Showing papers by "University of Nigeria, Nsukka published in 2021"

Exploring the impact of COVID-19 on tourism: transformational potential and implications for a sustainable recovery of the travel and leisure industry

Abstract: The study stipulates phases to observe the proposed mechanism in formulating the travel and leisure industry's recovery strategies. The present pandemic COVID-19 has resulted in global challenges, economic and healthcare crises, and posed spillover impacts on the global industries, including tourism and travel that the major contributor to the service industry worldwide. The tourism and leisure industry has faced the COVID-19 tourism impacts hardest-hit and lies among the most damaged global industries. The leisure and internal tourism indicated a steep decline amounting to 2.86 trillion US dollars, which quantified more than 50% revenue losses. In the first step, the study explores the consequences and settings of the COVID-19 pandemic and how innovation and change can contribute to the tourism industry's revival to the next normal. Thus, the study determines that tourism enterprises and scholars must consider and change the basic principles, main assumptions, and organizational situations related to research and practice framework through rebuilding and establishing the tourism sector. In the second step, the study discusses direct COVID-19 tourism impacts, attitudes, and practices in gaining the leisure industry's boom and recovery. In the third phase, the study proposes to observe the characteristics and COVID-19 tourism consequences on the travel and tourism research. The findings provide insights in regaining the tourism industry's operational activities and offer helpful suggestions to government officials, scholars, and tourism firms to reinvest in the tourism industry to set it back to a normal position.

Sustainable Development Goals relevant to kidney health: an update on progress.

Abstract: Globally, more than 5 million people die annually from lack of access to critical treatments for kidney disease — by 2040, chronic kidney disease is projected to be the fifth leading cause of death worldwide. Kidney diseases are particularly challenging to tackle because they are pathologically diverse and are often asymptomatic. As such, kidney disease is often diagnosed late, and the global burden of kidney disease continues to be underappreciated. When kidney disease is not detected and treated early, patient care requires specialized resources that drive up cost, place many people at risk of catastrophic health expenditure and pose high opportunity costs for health systems. Prevention of kidney disease is highly cost-effective but requires a multisectoral holistic approach. Each Sustainable Development Goal (SDG) has the potential to impact kidney disease risk or improve early diagnosis and treatment, and thus reduce the need for high-cost care. All countries have agreed to strive to achieve the SDGs, but progress is disjointed and uneven among and within countries. The six SDG Transformations framework can be used to examine SDGs with relevance to kidney health that require attention and reveal inter-linkages among the SDGs that should accelerate progress. Working towards sustainable development is essential to tackle the rise in the global burden of non-communicable diseases, including kidney disease. Five years after the Sustainable Development Goal agenda was set, this Review examines the progress thus far, highlighting future challenges and opportunities, and explores the implications for kidney disease.

Nanoparticles as therapeutic options for treating multidrug-resistant bacteria: research progress, challenges, and prospects

Abstract: Resistance to antimicrobial agents has been alarming in recent years and poses a huge public health threat globally according to the WHO. The increase in morbidity and mortality resulting from microbial infections has been attributed to the emergence of multidrug-resistant microbes. Associated with the increase in multidrug resistance is the lack of new and effective antimicrobials. This has led to global initiatives to identify novel and more effective antimicrobial agents in addition to discovering novel and effective drug delivery and targeting methods. The use of nanoparticles as novel biomaterials to fully achieve this feat is currently gaining global attention. Nanoparticles could become an indispensable viable therapeutic option for treating drug-resistant infections. Of all the nanoparticles, the metals and metal oxide nanoparticles appear to offer the most promise and have attracted tremendous interest from many researchers. Moreover, the use of nanomaterials in photothermal therapy has received considerable attention over the years. This review provides current insight on antimicrobial resistance as well as the mechanisms of nanoparticle antibacterial activity. It offers an in-depth review of all the recent findings in the use of nanomaterials as agents against multi-resistant pathogenic bacteria. Also, nanomaterials that can respond to light stimuli (photothermal therapy) to kill microbes and facilitate enhanced drug delivery and release are discussed. Moreover, the synergistic interactions of nanoparticles with antibiotics and other nanomaterials, microbial adaptation strategies to nanoparticles, current challenges, and future prospects were extensively discussed.

