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Institution

University of Madras

EducationChennai, Tamil Nadu, India
About: University of Madras is a education organization based out in Chennai, Tamil Nadu, India. It is known for research contribution in the topics: Ring (chemistry) & Lipid peroxidation. The organization has 8496 authors who have published 11369 publications receiving 211152 citations. The organization is also known as: Madras University & University of Chennai.


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Journal ArticleDOI
TL;DR: A novel strategy for the biological synthesis of anisotropic gold and quasi-spherical silver nanoparticles by using apiin as the reducing and stabilizing agent is reported, expected to be of application in hyperthermia of cancer cells and in IR-absorbing optical coatings.

494 citations

Journal ArticleDOI
TL;DR: In this article, an analytical formulation of the theories of nutation and wobble reveals the combinations of basic Earth parameters that govern the nutation-wobble response of the Earth to gravitational (tidal) forcing by heavenly bodies and makes it possible to estimate several of them through a least squares fit of the theoretical expressions to the high-precision data now available.
Abstract: [1] The analytical formulation of the theories of nutation and wobble reveals the combinations of basic Earth parameters that govern the nutation-wobble response of the Earth to gravitational (tidal) forcing by heavenly bodies and makes it possible to estimate several of them through a least squares fit of the theoretical expressions to the high-precision data now available. This paper presents the essentials of the theoretical framework, the procedure that we used for least squares estimation of basic Earth parameters through a fit of theory to nutation-precession data derived from an up-to-date very long baseline interferometry data set, the results of the estimation and their geophysical interpretation, and the nutation series constructed using the estimated values of the parameters. The theoretical formulation used here differs from earlier ones in the incorporation of anelasticity and ocean tide effects into the basic structure of the dynamical equations of the theory and in the inclusion of electromagnetic couplings of the mantle and the solid inner core to the fluid outer core, though this generalization comes at the cost of making some of the system parameters complex and frequency dependent; it is also more complete, as it takes account of nonlinear terms in these equations, including effects of the time-dependent deformations produced by zonal and sectorial tides, which had been traditionally neglected in nonrigid Earth theories. Among the geophysical results obtained from our fit are estimates for the dynamic ellipticity e of the Earth (e = 0.0032845479 with an uncertainty of 12 in the last digit), for the dynamical ellipticity ef of the fluid core (3.8% higher than its hydrostatic equilibrium value, rather than ∼5% as hitherto), and for the two complex electromagnetic coupling constants. Our best estimates for the RMS radial magnetic fields at the core mantle boundary and at the inner core boundary, based on the estimates for these coupling constants, are ~6.9 and 72 gauss, respectively, when the magnetic field configurations are restricted to certain simple classes. The field strength needed at the inner core boundary could be lower if the density of the core fluid at this boundary or the ellipticity of the solid inner core were lower than that for the Preliminary Reference Earth Model. Our estimate for the resonance frequency of the prograde free core nutation mode, with an uncertainty of ∼10%, constitutes the first firm detection of the resonance associated with this mode; the period found is ∼1025 days, double that with electromagnetic couplings ignored. (Throughout this work, “days,” referring to periods, stands for “mean solar days.”) A new nutation series (MHB2000) is constructed by direct solution of the linearized dynamical equations (with our best fit values adopted for all the estimated Earth parameters) for each forcing frequency, and adding on the contributions from the nonlinear terms and other effects not included in the linearized equations. This series gives a considerably better fit to the nutation data than any of the earlier series based on geophysical theory. In particular, the residuals in the out of phase amplitudes of the retrograde 18.6 year and annual nutations, which had long remained at ∼0.5 milliseconds of arc (mas), are now reduced to the level of the uncertainties in the observational estimates, thanks mainly to the role played by the electromagnetic couplings. The largest remaining discrepancy is that in the out of phase prograde 18.6 year nutation, of ∼72 micorseconds of arc (μas). The frequency dependence of the nutation amplitudes cannot be exactly represented through a resonance formula, nor may the resonance frequencies themselves be interpreted as the eigenfrequencies of free modes because of the presence of complex and frequency-dependent system parameters. Nevertheless, we have constructed a new resonance formula which reproduces our nutation series accurately for almost all nutation frequencies; for the few remaining frequencies, a listing is given of the corrections to be applied in order to reproduce the exact results of the direct solution.

487 citations

Journal ArticleDOI
TL;DR: This review summarizes the recent work on the development of biocomposites containing natural polymers with hydroxyapatite particles suitable for use in bone defects/bone regeneration.

477 citations

Journal ArticleDOI
TL;DR: In this article, Petrographic, major, trace, and rare earth element compositions of sandstones from the upper Miocene Kudankulam Formation, Southern India, have been investigated to determine their provenance, tectonic setting, and weathering conditions.
Abstract: Petrographic, major, trace, and rare earth element compositions of sandstones from the upper Miocene Kudankulam Formation, Southern India, have been investigated to determine their provenance, tectonic setting, and weathering conditions. All sandstone samples are highly enriched in quartz (Q) but poor in feldspar (F) and lithic fragments (L). The major-element concentrations of these sandstones reveal the relative homogeneity of their source. Geochemically, the Kudankulam sandstones are classified as arkose, subarkose, litharenite, and sublitharenite. The CIA values (chemical index of alteration; mean value 44.5) for these sandstones and the A-CN-K diagram suggest their low-weathering nature. Similarly, their Fe2O3* + MgO (mean 2.7), Al2O3/SiO2 ( 0.09), K2O/Na2O ( 2.2) ratios and TiO2 contents ( 0.3) are consistent with a passive-margin setting. The Eu/Eu* ( 0.5), (La/Lu)cn ( 21), La/Sc ( 5.9), Th/Sc ( 1.9), La/Co ( 5.7), Th/Co ( 1.8), and Cr/Th ( 5.3) ratios support a felsic source for these sandstones. Chondrite-normalized REE patterns with LREE enrichment, flat HREE, and negative Eu anomaly also are attributed to felsic source-rock characteristics for Kudankulam sandstones. Total REE concentrations of these sandstones reflect the variations in their grain-size fractions. The source rocks are probably identified to be Proterozoic gneisses, charnockites, and granites of the Kerala Khondalite Belt, which must have been exposed at least since the late Miocene. Finally, the unusual Ni enrichment in the Kudankulam sandstones, unaccompanied by a similar enrichment in Cr, Co, and V, may be related to either the presence of pyrite in the sandstones or, more likely, the fractionation of garnet from the source rocks during transportation.

470 citations

Journal ArticleDOI
TL;DR: In this paper, a nanorod of pure ZnO was synthesized by simple thermal decomposition method using direct calcination of zinc acetate dihydrate, which was confirmed by X-ray diffraction.

450 citations


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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
202315
202283
2021644
2020564
2019457
2018435