to guide research toward the commercialization of flexible ZIBs.

Palladium alloys used as electrocatalysts for the oxygen reduction reaction

Abstract: Palladium-based alloy materials as cathodes for the reduction of oxygen are regarded as potential substitutes for platinum-based catalysts in fuel cells. In this work, we present a scientometric analysis and critically review the use of Pd alloys for the oxygen reduction reaction (ORR). Through scientometric analysis, publication information, research fronts and hotspots are identified. For the critical review, reaction mechanisms in different media are discussed, with the aid of volcano plots to show the general principles for catalyst modifications to maximise the ORR. Influencing factors, including alloying, structure, strain and ligands, particle size, crystal facets and dealloying are considered with a view to informing the theoretical feasibility to enhance the ORR activity. In addition, Pd-based alloys synthesized by different methods are presented and compared in terms of ORR activities. Future research directions are discussed and possible approaches to mass production for industrialization are also proposed.

A year of genomic surveillance reveals how the SARS-CoV-2 pandemic unfolded in Africa.

Abstract: The progression of the SARS-CoV-2 pandemic in Africa has so far been heterogeneous and the full impact is not yet well understood. Here, we describe the genomic epidemiology using a dataset of 8746 genomes from 33 African countries and two overseas territories. We show that the epidemics in most countries were initiated by importations predominantly from Europe, which diminished following the early introduction of international travel restrictions. As the pandemic progressed, ongoing transmission in many countries and increasing mobility led to the emergence and spread within the continent of many variants of concern and interest, such as B.1.351, B.1.525, A.23.1 and C.1.1. Although distorted by low sampling numbers and blind spots, the findings highlight that Africa must not be left behind in the global pandemic response, otherwise it could become a source for new variants.

Global blue carbon accumulation in tidal wetlands increases with climate change.

Abstract: Coastal tidal wetlands produce and accumulate significant amounts of organic carbon (C) that help to mitigate climate change. However, previous data limitations have prevented a robust evaluation of the global rates and mechanisms driving C accumulation. Here, we go beyond recent soil C stock estimates to reveal global tidal wetland C accumulation and predict changes under relative sea-level rise, temperature and precipitation. We use data from literature study sites and our new observations spanning wide latitudinal gradients and 20 countries. Globally, tidal wetlands accumulate 53.65 (95%CI: 48.52–59.01) Tg C yr−1, which is ∼30% of the organic C buried on the ocean floor. Modelling based on current climatic drivers and under projected emissions scenarios revealed a net increase in the global C accumulation by 2100. This rapid increase is driven by sea-level rise in tidal marshes, and higher temperature and precipitation in mangroves. Countries with large areas of coastal wetlands, like Indonesia and Mexico, are more susceptible to tidal wetland C losses under climate change, while regions such as Australia, Brazil, the USA and China will experience a significant C accumulation increase under all projected scenarios.

The plastic waste problem in Malaysia: management, recycling and disposal of local and global plastic waste

Abstract: Plastic waste is one of the world’s most pressing human health and environmental concerns. Plastic constitutes the third highest waste source globally, with the total volume of plastic waste growing in-line with increases in the global population and per capita consumption. Malaysia is tracking global trends in both the overall generation of plastic waste and the consumption of single-use plastics and since 2017 has been the world’s largest importer of plastic waste. These elements create a number of major challenges for the country’s waste management system. This review outlines the current state of plastic waste production and management in Malaysia, including options for landfill, recycling and incineration. It presents information on the scale and both the human and ecological risks of plastic waste in the country (i.e. microplastics, landfill, incineration), outlines key plastic waste management policy initiatives (including plastics alternatives such as biodegradable plastics) and highlights key constraints on the success of these. Significant internal constraints stem from the inconsistent application of policy initiatives by state governments, in addition to the lack of public awareness and interest in household recycling. The paper closes by discussing options for and constraints on the switch to biodegradable alternatives and proposes a model of plastic management based on a circular economy approach and solid waste management hierarchy. Success in reducing the problems posed by plastic in Malaysia will require sustained effort at many levels, but positive experiences in other countries give some cause for optimism.

The effect of face masks and sunglasses on identity and expression recognition with super-recognizers and typical observers.

Abstract: Face masks present a new challenge to face identification (here matching) and emotion recognition in Western cultures. Here, we present the results of three experiments that test the effect of masks, and also the effect of sunglasses (an occlusion that individuals tend to have more experienced with) on (i) familiar face matching, (ii) unfamiliar face matching and (iii) emotion categorization. Occlusion reduced accuracy in all three tasks, with most errors in the mask condition; however, there was little difference in performance for faces in masks compared with faces in sunglasses. Super-recognizers, people who are highly skilled at matching unconcealed faces, were impaired by occlusion, but at the group level, performed with higher accuracy than controls on all tasks. Results inform psychology theory with implications for everyday interactions, security and policing in a mask-wearing society.

