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Showing papers by "University of Science and Technology Beijing published in 1994"


Journal ArticleDOI
TL;DR: In this article, a method for estimating critical temperatures (Tb) of thermal explosion for energetic materials is derived from Semenov's thermal explosion theory and the non-isothermal kinetic equation dα/dt = Af(α)e−E/RT using reasonable hypotheses.

293 citations


Journal ArticleDOI
TL;DR: In this article, the hydrophobic adhesion force of fine hematite, siderite, and rhodochrosite particles was measured using the slope method and the results revealed that this flocculation cannot be interpreted by classical DLVO theory.

66 citations


Journal ArticleDOI
TL;DR: In this article, the structure and orientation of graphite platelets in graphite spherulites (GS) in cast irons modified by either cerium or magnesium plus cerium were investigated by TEM and micro-diffraction.
Abstract: The structure and orientation of graphite platelets in graphite spherulites (GS) in cast irons modified by either cerium or magnesium plus cerium were investigated by TEM and micro-diffraction. The platelets have a rhombohedral structure with their [001] directions nearly parallel to the radius of the GS, but each platelet is twisted about 2 ° over a 1 μm length. Randomly orientated graphite is located in the interplatelet areas, in which most of the graphite has a hexagonal structure rather than rhombohedral structure. Based on the crystallographic characterization of the graphite and the cerium and magnesium elemental distribution in the GS, the model for the growth of GS as originally proposed by Double and Hellawell is re-examined.

61 citations


Journal ArticleDOI
TL;DR: In this article, it is shown that the selection of the abrasive waterjet cutting parameters for a required depth of cut in the given material can be effectively done by applying the principles of the fuzzy set theory.
Abstract: Currently, the abrasive waterjet cutting parameters for the milling operation have to be determined by a combination of prior experience and trial and error. It is shown that the selection of the abrasive waterjet cutting parameters for a required depth of cut in the given material can be effectively done by applying the principles of the fuzzy set theory. This approach will eliminate the need for extensive experimental work in order to select the magnitudes of the most influential abrasive waterjet parameters on the depth of cut. Fuzzy logic provides a methodology and imitation of a human's way of making decisions which is very useful in such applications where the mathematical model of the process does not exist, and one of such processes is indeed abrasive waterjet cutting. A number of case studies are performed to verify the validity of the proposed methodology for selecting the abrasive waterjet cutting parameters in order to achieve the predetermined depth of cut.

48 citations


Journal ArticleDOI
TL;DR: In this article, the effect of anodic and cathodic polarizations on the ambient creep of brass in 3.5% NaCl and CH3COOH + CH3COONa solutions has been investigated.

36 citations


Journal ArticleDOI
TL;DR: In this paper, a general and exact solution of inverse lattice problems in physics for simple cubic (sc), fcc and binary structures is presented based on a three-dimensional Mobius inversion formula, which is unexpectedly concise and easy.

33 citations


Journal ArticleDOI
TL;DR: In this paper, a pinning mechanism of a stress field has been proposed in high-Tc superconductors, where the authors focus on the interaction between magnetic flux and lattice mismatch induced by substitution of Ho for Y in YBa2Cu3O7−δ.
Abstract: A pinning mechanism of a stress field has been proposed in high-Tc superconductors. The studies focus on the interaction between magnetic flux and lattice mismatch induced by substitution of Ho for Y in YBa2Cu3O7−δ. By establishing an effective defect model, the stress distribution, centered on the substitutional dopant Ho, is briefly described. Moreover, a calculation on the pinning strength has been performed for the flux lines in such a stress field. The calculated result further demonstrates that rare-earth dopants for Y can become the effective pinning centers under the appropriate doping level.

30 citations


Journal ArticleDOI
TL;DR: In this article, slow strain rate tests were conducted in solutions of HCl + NaCl at ambient temperature on type 304 (UNS S30400) stainless steel weldments that exhibited a duplex ferrite-austenite structure in the weld fusion zone.
Abstract: Slow strain rate tests (SSRT) were conducted in solutions of hydrochloric acid (HCl) + sodium chloride (NaCl) at ambient temperature on type 304 (UNS S30400) stainless steel (SS) weldments that exhibited a duplex ferrite-austenite structure in the weld fusion zone. Results indicated the weld fusion zone corroded preferentially. Stress corrosion cracking (SCC) initiated and propagated along the ferrite-austenite interphase. Austenitic dendrite was observed by scanning electron microscopy (SEM) in the fracture surface morphology. This interfacial cracking was attributed to the formation of a complex cell structure consisting of weld fusion zone/parent metal with delta-ferrite/austenite in the weld zone. The delta-ferrite was microanodic phase. The proposed model of SCC for type 304 SS weldments in HCl + NaCl was film formation-slip (film rupture)-dissolution-crack propagation. Because of the presence of the complex cell structure, the surface film was nonuniform, which was favorable for crack initi...