The influence of renewable energy use, human capital, and trade on environmental quality in South Africa: multiple structural breaks cointegration approach

Abstract: Recent economic and environmental literature suggests that the current state of energy use in South Africa amidst rapid growing population is unsustainable. Researchers in this area mostly focus on the effect of fossil energy use on carbon (CO2) emission, which represents only an aspect of environmental quality. In contrast, the current study evaluates the influence of renewable energy use, human capital, and trade on ecological footprint––a more comprehensive measure of environmental quality. To this end, the study employs multiple structural breaks cointegration tests (Maki cointegration tests), dynamic unrestricted error correction model through Autoregressive Distributed Lag (ARDL) model, and VECM Granger causality tests. The results of the Maki cointegration tests reveal the existence of a cointegration between the variables in all the models with evidence of multiple structural breaks. Further, the ARDL results divulge that an increase in renewable energy use, human capital, and trade improves environmental quality through a decrease in ecological footprint, while an increase in income stimulates ecological footprint. Moreover, causal relationship is found, running from all the variables to renewable energy and trade flow in the long run, while in the short run, economic growth causes ecological footprint. Trade is found to Granger-cause human capital, while human capital causes renewable energy. Additionally, human capital, renewable energy, and economic growth are predictors of trade. The study therefore recommends South African policymakers to consider the importance of renewable energy, human capital development, and trade as a policy option to reduce ecological footprint and improve environmental quality.

Bio-based flocculants for sustainable harvesting of microalgae for biofuel production. A review

Abstract: Energy is indispensable to human existence and sustains economic and individual activities globally. The rising environmental challenges of global warming and other climate changes due to increasing dependence on fossil fuels (coal, petroleum, natural gas) as the primary energy source requires innovation away from carbon-based fossil fuel sources. Hence, the development of renewable and low-emission energy sources becomes imperative to guarantee sustainable economic and human population growth and fuel security. In this context, microalgae biofuels are increasingly appreciated as viable alternative to fossil-based fuels because their biomass can be transformed into various clean fuel commodities such as biodiesel, biogas, and bioethanol in an environmentally-friendly and sustainable manner. However, high energy and financial costs of harvesting microalgal biomass for biofuel production constitute a substantial bottleneck in the industry. Bio-based flocculation methods have recently received increased research attention due to their high efficiency, sustainability, and environmentally-friendly attributes. In this review, the feasibility and performance of bio-based technologies for large-scale, cost-effective and sustainable harvesting of microalgal biomass for biofuel production were evaluated. The review shows that the harvesting efficiencies of bio-based processes are not significantly different from those achieved with energy-intensive traditional biomass separation methods such as centrifugation and membrane filtration. Harvested biomass met the moisture content metrics for biofuel feedstocks. The utilization of natural coagulants in algal biomass recovery is associated with low energy consumption, low environmental impacts and reduced effect on the chemistry of recycled medium. Production of recombinant bioflocculants are emerging but the application in algal biomass harvesting is yet to be reported. Bioflocculation approaches provide opportunities for the integration of photosynthetic biorefineries with bioremediation of wastewaters, and this enhances the potential of microalgae biotechnology for biofuel production.

Toxicity of Nanoparticles in Biomedical Application: Nanotoxicology.

Abstract: Nanoparticles are of great importance in development and research because of their application in industries and biomedicine. The development of nanoparticles requires proper knowledge of their fabrication, interaction, release, distribution, target, compatibility, and functions. This review presents a comprehensive update on nanoparticles' toxic effects, the factors underlying their toxicity, and the mechanisms by which toxicity is induced. Recent studies have found that nanoparticles may cause serious health effects when exposed to the body through ingestion, inhalation, and skin contact without caution. The extent to which toxicity is induced depends on some properties, including the nature and size of the nanoparticle, the surface area, shape, aspect ratio, surface coating, crystallinity, dissolution, and agglomeration. In all, the general mechanisms by which it causes toxicity lie on its capability to initiate the formation of reactive species, cytotoxicity, genotoxicity, and neurotoxicity, among others.

Bioactive Compounds Effective Against Type 2 Diabetes Mellitus: A Systematic Review

