University of Maryland, Baltimore County

About: University of Maryland, Baltimore County is a education organization based out in Baltimore, Maryland, United States. It is known for research contribution in the topics: Population & Aerosol. The organization has 8749 authors who have published 20843 publications receiving 795706 citations. The organization is also known as: UMBC.

Evidence for perchlorates and the origin of chlorinated hydrocarbons detected by SAM at the Rocknest aeolian deposit in Gale Crater

Abstract: [1] A single scoop of the Rocknest aeolian deposit was sieved (<150 μm), and four separate sample portions, each with a mass of ~50mg, were delivered to individual cups inside the Sample Analysis at Mars (SAM) instrument by the Mars Science Laboratory rover’ ss ample acquisition system. The samples were analyzed separately by the SAM pyrolysis evolved gas and gas chromatograph mass spectrometer analysis modes. Several chlorinated hydrocarbons including chloromethane, dichloromethane, trichloromethane, a chloromethylpropene, and chlorobenzene were identified by SAM above background levels with abundances of ~0.01 to 2.3nmol. The evolution of the chloromethanes observed during pyrolysis is coincident with the increase in O2 released from the Rocknest sample and the decomposition of a product of N-methyl-N-(tert-butyldimethylsilyl)-trifluoroacetamide (MTBSTFA), a chemical whose vapors were released from a derivatization cup inside SAM. The best candidate for the oxychlorine compounds in Rocknest is a hydrated calcium perchlorate (Ca(ClO4)2·nH2O), based on the temperature release of O2 that correlates with the release of the chlorinated hydrocarbons measured by SAM, although other chlorine-bearing phases are being considered. Laboratory analog experiments suggest that the reaction of Martian chlorine from perchlorate decomposition with terrestrial organic carbon from MTBSTFA during pyrolysis can explain the presence of three chloromethanes and a chloromethylpropene detected by SAM. Chlorobenzene may be attributed to reactionsofMartian chlorine released during pyrolysiswith terrestrial benzene or toluene derived from 2,6-diphenylphenylene oxide (Tenax) on the SAM hydrocarbon trap. At this time we do not have definitive evidence to support a nonterrestrial carbon source for these chlorinated hydrocarbons, nor do we exclude the possibility that future SAM analyses will reveal the presence of organic compounds native to the Martian regolith.

MODIS 3 km aerosol product: algorithm and global perspective

Abstract: . After more than a decade of producing a nominal 10 km aerosol product based on the dark target method, the MODerate resolution Imaging Spectroradiometer (MODIS) aerosol team will be releasing a nominal 3 km product as part of their Collection 6 release. The new product differs from the original 10 km product only in the manner in which reflectance pixels are ingested, organized and selected by the aerosol algorithm. Overall, the 3 km product closely mirrors the 10 km product. However, the finer resolution product is able to retrieve over the ocean closer to islands and coastlines, and is better able to resolve fine aerosol features such as smoke plumes over both ocean and land. In some situations, it provides retrievals over entire regions that the 10 km product barely samples. In situations traditionally difficult for the dark target algorithm such as over bright or urban surfaces, the 3 km product introduces isolated spikes of artificially high aerosol optical depth (AOD) that the 10 km algorithm avoids. Over land, globally, the 3 km product appears to be 0.01 to 0.02 higher than the 10 km product, while over ocean, the 3 km algorithm is retrieving a proportionally greater number of very low aerosol loading situations. Based on collocations with ground-based observations for only six months, expected errors associated with the 3 km land product are determined to be greater than that of the 10 km product: ± 0.05 ± 0.20 AOD. Over ocean, the suggestion is for expected errors to be the same as the 10 km product: ± 0.03 ± 0.05 AOD, but slightly less accurate in the coastal zone. The advantage of the product is on the local scale, which will require continued evaluation not addressed here. Nevertheless, the new 3 km product is expected to provide important information complementary to existing satellite-derived products and become an important tool for the aerosol community.