Industry 4.0 and circular economy: An exploratory analysis of academic and practitioners' perspectives

Abstract: The union between Industry 4.0 and the circular economy (CE) appears relatively recent. In this sense, new trading zones for sharing a common scenario among academics and practitioners are needed. The paper aims to investigate the link between Industry 4.0 and the CE by understanding how Industry 4.0 can foster the impact of the CE on companies. The study proposes a broader perspective that includes thematic and content analysis gathering data on professional documents based on business cases, newspaper articles, press releases and specialised blogs, as well as scientific papers. The joint academic‐practitioners view highlights how Industry 4.0 has the potential to impact on the CE through countless actions: increasing waste disposal; promoting remanufacturing; enhancing the efficiency of critical resources such as water, energy, gas and CO2; and improving business models and the mission of companies. However, barriers still exist in its adoption, stressing the need for holistic and integrated design and a proactive environment of collaboration among stakeholders. Results lead to practical as well as research implications.

Cathode Design for Aqueous Rechargeable Multivalent Ion Batteries: Challenges and Opportunities

Abstract: With the rapid growth in energy consumption, renewable energy is a promising solution. However, renewable energy (e.g., wind, solar, and tidal) is discontinuous and irregular by nature, which poses new challenges to the new generation of large-scale energy storage devices. Rechargeable batteries using aqueous electrolyte and multivalent ion charge are considered more suitable candidates compared to lithium-ion and lead-acid batteries, owing to their low cost, ease of manufacture, good safety, and environmentally benign characteristics. However, some substantial challenges hinder the development of aqueous rechargeable multivalent ion batteries (AMVIBs), including the narrow stable electrochemical window of water (≈1.23 V), sluggish ion diffusion kinetics, and stability issues of electrode materials. To address these challenges, a range of encouraging strategies has been developed in recent years, in the aspects of electrolyte optimization, material structure engineering and theoretical investigations. To inspire new research directions, this review focuses on the latest advances in cathode materials for aqueous batteries based on the multivalent ions (Zn2+, Mg2+, Ca2+, Al3+), their common challenges, and promising strategies for improvement. In addition, further suggestions for development directions and a comparison of the different AMVIBs are covered.

Heterogeneous contributions of change in population distribution of body mass index to change in obesity and underweight

Abstract: From 1985 to 2016, the prevalence of underweight decreased, and that of obesity and severe obesity increased, in most regions, with significant variation in the magnitude of these changes across regions. We investigated how much change in mean body mass index (BMI) explains changes in the prevalence of underweight, obesity, and severe obesity in different regions using data from 2896 population-based studies with 187 million participants. Changes in the prevalence of underweight and total obesity, and to a lesser extent severe obesity, are largely driven by shifts in the distribution of BMI, with smaller contributions from changes in the shape of the distribution. In East and Southeast Asia and sub-Saharan Africa, the underweight tail of the BMI distribution was left behind as the distribution shifted. There is a need for policies that address all forms of malnutrition by making healthy foods accessible and affordable, while restricting unhealthy foods through fiscal and regulatory restrictions.

To which world regions does the valence–dominance model of social perception apply?

Abstract: Over the past 10 years, Oosterhof and Todorov’s valence–dominance model has emerged as the most prominent account of how people evaluate faces on social dimensions. In this model, two dimensions (valence and dominance) underpin social judgements of faces. Because this model has primarily been developed and tested in Western regions, it is unclear whether these findings apply to other regions. We addressed this question by replicating Oosterhof and Todorov’s methodology across 11 world regions, 41 countries and 11,570 participants. When we used Oosterhof and Todorov’s original analysis strategy, the valence–dominance model generalized across regions. When we used an alternative methodology to allow for correlated dimensions, we observed much less generalization. Collectively, these results suggest that, while the valence–dominance model generalizes very well across regions when dimensions are forced to be orthogonal, regional differences are revealed when we use different extraction methods and correlate and rotate the dimension reduction solution.

Greenland surface air temperature changes from 1981 to 2019 and implications for ice-sheet melt and mass-balance change

Abstract: We provide an updated analysis of instrumental Greenland monthly temperature data to 2019, focusing mainly on coastal stations but also analysing ice-sheet records from Swiss Camp and Summit. Significant summer (winter) coastal warming of ~1.7 (4.4) C occurred from 1991-2019, but since 2001 overall temperature trends are generally flat and insignificant due to a cooling pattern over the last 6-7 years. Inland and coastal stations show broadly similar temperature trends for summer. Greenland temperature changes are more strongly correlated with Greenland Blocking than with North Atlantic Oscillation changes. In quantifying the association between Greenland coastal temperatures and Greenland Ice Sheet (GrIS) mass-balance changes, we show a stronger link of temperatures with total mass balance rather than surface mass balance. Based on Greenland coastal temperatures and modelled mass balance for the 1972-2018 period, each 1C of summer warming corresponds to ~ (91) 116 Gt yr-1 of GrIS (surface) mass loss and a 26 Gt yr-1 increase in solid ice discharge. Given an estimated 4.0-6.6C of further Greenland summer warming according to the regional model MAR projections run under CMIP6 future climate projections (SSP5-8.5 scenario), and assuming that ice-dynamical losses and ice sheet topography stay similar to the recent past, linear extrapolation gives a corresponding GrIS global sea-level rise (SLR) contribution of ~10.0-12.6 cm by 2100, compared with the 8-27 cm (mean 15 cm) “likely” model projection range reported by IPCC (2019, SPM.B1.2). However, our estimate represents a lower limit for future GrIS change since fixed dynamical mass losses and amplified melt arising from both melt-albedo and melt-elevation positive feedbacks are not taken into account here.