Abstract: BACKGROUND Type 2 diabetes (adult onset diabetes) is the most common type of diabetes, accounting for around 90% of all diabetes cases with insulin resistance and insulin secretion defect. The key goal of anti-diabetic therapy is to increase the development of insulin, immunity and/or decrease the amount of blood glucose. While many synthetic compounds have been produced as antidiabetic agents, due to their side effects and limited effectiveness, their usefulness has been hindered. METHODS This systematic review investigated the bioactive compounds reported to possess activities against type 2 diabetes. Three (3) databases, PubMed, ScienceDirect and Google Scholar were searched for research articles published between January 2010 and October 2020. A total of 6464 articles were identified out of which 84 articles were identified to be elligible for the study. RESULT AND DISCUSSION From the data extracted, it was found that quercetin, Kaempferol, Rosmarinic acid, Cyanidin, Rutin, Catechin, Luteolin and Ellagic acid were the most cited bioactive compounds which all falls within the class of polyphenolic compounds. The major sources of these bioactive compounds includes citrus fruits, grapes, onions, berries, cherries, broccoli, honey, apples, green tea, Ginkgo biloba, St. John's wort, green beans, cucumber, spinach, tea, Rosmarinus officinalis, Aloe vera, Moringa oleifera, tomatoes, potatoes, oregano, lemon balm, thyme, peppermint, Ocimum basilicum, red cabbage, pears, olive oil and walnut.

Trends in the development and utilization of agricultural wastes as heterogeneous catalyst for biodiesel production

Abstract: Biodiesel is unarguably one of the most considered substitutes for fossil-based liquid fuels. However, the high cost of biodiesel production has been a major inhibitor for its large-scale activity. Apart from the cost of feedstock, catalysts contribute to the high pump price of biodiesel. Wastes derived from agricultural sources have been seen as viable means of synthesizing cost-effective and environmentally friendly catalysts and is an appropriate disposal of wastes. In this study recent trends in converting and utilizing agricultural wastes as heterogeneous catalysts for biodiesel production were reviewed. Agricultural wastes classifications, types of catalysts for biodiesel production, and the effects of conversion and modification techniques on pore size, acidity, surface area, and other fingerprints that enhance the catalytic activity were discussed. The use of characterization methods to test the suitability of solid catalysts was analysed, and some published works on the use of some agricultural wastes-derived catalysts were scrutinized. The paper concludes that catalysts derived from agricultural wastes offer a cheap, readily available, easy to produce, and environmentally benign replacement for the imported commercial ones. Going forward, more target investigations are needed on the suitability of some unexplored agricultural wastes to convert them to green catalysts. Researchers should explore the use of optimization models and statistical tools to determine the appropriate conditions for effective performance of biofuels.

Affective Interpersonal Touch in Close Relationships: A Cross-Cultural Perspective.

Abstract: Interpersonal touch behavior differs across cultures, yet no study to date has systematically tested for cultural variation in affective touch, nor examined the factors that might account for this variability. Here, over 14,000 individuals from 45 countries were asked whether they embraced, stroked, kissed, or hugged their partner, friends, and youngest child during the week preceding the study. We then examined a range of hypothesized individual-level factors (sex, age, parasitic history, conservatism, religiosity, and preferred interpersonal distance) and cultural-level factors (regional temperature, parasite stress, regional conservatism, collectivism, and religiosity) in predicting these affective-touching behaviors. Our results indicate that affective touch was most prevalent in relationships with partners and children, and its diversity was relatively higher in warmer, less conservative, and religious countries, and among younger, female, and liberal people. This research allows for a broad and integrated view of the bases of cross-cultural variability in affective touch.

Negative emotions about climate change are related to insomnia symptoms and mental health: Cross-sectional evidence from 25 countries

Abstract: Climate change threatens mental health via increasing exposure to the social and economic disruptions created by extreme weather and large-scale climatic events, as well as through the anxiety associated with recognising the existential threat posed by the climate crisis. Considering the growing levels of climate change awareness across the world, negative emotions like anxiety and worry about climate-related risks are a potentially pervasive conduit for the adverse impacts of climate change on mental health. In this study, we examined how negative climate-related emotions relate to sleep and mental health among a diverse non-representative sample of individuals recruited from 25 countries, as well as a Norwegian nationally-representative sample. Overall, we found that negative climate-related emotions are positively associated with insomnia symptoms and negatively related to self-rated mental health in most countries. Our findings suggest that climate-related psychological stressors are significantly linked with mental health in many countries and draw attention to the need for cross-disciplinary research aimed at achieving rigorous empirical assessments of the unique challenge posed to mental health by negative emotional responses to climate change.

Effects of tourism, financial development, and renewable energy on environmental performance in EU-28: does institutional quality matter?

