University of Rennes

About: University of Rennes is a education organization based out in Rennes, France. It is known for research contribution in the topics: Population & Catalysis. The organization has 18404 authors who have published 40374 publications receiving 995327 citations.

Unsupervised classification of multifrequency and fully polarimetric SAR images based on the H/A/Alpha-Wishart classifier

Abstract: Introduces a new classification scheme for dual frequency polarimetric SAR data sets. A (6/spl times/6) polarimetric coherency matrix is defined to simultaneously take into account the full polarimetric information from both images. This matrix is composed of the two coherency matrices and their cross-correlation. A decomposition theorem is applied to both images to obtain 64 initial clusters based on their scattering characteristics. The data sets are then classified by an iterative algorithm based on a complex Wishart density function of the 6/spl times/6 matrix. A class number reduction technique is then applied on the 64 resulting clusters to improve the efficiency of the interpretation and representation of each class. An alternative technique is also proposed which introduces the polarimetric cross-correlation information to refine the results of classification to a small number of clusters using the conditional probability of the cross-correlation matrix. These classification schemes are applied to full polarimetric P, L, and C-band SAR images of the Nezer Forest, France, acquired by the NASA/JPL AIRSAR sensor in 1989.

Charge instability in quadrupolar chromophores: symmetry breaking and solvatochromism.

Abstract: We present a joint theoretical and experimental work aimed to understand the spectroscopic behavior of multipolar dyes of interest for nonlinear optics (NLO) applications. In particular, we focus on the occurrence of broken-symmetry states in quadrupolar organic dyes and their spectroscopic consequences. To gain a unified description, we have developed a model based on a few-state description of the charge-transfer processes characterizing the low-energy physics of these systems. The model takes into account the coupling between electrons and slow degrees of freedom, namely, molecular vibrations and polar solvation coordinates. We predict the occurrence of symmetry breaking in either the ground or first excited state. In this respect, quadrupolar chromophores are classified in three different classes, with distinctively different spectroscopic behavior. Cases of true and false symmetry breaking are discriminated and discussed by making resort to nonadiabatic calculations. The theoretical model is applied to three representative quadrupolar chromophores: their qualitatively different solvatochromic properties are connected to the presence or absence of broken-symmetry states and related to two-photon absorption (TPA) cross-sections. The proposed approach provides useful guidelines for the synthesis of dyes for TPA application and represents a general and unifying reference frame to understand energy-transfer processes in multipolar molecular systems, offering important clues to understand basic properties of materials of interest for NLO and energy-harvesting applications.