University of Massachusetts Amherst

About: University of Massachusetts Amherst is a education organization based out in Amherst Center, Massachusetts, United States. It is known for research contribution in the topics: Population & Galaxy. The organization has 37274 authors who have published 83965 publications receiving 3834996 citations. The organization is also known as: UMass Amherst & Massachusetts State College.

Global cooling during the eocene-oligocene climate transition.

Abstract: About 34 million years ago, Earth's climate shifted from a relatively ice-free world to one with glacial conditions on Antarctica characterized by substantial ice sheets. How Earth's temperature changed during this climate transition remains poorly understood, and evidence for Northern Hemisphere polar ice is controversial. Here, we report proxy records of sea surface temperatures from multiple ocean localities and show that the high-latitude temperature decrease was substantial and heterogeneous. High-latitude (45 degrees to 70 degrees in both hemispheres) temperatures before the climate transition were ∼20°C and cooled an average of ∼5°C. Our results, combined with ocean and ice-sheet model simulations and benthic oxygen isotope records, indicate that Northern Hemisphere glaciation was not required to accommodate the magnitude of continental ice growth during this time.

Nanoscopic Templates from Oriented Block Copolymer Films

Abstract: cylindrical microdomains, an orientation normal to the substrate surface is desirable. Two different approaches are used to this end. In thin films, random copolymers anchored to a substrate can be used to produce a neutral surface. [5] For entropic reasons, the microdomains orient normal to the substrate surface. [6] In a second approach, electric fields were used to orient the cylindrical microdomains parallel to the field lines. [7‐10] The approach relies on the orientation-dependent polarization energy induced when an anisotropic body is placed in an electric field. An anisotropic microphase structure will orient such that the interfaces between the two blocks are aligned parallel to the electric field. In this article it is shown that cylindrical microdomains of a copolymer film can be used to generate an array of ordered nanoscopic pores with well-controlled size, orientation, and structure. To this end, selective etching procedures and a characterization of the samples by quantitative analysis of the X-ray scattering along with electron (EM) and atomic force microscopies (AFM) are described. The processes outlined are shown to be operative over a very large range in sample thickness ranging from 40 nm up to several micrometers. The resulting nanoporous films are promising candidates as membranes with specific transport properties and as templates for electronic and magnetic nanostructured materials. Figures 1A and 1B show AFM images obtained from a

Soil moisture mapping at regional scales using microwave radiometry: the Southern Great Plains Hydrology Experiment

Abstract: Surface soil moisture retrieval algorithms based on passive microwave observations, developed and verified at high spatial resolution, were evaluated in a regional scale experiment. Using previous investigations as a base, the Southern Great Plains Hydrology Experiment (SGP97) was designed and conducted to extend the algorithm to coarser resolutions, larger regions with more diverse conditions, and longer time periods. The L-band electronically scanned thinned array radiometer (ESTAR) was used for daily mapping of surface soil moisture over an area greater than 10000 km/sup 2/ for a one month period. Results show that the soil moisture retrieval algorithm performed the same as in previous investigations, demonstrating consistency of both the retrieval and the instrument. Error levels were on the order of 3% for area Integrated averages of sites used for validation. This result showed that for the coarser resolution used that the theory and techniques employed in the algorithm apply at this scale. Spatial patterns observed in the Little Washita Watershed in previous investigations were also observed. These results showed that soil texture dominated the spatial pattern at this scale. However, the regional soil moisture patterns were a reflection of the spatially variable rainfall and soil texture patterns were not as obvious.

The “Lotus Effect” Explained: Two Reasons Why Two Length Scales of Topography Are Important

Abstract: Surfaces containing 4 × 8 × 40 μm staggered rhombus posts were hydrophobized using two methods. One, using a dimethyldichlorosilane reaction in the vapor phase, introduces a smooth modified layer, and the other, a solution reaction using methyltrichlorosilane, imparts a second (nanoscopic) length scale of topography. The smooth modified surface exhibits contact angles of θA/θR = 176°/156°. Arguments are made that the pinning of the receding contact line by the post tops (with θA/θR = 104°/103°) is responsible for the hysteresis. The second level of topography raises the contact angles of the post tops and the macroscopic sample to θA/θR = >176°/>176° and eliminates hysteresis. The increase in Laplace pressure due to the increase in the advancing contact angle of the post tops is a second reason that two length scales of topography are important.

Polyphasic taxonomy of the genus Shewanella and description of Shewanella oneidensis sp. nov

Abstract: The genus Shewanella has been studied since 1931 with regard to a variety of topics of relevance to both applied and environmental microbiology. Recent years have seen the introduction of a large number of new Shewanella-like isolates, necessitating a coordinated review of the genus. In this work, the phylogenetic relationships among known shewanellae were examined using a battery of morphological, physiological, molecular and chemotaxonomic characterizations. This polyphasic taxonomy takes into account all available phenotypic and genotypic data and integrates them into a consensus classification. Based on information generated from this study and obtained from the literature, a scheme for the identification of Shewanella species has been compiled. Key phenotypic characteristics were sulfur reduction and halophilicity. Fatty acid and quinone profiling were used to impart an additional layer of information. Molecular characterizations employing small-subunit 16S rDNA sequences were at the limits of resolution for the differentiation of species in some cases. As a result, DNA-DNA hybridization and sequence analyses of a more rapidly evolving molecule (gyrB gene) were performed. Species-specific PCR probes were designed for the gyrB gene and used for the rapid screening of closely related strains. With this polyphasic approach, in addition to the ten described Shewanella species, two new species, Shewanella oneidensis and 'Shewanella pealeana', were recognized; Shewanella oneidensis sp. nov. is described here for the first time.