Abstract: Institutional quality largely influences the ways in which economic agents align their production and operational behaviors towards expanding the share of renewable energy in the total energy mix and enhancing environmental performance. This study therefore explores the panel data for the EU-28 countries to assess the dynamic effects of institutional quality, tourism development, financial development, and renewable energy on environmental performance over the period 2002 to 2014. Using a two-step dynamic system generalized method of moments (GMM), the empirical results broadly suggest that institutional quality can be explored to dampen the potential negative effects of tourism and economic growth on environmental performance. In addition, financial development and renewable energy are positively related to environmental performance. This suggests that financial stability and energy consumption transition to renewable energy are necessary requirements to improve environmental performance. The policy implication for this study is that strengthening of institutional quality, financial stability, and adjusting to alternative and clean energy systems are the surest ways to achieve a cleaner and sustainable environment in the EU region.

Application of 3-algorithm ANN programming to predict the strength performance of hydrated-lime activated rice husk ash treated soil

Abstract: Artificial neural network (ANN) method has been applied in the present work to predict the California bearing ratio (CBR), unconfined compressive strength (UCS), and resistance value (R) of expansive soil treated with recycled and activated composites of rice husk ash. Pavement foundations suffer from poor design and construction, poor material handling and utilization and management lapses. The evolutions of soft computing techniques have produced various algorithms developed to overcome certain lapses in performance. Three of such algorithms from ANN are Levenberg–Muarquardt Backpropagation (LMBP), Bayesian Programming (BP), and Conjugate Gradient (CG) algorithms. In this work, the expansive soil classified as A-7-6 group soil was treated with hydrated-lime activated rice husk ash (HARHA) in varying proportions between 0.1 and 12% by weight of soil at the rate of 0.1% to produce 121 datasets. These were used to predict the behavior of the soil’s strength parameters (CBR, UCS and R) utilizing the evolutionary hybrid algorithms of ANN. The predictor parameters were HARHA, liquid limit (wL), (plastic limit (wP), plasticity index (IP), optimum moisture content (wOMC), clay activity (AC), and (maximum dry density (δmax). A multiple linear regression (MLR) was also conducted on the datasets in addition to ANN to serve as a check and linear validation mechanism. MLR and ANN methods agreed in terms of performance and fit at the end of computing and iteration. However, the response validation on the predicted models showed a good correlation above 0.9 and a great performance index. Comparatively, the LMBP algorithm yielded an accurate estimation of the results in lesser iterations than the Bayesian and the CG algorithms, while the Bayesian technique produced the best result with the required number of iterations to minimize the error. And finally, the LMBP algorithm outclassed the other two algorithms in terms of the predicted models’ accuracy.

Bioaccessibility of bioactive peptides: recent advances and perspectives

Abstract: Food-derived bioactive peptides are gaining popularity for their vast amount of potential health benefits against diseases such as obesity, hypertension, type 2 diabetes, and many more. However, many of these bioactivities are demonstrated using in vitro models, which do not completely reflect the true conditions that peptides experience upon oral ingestion. Furthermore, results obtained from in vivo studies are not entirely reproducible in other in vivo models due to systemic physiological differences. This review discusses the different bioaccessibility challenges, such as gastrointestinal tract hydrolysis by proteases, food matrix interactions, and intestinal barrier interaction that must be considered when developing peptide-based nutraceuticals or functional foods. The paper also discusses the potential avenues for improving bioaccessibility of bioactive peptides, amongst other factors that should be considered, during the design and production phases.

Effect of learning management system on Student’s performance in educational measurement and evaluation

Abstract: This study determined the effect of Learning Management system (LMS) on students performance in educational measurement and evaluation course. A non-equivalent group quasi experimental research design was adopted for the study, using a population of all the undergraduate students in Imo State University, Nigeria. A sample of 232 students was purposively selected comprising of 109 males and 123 females. An instrument titled “Measurement and evaluation Achievement Test (MEAT)” was used for data collection. The internal consistency reliability of the items of the MEAT was estimated to be 0.88 using Kuder-Richardson formula (K-R20) method, while the estimated temporal stability was obtained to be 0.89 using Pearson Product-moment correlation. The Data collected were analyzed using mean and standard deviation to answer the research questions while analysis of co-variance (ANCOVA) was used to test the null hypotheses. The findings of the study revealed that students taught using LMS (Moodle) performed better than those exposed to the CAI4ME Package. It was equally revealed that female students performed better than the males in both the two approaches although the male students recorded a higher gain score. Based on the findings, the researchers recommend that, LMS Packages such as Moodle should be learnt and used by lecturers of Educational Measurement and Evaluation.