22 citations


Journal ArticleDOI
TL;DR: The subsolidus phase relations of Nd2O3-SrO-CuO ternary system sintered in air at 950-1000-degrees-C have been investigated by X-ray powder diffraction.

22 citations


Journal ArticleDOI
TL;DR: In this paper, a rapid quenching technique was used to improve the electrode durability of a hydride-forming compound, LaNi 4.5 Mn 0.5, by using X-Ray diffraction energy-dispersive X-ray analysis.

22 citations


Journal ArticleDOI
TL;DR: In this article, a series of TiAl+Nb alloys with various Nb contents has been employed to explore the phase relationship and the development of microstructure, and the supercell reflection spots of L1(0) (TiAl) structure have been found in the alloy containing Nb up to 11 at.%.

Journal ArticleDOI
TL;DR: In this paper, Chen et al. used the Mobius inversion formulation corresponding to inequally weighted summations for solving some three-dimensional lattice problems to obtain the pair potentials for fcc and L12 structures.

Journal ArticleDOI
TL;DR: In this paper, a method was established that uses only two characteristic points of a single non-isothermal DSC curve, (d/dT) = 0 and (d2/DT2) = 1, from the classic isothermal kinetic equation dα/dt = Af(α)e−E/RT.

Journal ArticleDOI
TL;DR: Mossbauer spectroscopy and the positron annihilation technique have been used to investigate the structure of the amorphous phase of Fe73.5Cu1Nb3Si13.5B9 nanocrystalline alloy annealed at different temperatures as mentioned in this paper.

Journal ArticleDOI
TL;DR: In this article, the diffusion motion of a Brownian particle was investigated by both a friction force with memory effect and a noise, and the correlation effects of noise may bring about that the effective diffusion coefficient is dependent on both the displacement and time.
Abstract: We investigate the diffusion motion of a Brownian particle which is acted upon by both a friction force with memory effect and a noise. The noise is expressed as f(X, t) is similar to X-sigma F(t), sigma > 0, where X and t are the displacement and time, respectively, and F(t) has the long-time correlation effect [F(0) F(t)] is similar to t(-beta), 0 < beta < 1, beta = 1, 1 < beta < 2. The generalized Langevin equation, the corresponding Fokker-Planck equation and its solution at large time are established. A variety of anomalous diffusion patterns are proposed. The correlation effects of noise may bring about that the effective diffusion coefficient is dependent on both the displacement and time, and the probability density for finding the Brownian particle is a non-Gaussian distribution. O'Shaughnessy and Procaccia's results on the diffusion on fractals can be derived from our model.

Journal ArticleDOI
TL;DR: In this paper, the authors studied the possibility of initiating a micro-crack with nanometer size in the DFZ of the ductile materials and to clarify how a microcrack transforms into a void through an in-situ tensile test.
Abstract: The in-situ tensile test in a transmission electron microscope (TEM) is a powerful method for studying the mechanism of the initiation and propagation of microcracking and voiding in ductile fracture For fcc materials, it is generally recognized that voids or microcracks with a length of a micrometer initiate and grow through the thinning of a thin zone resulting from multiple slip and link with the main crack resulting in a zig-zag crack propagation The microcracks reported here, however, were in fact voids with sizes from hundreds of nanometers to several micrometers Until now, there are no reports about the initiation of a microcrack with nanometer sizes, and blunting into a void with micrometer sizes Neither is it clear where and how a microcrack nucleates and changes into a void It has been generally accepted and there is a dislocation free zone (DFS) ahead of a crack tip, though the argument about it still persists The principle topics of this paper are to study the possibility of initiating a microcrack with nanometer size in the DFZ of the ductile materials and to clarify how a microcrack transforms into a void through an in-situ tensile test The ductile material used for thismore » investigation was a stable austenitic stainless steel of type 310« less

