University of Patras

About: University of Patras is a education organization based out in Pátrai, Greece. It is known for research contribution in the topics: Population & Catalysis. The organization has 13372 authors who have published 31263 publications receiving 677159 citations. The organization is also known as: Panepistímio Patrón.

A reaction engineering approach to the problem of concrete carbonation

Abstract: Steel bars in reinforced concrete are protected from corrosion by the high pH environment of the surrounding concrete This alkaline environment is destroyed by the reaction of atmospheric CO2 with the Ca(OH)2 of the concrete mass When this process, called carbonation of concrete, reaches the reinforcing bars, corrosion of the latter may commence In this paper, the physiochemical processes in this phenomenon are presented and modeled mathematically The mathematical model is fairly complex, but certain simplifying assumptions are possible, which lead to the formation of a “carbonation front” and to a simple analytical expression for the evolution in time of this front, in terms of the composition parameters of cement and concrete and of the environmental conditions This simple expression is in very good agreement with experimental results obtained in this and in previous studies The effect of some parameters on the carbonation front propagation is also discussed

Solar Light-Responsive Pt/CdS/TiO2 Photocatalysts for Hydrogen Production and Simultaneous Degradation of Inorganic or Organic Sacrificial Agents in Wastewater

Abstract: Photocatalytic degradation of waste material in aqueous solutions and simultaneous production of hydrogen was studied with the double purpose of environmental remediation and renewable energy production. Both powdered and immobilized Pt/CdS/TiO(2) photocatalysts were used to oxidize model inorganic (S(2-)/SO(3)(2-)) and organic (ethanol) sacrificial agents/pollutants in water. Powdered Pt/CdS/TiO(2) photocatalysts of variable CdS content (0-100%) were synthesized by precipitation of CdS nanoparticles on TiO(2) (Degussa P25) followed by deposition of Pt (0.5 wt %) and were characterized with BET, XRD, and DRS. Immobilized photocatalysts were deposited either on plain glass slides or on transparent conductive fluorine-doped SnO(2) electrodes. The results show that it is possible to produce hydrogen efficiently (20% quantum efficiency at 470 nm) by using simulated solar light and by photocatalytically consuming either inorganic or organic substances. CdS-rich photocatalysts are more efficient for the photodegradation of inorganics, while TiO(2)-rich materials are more effective for the photodegradation of organic substances.

Physics at a future Neutrino Factory and super-beam facility

Abstract: The conclusions of the Physics Working Group of the International Scoping Study of a future Neutrino Factory and super-beam facility (the ISS) are presented. The ISS was carried out by the international community between NuFact05, (the 7th International Workshop on Neutrino Factories and Super-beams, Laboratori Nazionali di Frascati, Rome, 21–26 June 2005) and NuFact06 (Ivine, CA, 24–30 August 2006). The physics case for an extensive experimental programme to understand the properties of the neutrino is presented and the role of high-precision measurements of neutrino oscillations within this programme is discussed in detail. The performance of second-generation super-beam experiments, beta-beam facilities and the Neutrino Factory are evaluated and a quantitative comparison of the discovery potential of the three classes of facility is presented. High-precision studies of the properties of the muon are complementary to the study of neutrino oscillations. The Neutrino Factory has the potential to provide extremely intense muon beams and the physics potential of such beams is discussed in the final section of the report.