Perceptions of the appropriate response to norm violation in 57 societies

Abstract: Norm enforcement may be important for resolving conflicts and promoting cooperation. However, little is known about how preferred responses to norm violations vary across cultures and across domains. In a preregistered study of 57 countries (using convenience samples of 22,863 students and non-students), we measured perceptions of the appropriateness of various responses to a violation of a cooperative norm and to atypical social behaviors. Our findings highlight both cultural universals and cultural variation. We find a universal negative relation between appropriateness ratings of norm violations and appropriateness ratings of responses in the form of confrontation, social ostracism and gossip. Moreover, we find the country variation in the appropriateness of sanctions to be consistent across different norm violations but not across different sanctions. Specifically, in those countries where use of physical confrontation and social ostracism is rated as less appropriate, gossip is rated as more appropriate.

Does economic growth, international trade and urbanization uphold environmental sustainability in sub-Saharan Africa? Insights from quantile and causality procedures

Abstract: International trade and urbanization are increasing at an unprecedented rate in sub-Saharan Africa (SSA). The region has also witnessed a fair share of economic growth, with minimal investment and consumption of renewables. Therefore, this study investigates the influence of economic growth, international trade, and urbanization on CO2 emissions in SSA. The current study enriches the existing literature by employing the panel quantile regression analysis to account for existing levels of CO2 emissions in the region. Empirical findings reveal that GDP increases CO2 emissions across quantiles, especially in countries where the existing level of CO2 emissions is low. International trade improves environmental sustainability in countries where the existing levels of CO2 emissions are at their lowest and highest levels but exacts a reversed impact on CO2 emissions at the median. Further findings suggest that urbanization increases CO2 emissions across the observed quantiles with a more pronounced effect in countries where the existing levels of CO2 emissions are at its lowest level. The study also reveals a bi-directional causality between economic growth, international trade, urbanization, and the emissions of CO2. The limitations of the study and possible direction for future research have been highlighted. Policy directions are discussed.

Adsorption of tartrazine and sunset yellow anionic dyes onto activated carbon derived from cassava sievate biomass

Abstract: The toxic effects of anionic dyes such as tartrazine and sunset yellow on humans and the aquatic environment are of serious concern. The need for the removal of these dyes from wastewaters led to the use of adsorption techniques as a cheap and efficient treatment method. Thus, this research was based on the preparation of a low-cost activated carbon derived from cassava sievate designated as CS, which was utilized in the adsorption of sunset yellow and tartrazine from simulated wastewater. The sorption process was carried out under varying process factors in a batch mode. Adsorbent characterization displayed the presence of surface functional groups by the FT-IR and a porous structure as revealed by scanning electron microscopy. Optimum dye uptake was recorded at pH (1.0–2.0), temperature (30–40 °C), CS dosage (0.1 g), and dye concentration (150 mg/L). A maximum CS monolayer uptake of 20.83 and 0.091 mg/g was recorded for tartrazine and sunset yellow dyes, respectively. The pseudo-second-order (R2 > 0.99) and Freundlich (R2 > 0.92) models were most fitted to the kinetics and isotherm data of the uptake of the dyes on CS. The adsorption equilibrium attainment was reached was within 90 min of dye sequestration. The experimental results revealed that both sunset yellow and tartrazine dyes were considerably adsorbed onto the environmentally compatible and low-cost activated carbon derived from cassava sievate.

Rational Emotive Occupational Health Coaching in the Management of Police Subjective Well-Being and Work Ability: a Case of Repeated Measures

Abstract: Low subjective well-being and work ability constitute threats to employees’ job performances across the world. Indices of low subjective well-being have been observed among police officers in Nigeria and have been linked to their occupational experiences. Managing enhanced subjective well-being is paramount for police officers’ job effectiveness. The current study investigated the effectiveness of rational emotive occupational health coaching (REOHC) in enhancing subjective well-being of police officers in Enugu state, Nigeria. Participants (N = 151) included police officers with not less than 5-year working experience who were randomly assigned to intervention (N = 76) and nonintervention (N = 75) groups. Participants in the intervention group were exposed to 120-min REOHC program weekly for a period of 16 weeks. Subjective well-being scale (SWBS) and perceived work ability index (PWAI) were used to collect data at pre-test, post-test, and follow-up assessments. Data collected were analyzed using independent samples as well as paired sample t test statistics and repeated measure ANOVA. Results revealed that participants in the intervention group had significant improvement in their life satisfaction, affect balance, and flourishing scores at post-test and follow-up assessments compared with the pre-test. Participants in the nonintervention control group did not have a significant change in subjective well-being subscale scores across pre-test, post-test, and follow-up evaluations. The conclusion drawn was that REOHC can be effective in managing subjective well-being among police officers and employees who work under chronic stressful conditions.