Journal ArticleDOI
TL;DR: In this paper, a relationship between the fracture appearance of materials and the fractal value of the fracture surface for ductile materials was established, where the authors showed a correlation between hydrogen-induced J{sub 1c} decrease and hydrogen decreases in fractal values of fracture surface.
Abstract: When the fracture appearance of materials can be considered as approximately fractal, a relationship between j{sub 1c} and fractal value of the fracture surface for ductile materials can be established The new theoretical formula is J{sub 1c} = ({sigma}{sub 0}/3)ln((4{sup (1{minus}D{sub F}{sup {minus}1})}{minus} 1)/12f{sub p})l{sub 0} where {sigma}{sub 0} is the tensile strength of the material, D{sub F} is the fractal value of the fracture surface, f{sub p} is the volume fraction of void initiating particles, l{sub 0} is the characteristic distance The formula shows that the higher the fractal value of the fracture surface, the larger the J{sub 1c} value There is a correlation between hydrogen-induced J{sub 1c} decrease and hydrogen decreases in the fractal value of the fracture surface, which is consistent with experimental observations

Journal ArticleDOI
TL;DR: In this paper, the prebainitic phenomenon in several copper alloys and ferrous alloys was investigated by means of internal friction measurement and composition analysis, and the possibility of bainite shear nucleation in solute atoms' depleted regions was pointed out.
Abstract: The prebainitic phenomenon in several copper alloys and ferrous alloys was investigated by means of internal friction measurement and composition analysis. The internal friction peaks of zinc or carbon atoms diffusion inβ brasses or in austenite of ferrous alloys, respectively, were related to the zinc or carbon-depleted region formation within the bainitic incubation period observed by composition analysis. The possibility of bainite shear nucleation in solute atoms’ depleted regions, formed by diffusing of solute atoms to a certain level, was pointed out.

Journal ArticleDOI
TL;DR: In this paper, the authors check the possibility of dislocation emissions, DFZ formation, and initiation and propagation of a micro-crack in the DFZ for the brittle material, e.g., Ti-24Al-11Nb or TiAl.
Abstract: Rice and Thomson assumed that the emissions of dislocation from a crack tip would lead to plastic blunting of the crack tip, and the materials were categorized as intrinsically cleavage if a condition for decohesion of the crystal plane ahead of the crack was reached before those for dislocation emission from the crack. For the ductile material, the TEM in-situ observation showed that a main crack tip might still be sharp after the dislocations had been emitted from the crack tip and the dislocation free zone (DFZ) had been formed; thus, the local stress near the crack tip in the DFZ was high enough to equal the cohesive strength, and then a microcrack with size of nanometers nucleated in the DFZ. The microcracks initiated in the DFZ would blunt into voids through the movement of the existing dislocation and/or those emanated from the crack tip and the nearby dislocation source. The discontinuous void resulting from the blunting of the microcracks in the DFZ would link with each other and with the main crack, resulting in ductile fracture. For brittle materials, the authors wonder whether the DFZ also exist and whether a microcrack with the size of nanometers nucleated preferably inmore » the DFZ. If such occurred, the microcrack initiated in the DFZ should propagate into a cleavage crack rather than blunt into void. The goal of the present work was to check the possibility of dislocation emissions, DFZ formation, and initiation and propagation of a microcrack in the DFZ for the brittle material. For the titanium aluminides, e.g., Ti-24Al-11Nb or TiAl, a brittle fracture occurred by slow stable crack growth characterized by a well-defined resistance curve, i.e., the resistance of the cleavage crack propagation increased with crack growth.« less

Journal ArticleDOI
Z. Fang1, Y. Wu1, R. Zhu1, B. Cao1, F. Xiao1 
TL;DR: In this article, a layer of Austrian type 304 (UNS S30400) stainless steel is susceptible to stress corrosion cracking in acidic chloride (Cl−) solutions at ambient temperature.
Abstract: Austenitic type 304 (UNS S30400) stainless steel is susceptible to stress corrosion cracking (SCC) in acidic chloride (Cl−) solutions at ambient temperature. In this study, a layer of adso...

Journal ArticleDOI
TL;DR: In this article, the non-equilibrium segregation of solutes to static grain boundary during cooling (quenching-induced segregation) and to moving grain boundary in recrystallization was studied.
Abstract: Mechanisms for the non-equilibrium segregation of solutes to static grain boundary during cooling (quenching-induced segregation) and to moving grain boundary during recrystallization (moving-induced segregation) are proposed. For quenching-induced segregation, in consideration of the local equilibrium among vacancies, solute atoms and vacancy-solute atom complexes, as well as the influence of equilibrium grain-boundary segregation, the theoretical dynamic formulae for this non-equilibrium segregation have been derived on the basis of the vacancy-dragging mechanism. Theoretical calculations have been carried out for the non-equilibrium segregation of boron to austenitic grain boundaries during isothermal holding and continuous cooling after heating at high temperature; the results agree well with those obtained from experiments. The model has also successfully explained the different behaviours of boron segregation during cooling in α-Fe and in γ-Fe. For moving-induced segregation, based on the interaction between dislocations and the moving boundaries during recrystallization, a dislocation relaxation and widening grain-boundary mechanism of solute segregation on moving boundaries is proposed. Applying this model, we have calculated the boron segregation on moving boundaries during recrystallization in Fe-3% Si alloy; the results of these calculations agree with experimental results.