Pedestrian Models for Autonomous Driving Part II: High-Level Models of Human Behavior

Abstract: Autonomous vehicles (AVs) must share space with pedestrians, both in carriageway cases such as cars at pedestrian crossings and off-carriageway cases such as delivery vehicles navigating through crowds on pedestrianized high-streets. Unlike static obstacles, pedestrians are active agents with complex, interactive motions. Planning AV actions in the presence of pedestrians thus requires modelling of their probable future behavior as well as detecting and tracking them. This narrative review article is Part II of a pair, together surveying the current technology stack involved in this process, organising recent research into a hierarchical taxonomy ranging from low-level image detection to high-level psychological models, from the perspective of an AV designer. This self-contained Part II covers the higher levels of this stack, consisting of models of pedestrian behavior, from prediction of individual pedestrians’ likely destinations and paths, to game-theoretic models of interactions between pedestrians and autonomous vehicles. This survey clearly shows that, although there are good models for optimal walking behavior, high-level psychological and social modelling of pedestrian behavior still remains an open research question that requires many conceptual issues to be clarified. Early work has been done on descriptive and qualitative models of behavior, but much work is still needed to translate them into quantitative algorithms for practical AV control.

How do intermittency and simultaneous processes obfuscate the Arctic influence on midlatitude winter extreme weather events

Abstract: Pronounced changes in the Arctic environment add a new potential driver of anomalous weather patterns in midlatitudes that affect billions of people. Recent studies of these Arctic/midlatitude weather linkages, however, state inconsistent conclusions. A source of uncertainty arises from the chaotic nature of the atmosphere. Thermodynamic forcing by a rapidly warming Arctic contributes to weather events through changing surface heat fluxes and large-scale temperature and pressure gradients. But internal shifts in atmospheric dynamics — the variability of the location, strength, and character of the jet stream, blocking, and stratospheric polar vortex (SPV) — obscure the direct causes and effects. It is important to understand these associated processes to differentiate Arctic-forced variability from natural variability. For example in early winter, reduced Barents/Kara Seas sea-ice coverage may reinforce existing atmospheric teleconnections between the North Atlantic/Arctic and central Asia, and affect downstream weather in East Asia. Reduced sea ice in the Chukchi Sea can amplify atmospheric ridging of high pressure near Alaska, influencing downstream weather across North America. In late winter southward displacement of the SPV, coupled to the troposphere, leads to weather extremes in Eurasia and North America. Combined tropical and sea ice conditions can modulate the variability of the SPV. Observational evidence for Arctic/midlatitude weather linkages continues to accumulate, along with understanding of connections with pre-existing climate states. Relative to natural atmospheric variability, sea-ice loss alone has played a secondary role in Arctic/midlatitude weather linkages; the full influence of Arctic amplification remains uncertain.

In situ construction of heterostructured bimetallic sulfide/phosphide with rich interfaces for high-performance aqueous Zn-ion batteries

Abstract: It is still challenging to develop suitable cathode structures for high-rate and stable aqueous Zn-ion batteries. Herein, a phosphating-assisted interfacial engineering strategy is designed for the controllable conversion of NiCo2S4 nanosheets into heterostructured NiCoP/NiCo2S4 as the cathodes in aqueous Zn-ion batteries. The multicomponent heterostructures with rich interfaces can not only improve the electrical conductivity but also enhance the diffusion pathways for Zn-ion storage. As expected, the NiCoP/NiCo2S4 electrode has high performance with a large specific capacity of 251.1 mA h g−1 at a high current density of 10 A g−1 and excellent rate capability (retaining about 76% even at 50 A g−1). Accordingly, the Zn-ion battery using NiCoP/NiCo2S4 as the cathode delivers a high specific capacity (265.1 mA h g−1 at 5A g−1), a long-term cycling stability (96.9% retention after 5000 cycles), and a competitive energy density (444.7 W h kg−1 at the power density of 8.4 kW kg−1). This work therefore provides a simple phosphating-assisted interfacial engineering strategy to construct heterostructured electrode materials with rich interfaces for the development of high-performance energy storage devices in the future.