One-pot synthesis of zinc oxide nanoparticles via chemical precipitation for bromophenol blue adsorption and the antifungal activity against filamentous fungi.

Abstract: In this research, zinc oxide nanoparticles (ZnONPs) were prepared via a facile one-pot chemical precipitation approach and applied in the adsorption of bromophenol blue (BRB) and as antifungal agents against the filamentous fungi and plant pathogens; Alternaria alternata CGJM3078, Alternaria alternata CGJM3006 and Fusarium verticilliodes CGJM3823. The ZnONPs were characterized by the UV–Vis, FTIR, XRD, TGA, BET, SEM, TEM, and EDX techniques, which showed efficient synthesis. The characteristics ZnO UV–Vis absorption band was observed at 375 nm, while the XRD showed an average ZnONPs crystalline size of 47.2 nm. The SEM and TEM images showed an irregular shaped and aggregated porous structure of 65.3 nm average-sized ZnONPs. The TGA showed 22.9% weight loss at 800 °C indicating the high thermal stability of ZnONPs, while BET analysis revealed a surface area, pore volume and pore diameter of 9.259 m2/g, 0.03745 cm3/g and 9.87 nm respectively. The Freundlich, pseudo-second-order, and intra-particle diffusion models showed R2 > 0.9494 and SSE A. alternata CGJM3078 (range from 22.73 to 30.63 mm) in comparison to Bleach 5% (positive control). Additionally a model was proposed based on the possible underlying mechanisms for the antifungal effect. This research demonstrated the potent use of ZnONPs for the adsorption of BRB and as effective antifungal agents.

Trend Analysis and Variability of Air Temperature and Rainfall in Regional River Basins

Abstract: Global warming and climate variability are emerging as the foremost environmental problems in the 21 st century, especially in developing countries. Full knowledge of key climate change variables is crucial in managing water resources in river basins. This study examines the variability of air temperature and rainfall in the five states of South-Eastern region of Nigeria, using the trend analysis approach. For this purpose, temporal trends in annual rainfall and temperature were detected using non-parametric Mann-Kendall test at 5% significance level. The time series rainfall and temperature data for the period 1922-2008 were analyzed statistically for each state separately. The results of Mann Kendall test showed that there is trend in rainfall in all the capital cities in South-East except Owerri and Awka. It is also observed that the trend of rainfall is decreasing for all the study areas in South-East with the lowest trend rate of -0.1153 mm rainfall occurring in Umuahia. In the case of air temperature, it is observed that the trend is increasing for all the study areas in South-East with the highest trend rate of 0.04698 o C/year occurring in Enugu. These findings provide valuable information for assessing the influence of changes on air temperature and rainfall on water resources and references for water management in the South-Eastern river basin of Nigeria. It also proved that Mann-Kendall technique is an effective tool in analyzing temperature and rainfall trends in a regional watershed. Doi: 10.28991/cej-2021-03091692 Full Text: PDF

Facile synthesis and characterization of TiO 2 nanoparticles: X-ray peak profile analysis using Williamson–Hall and Debye–Scherrer methods

Abstract: In this study, TiO2 nanoparticles were synthesized by a sol–gel method involving the interaction of the titanium isopropoxide precursor and sodium hydroxide followed by calcination at a temperature of 450 °C. The effects of stirring time and solution pH on the morphology, phase types and crystallite sizes were investigated. The prepared TiO2 nanoparticles were characterized using X-ray diffraction analysis (XRD), high resolution scanning electron microscopy (HRSEM), high-resolution transmission electron microscopy (HRTEM), selective area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The HRSEM/HRTEM micrograph showed the formation of well distinct TiO2 nanoparticles with spherical shapes except at pH 2. FTIR spectroscopy showed the presence of the Ti–O stretching modes and Ti–O–Ti vibration modes in the samples. Crystallite size and lattice strain at peak broadening of TiO2 nanoparticles were studied using Williamson–Hall analysis and Scherrer’s equation. It was found that W–H crystallite sizes were significantly different from the sizes obtained from Scherrer’s equation at basic medium (pH 8–12) under the applied conditions of stirring time and solution pH for TiO2 nanoparticles. XRD pattern demonstrated the formation of pure anatase phase of TiO2 irrespective of the solution pH and stirring time. XPS analysis showed the existence of the Ti 2p orbital in the oxidation states of + 4. The study demonstrated that stirring time and solution pH determined the crystallite sizes and not the phase types.