University of New Hampshire

About: University of New Hampshire is a education organization based out in Durham, New Hampshire, United States. It is known for research contribution in the topics: Population & Solar wind. The organization has 9379 authors who have published 24025 publications receiving 1020112 citations. The organization is also known as: UNH.

Substituent effects in pentacenes: gaining control over HOMO-LUMO gaps and photooxidative resistances

Abstract: A combined experimental and computational study of a series of substituted pentacenes including halogenated, phenylated, silylethynylated and thiolated derivatives is presented. Experimental studies include the synthesis and characterization of six new and six known pentacene derivatives and a kinetic study of each derivative under identical photooxidative conditions. Structures, HOMO−LUMO energies and associated gaps were calculated at the B3LYP/6-311+G**//PM3 level while optical and electrochemical HOMO−LUMO gaps were measured experimentally. The combined results provide for the first time a quantitative assessment of HOMO−LUMO gaps and photooxidative resistances for a large series of pentacene derivatives as a function of substituents. The persistence of each pentacene derivative is impacted by a combination of steric resistance and electronic effects as well as the positional location of each substituent. Silylethynyl-substituted pentacenes like TIPS-pentacene possess small HOMO−LUMO gaps but are not ...

AERONET-OC: A Network for the Validation of Ocean Color Primary Products

Abstract: The ocean color component of the Aerosol Robotic Network (AERONET-OC) has been implemented to support long-term satellite ocean color investigations through cross-site consistent and accurate measurements collected by autonomous radiometer systems deployed on offshore fixed platforms. The AERONET-OC data products are the normalized water-leaving radiances determined at various center wavelengths in the visible and near-infrared spectral regions. These data complement atmospheric AERONET aerosol products, such as optical thickness, size distribution, single scattering albedo, and phase function. This work describes in detail this new AERONET component and its specific elements including measurement method, instrument calibration, processing scheme, quality assurance, uncertainties, data archive, and products accessibility. Additionally, the atmospheric and bio-optical features of the sites currently included in AERONET-OC are briefly summarized. After illustrating the application of AERONET-OC dat...

A regional perspective on trends in continental evaporation

Abstract: [1] Climate models suggest that enhanced greenhouse gas concentrations and aerosols have major impacts on the land energy and water cycles, and in particular on evapotranspiration (ET). Here we analyze how the main external drivers of ET (incident solar radiation and precipitation) vary regionally, using recent data from a eddy-covariance flux tower network (FLUXNET) and a multi-model re-analysis (GSWP-2). Trends in radiation (global “dimming” and “brightening”) are expected to impact ET only in regions where ET correlates with radiation. In central Europe this correlation is particularly strong, and trends derived from weighing lysimeters and river-basin water budgets follow trends in radiation. In central North America the correlation is weak, and trends in precipitation rather than radiation explain trends in ET. Our results reconcile previous hypotheses by demonstrating the strongly regional and temporal differentiation of trends in evaporation.

Eustatic Curve for the Middle Jurassic--Cretaceous Based on Russian Platform and Siberian Stratigraphy: Zonal Resolution

Abstract: We have used the stratigraphy of the central part of the Russian platform and surrounding regions to construct a calibrated eustatic curve for the Bajocian through the Santonian. The study area is centrally located in the large Eurasian continental craton, and was covered by shallow seas during much of the Jurassic and Cretaceous. The geographic setting was a very low-gradient ramp that was repeatedly flooded and exposed. Analysis of stratal geometry of the region suggests tectonic stability throughout most of Mesozoic marine deposition. The paleogeography of the region led to extremely low rates of sediment influx. As a result, accommodation potential was limited and is interpreted to have been determined primarily by eustatic variations. The central part of the Russian latform thus provides a useful frame of reference for the quantification of eustatic variations throughout the Jurassic and Cretaceous. The biostratigraphy of the Russian platform provides the basis for reliably determining age and eustatic events. The Mesozoic section of the central part of the Russian platform is characterized by numerous hiatuses. In this study, we filled the sediment gaps left by unconformities in the central part of the Russian platform with data from stratigraphic information from the more continuous stratigraphy of the neighboring subsiding regions, such as northern Siberia. Although these sections reflect subsidence, the time scale of variations in subsidence rate is probably long relative to the duration of the stratigraphic gaps to be filled, so the subsidence rate can be calculated and filtered from the stratigraphic data. We thus have compiled a more complete eustatic curve than would be p ssible on the basis of Russian platform stratigraphy alone. Relative sea level curves were generated by backstripping stratigraphic data from well and outcrop sections distributed throughout the central part of the Russian platform. For determining paleowater depth, we developed a model specifically designed for this region based on paleoecology, sedimentology, geochemistry, and paleogeography. The curve describes a series of high-frequency eustatic events superimposed on longer term trends. Many of the events identified from our study can be correlated to those found by Haq et al. (1988) and other sea level studies from other parts of the world, but there are significant differences in the relative magnitudes of events. Because the eustatic curve resulting from this study is based on a stable reference frame, the curve can be used in sedimentary basin modeling and as a tool for quantifying subsidence history from the stratigraphy of passive margins, basins, and other active regions.