University of St Andrews

About: University of St Andrews is a education organization based out in St Andrews, Fife, United Kingdom. It is known for research contribution in the topics: Population & Laser. The organization has 16260 authors who have published 43364 publications receiving 1636072 citations. The organization is also known as: St Andrews University & University of St. Andrews.

Accretion during the Merger of Supermassive Black Holes

Abstract: We study the evolution of disk accretion during the merger of supermassive black hole binaries in galactic nuclei. In hierarchical galaxy formation models, the most common binaries are likely to arise from minor galactic mergers and have unequal-mass black holes. Once such a binary becomes embedded in an accretion disk at a separation of a ~ 0.1 pc, the merger proceeds in two distinct phases. During the first phase, the loss of orbital angular momentum to the gaseous disk shrinks the binary on a timescale of ~107 yr. The accretion rate onto the primary black hole is not increased, and can be substantially reduced, during this disk-driven migration. At smaller separations, gravitational radiation becomes the dominant angular momentum loss process, and any gas trapped inside the orbit of the secondary is driven inward by the inspiralling black hole. The implied accretion rate just prior to coalescence exceeds the Eddington limit, so the final merger is likely to occur within a common envelope formed from the disrupted inner disk and to be accompanied by high-velocity (~104 km s-1) outflows.

The interpretation of habitat preference metrics under use–availability designs

Abstract: Models of habitat preference are widely used to quantify animal–habitat relationships, to describe and predict differential space use by animals, and to identify habitat that is important to an animal (i.e. that is assumed to influence fitness). Quantifying habitat preference involves the statistical comparison of samples of habitat use and availability. Preference is therefore contingent upon both of these samples. The inferences that can be made from use versus availability designs are influenced by subjectivity in defining what is available to the animal, the problem of quantifying the accessibility of available resources and the framework in which preference is modelled. Here, we describe these issues, document the conditional nature of preference and establish the limits of inferences that can be drawn from these analyses. We argue that preference is not interpretable as reflecting the intrinsic behavioural motivations of the animal, that estimates of preference are not directly comparable among different samples of availability and that preference is not necessarily correlated with the value of habitat to the animal. We also suggest that preference is context-dependent and that functional responses in preference resulting from changing availability are expected. We conclude by describing advances in analytical methods that begin to resolve these issues.

Disruption of extended defects in solid oxide fuel cell anodes for methane oxidation.

Abstract: Point defects largely govern the electrochemical properties of oxides: at low defect concentrations, conductivity increases with concentration; however, at higher concentrations, defect-defect interactions start to dominate. Thus, in searching for electrochemically active materials for fuel cell anodes, high defect concentration is generally avoided. Here we describe an oxide anode formed from lanthanum-substituted strontium titanate (La-SrTiO3) in which we control the oxygen stoichiometry in order to break down the extended defect intergrowth regions and create phases with considerable disordered oxygen defects. We substitute Ti in these phases with Ga and Mn to induce redox activity and allow more flexible coordination. The material demonstrates impressive fuel cell performance using wet hydrogen at 950 degrees C. It is also important for fuel cell technology to achieve efficient electrode operation with different hydrocarbon fuels, although such fuels are more demanding than pure hydrogen. The best anode materials to date--Ni-YSZ (yttria-stabilized zirconia) cermets--suffer some disadvantages related to low tolerance to sulphur, carbon build-up when using hydrocarbon fuels (though device modifications and lower temperature operation can avoid this) and volume instability on redox cycling. Our anode material is very active for methane oxidation at high temperatures, with open circuit voltages in excess of 1.2 V. The materials design concept that we use here could lead to devices that enable more-efficient energy extraction from fossil fuels and carbon-neutral fuels.