Journal ArticleDOI
TL;DR: SrCe 0.95 Yb 0.05 O 3−a (SCYB) sinters were prepared, whose density was in the range of 95.8-96.5% of the theoretical value.

Journal ArticleDOI
01 Aug 1994-Polymer
TL;DR: In this article, the Williams-Landel-Ferry (WLF) empirical equation was used to describe the conductivity of a polymeric solid electrolyte with Na+ single-ionic conductivity.

Journal ArticleDOI
TL;DR: In this paper, the break-up of coagulates in the viscous subrange of turbulence was found to be consistent with a surface erosion mechanism through the calculation of criterion values for coagulate rupture.

Journal ArticleDOI
TL;DR: In this paper, the feasibility of an alternative process route for the improved recovery of niobium from Niobium lean ores from Baotou was investigated and two routes were investigated viz. (i) direct reduction of iron ore pellets in a rotary kiln and (ii) direct smelting of the iron ore concentrate in an electric arc furnace, the concentrate being fed through a hollow electrode.

Journal ArticleDOI
TL;DR: In this paper, high-temperature superconductors of the mercury-based system were synthesized under high temperature and high pressure, and measurements of resistance and DC magnetic susceptibility for the samples prepared at 20-35 kbar and 850-degrees-C for 1-3.5 h were obtained.
Abstract: High-temperature superconductors of the mercury-based system were synthesized under high temperature and high pressure. The measurements of resistance and DC magnetic susceptibility for the samples prepared at 20-35 kbar and 850-degrees-C for 1-3.5 h show that the as-synthesized sample (1) prepared at 20 kbar, 850-degrees-C for 1.5 h was a multiphase of Hg-1212 and Hg-1223 phases and showed superconducting transitions of both 132 and 120 K. The sample (2) prepared at 30 kbar, 850-degrees-C for 3.5 h has Hg-1212 as the major phase with only a small amount of impurity phase. The intergrowth of Hg-1212/Hg-1223 was found in the sample (1). The dependence of pressure on T(c) for the Hg-1212 and Hg-1223 phases, measured under hydrostatic pressure, shows that dT(c)/dp is 0.17 and 0.23 K/kbar, respectively, in the pressure range below 10 kbar.

Journal ArticleDOI
TL;DR: It is proved that, under almost the same conditions as Schmeichel and Hayes’s Theorem, namely, G is a 2-connected graph of ordern with δ(G) ≥ 7 for every pair of nonadjacent vertices andv, G has two edge-disjoint Hamiltonian cycles unlessG is one of the graphs in Fig. 2, and this conclusion is best possible.
Abstract: E. Schmeichel and D. Hayes showed that ifG is a 2-connected graph withd(u) +d(v)?n ?1 for every pair of nonadjacent vertices andv, then G has a Hamiltonian cycle unlessG is the graph of Fig. 2 (b). In this paper, it is proved that, under almost the same conditions as Schmeichel and Hayes's Theorem, namely,G is a 2-connected graph of ordern (n ? 40) with ?(G) ? 7 for every pair of nonadjacent vertices andv, G has two edge-disjoint Hamiltonian cycles unlessG is one of the graphs in Fig. 1 or Fig. 2, and this conclusion is best possible.

Journal ArticleDOI
TL;DR: In this paper, the variation of oxygen content with cation substitution for several types of high-T(c) copper oxide solid solutions has been analyzed in terms of both theoretical derivations and experiments.

Journal ArticleDOI
TL;DR: In this article, four alkaline earth metal salts of 3-nitro-1,2,4-triazol-5-one (NTO) have been prepared and characterized by using the presently available methods of infrared spectrometry, 13 C NMR, TG-DTG, elemental analysis, conductivity measurement and X-ray powder diffraction.

Journal ArticleDOI
TL;DR: In this paper, an ionic-crystal model of valleriite has been developed for determining the oxidation states of the major elements determined with the aid of X-ray photoelectron spectroscopy.