A New Determination of the Extragalactic Diffuse Gamma-Ray Background from EGRET Data

Abstract: We use the GALPROP model for cosmic-ray propagation to obtain a new estimate of the Galactic component of γ-rays and show that away from the Galactic plane it gives an accurate prediction of the observed EGRET intensities in the energy range 30 MeV to 50 GeV. On this basis we reevaluate the extragalactic γ-ray background. We find that for some energies previous work underestimated the Galactic contribution at high latitudes and hence overestimated the background. Our new background spectrum shows a positive curvature similar to that expected for models of the extragalactic emission based on the blazar population.

Transpacific transport of ozone pollution and the effect of recent Asian emission increases on air quality in North America: an integrated analysis using satellite, aircraft, ozonesonde, and surface observations

Abstract: We use an ensemble of aircraft, satellite, sonde, and surface observations for April–May 2006 (NASA/INTEX-B aircraft campaign) to better understand the mechanisms for transpacific ozone pollution and its implications for North American air quality The observations are interpreted with a global 3-D chemical transport model (GEOS-Chem) OMI NO2 satellite observations constrain Asian anthropogenic NOx emissions and indicate a factor of 2 increase from 2000 to 2006 in China Satellite observations of CO from AIRS and TES indicate two major events of Asian transpacific pollution during INTEX-B Correlation between TES CO and ozone observations shows evidence for transpacific ozone pollution The semi-permanent Pacific High and Aleutian Low cause splitting of transpacific pollution plumes over the Northeast Pacific The northern branch circulates around the Aleutian Low and has little impact on North America The southern branch circulates around the Pacific High and some of that air impacts western North America Both aircraft measurements and model results show sustained ozone production driven by peroxyacetylnitrate (PAN) decomposition in the southern branch, roughly doubling the transpacific influence from ozone produced in the Asian boundary layer Model simulation of ozone observations at Mt Bachelor Observatory in Oregon (27 km altitude) indicates a mean Asian ozone pollution contribution of 9±3 ppbv to the mean observed concentration of 54 ppbv, reflecting mostly an enhancement in background ozone rather than episodic Asian plumes Asian pollution enhanced surface ozone concentrations by 5–7 ppbv over western North America in spring 2006 The 2000–2006 rise in Asian anthropogenic emissions increased this influence by 1–2 ppbv

New Hyperspectral Discrimination Measure for Spectral Characterization

Abstract: The spectral angle mapper (SAM) has been widely used in multispectral and hyperspectral image analysis to measure spectral simi- larity between substance signatures for material identification. It has been shown that the SAM is essentially the Euclidean distance when the spectral angle is small. Most recently, a stochastic measure, called the spectral information divergence (SID), has been suggested to model the spectrum of a hyperspectral image pixel as a probability distribution, so that spectral variations among spectral bands can be captured more effectively in a stochastic manner. This paper develops a new hyper- spectral spectral discrimination measure, which combines the SID and the SAM into a mixed measure. More specifically, letr and r8 denote two hyperspectral image pixel vectors with their corresponding spectra speci- fied bys and s8. Then SAM(s,s8) measures the spectral angle between s and s8. Similarly, SID(s,s8) measures the information divergence be- tween the probability distributions generated by s and s8. The proposed new measure, referred to as the SID-SAM mixed measure, can be imple- mented in two versions, given by SID(s,s8)3tan(SAM(s,s8)) and SID(s,s8)3sin(SAM(s,s8)), where tan and sin are the usual trigonomet- ric functions. The spectral discriminability of such a mixed measure is greatly enhanced by multiplying the spectral abilities of the two mea- sures. In order to demonstrate its utility, a comparative study is con- ducted among the SID-SAM mixed measure, the SID, and the SAM. Our experimental results have shown that the discriminatory ability of the (SID,SAM) mixed measure can be a significant improvement over the SID and SAM. © 2004 Society of Photo-Optical Instrumentation Engineers.