University of Windsor

About: University of Windsor is a education organization based out in Windsor, Ontario, Canada. It is known for research contribution in the topics: Population & Argumentation theory. The organization has 10654 authors who have published 22307 publications receiving 435906 citations. The organization is also known as: UWindsor & Assumption University of Windsor.

Geochemical and petrological evidence for a suprasubduction zone origin of Neoarchean (ca. 2.5 Ga) peridotites, central orogenic belt, North China craton

Abstract: The 2.55–2.50 Ga Zunhua and Wutaishan belts within the central orogenic belt of the North China craton contain variably metamorphosed and deformed tectonic blocks of peridotites and amphibolites that occur in a sheared metasedimentary matrix. In the Zunhua belt, dunites comprise podiform chromitites with high and uniform Cr-numbers (88). Peridotites and associated picritic amphibolites are characterized by light rare earth element (LREE)–enriched patterns and negative high field strength element (HFSE: Nb, Zr, and Ti) anomalies. They have positive initial ϵ Hf values (+7.9 to +10.4), which are consistent with an extremely depleted mantle composition. Mass-balance calculations indicate that the composition of the 2.55 Ga mantle beneath the Zunhua belt was enriched in SiO 2 and FeO T compared to modern abyssal peridotites. These geochemical signatures are consistent with a suprasubduction zone geodynamic setting. Metasomatism of the subarc mantle by slab-derived hydrous melts and/or fluids at ca. 2.55 Ga is likely to have been the cause of the subduction zone geochemical signatures in peridotites of the Zunhua belt. In the Wutaishan belt, chromitite-hosting harzburgites and dunites display U-shaped rare earth element (REE) patterns and have high Mg-numbers (91.1–94.5). These geochemical characteristics are similar to those of Phanerozoic forearc peridotites. The dunites might have formed by dissolution of orthopyroxene in reactive melt channels, similar to those in modern ophiolites. However, they differ in detail, and they might be residues of Archean komatiites. Following the initiation of an intra-oceanic subduction zone, they were trapped as a forearc mantle wedge between the subducting slab and magmatic arc. Slab-derived hydrous melts infiltrating through the mantle wedge metasomatized the depleted mantle residue, resulting in U-shaped rare earth element (REE) patterns.

Dietary accumulation and metabolism of polybrominated diphenyl ethers by juvenile carp (Cyprinus carpio).

Abstract: Polybrominated diphenyl ethers (PBDEs) are hydrophobic organic contaminants with properties and nomenclature similar to polychlorinated biphenyls (PCBs). While much information is available on the bioaccumulation and pharamcokinetics of PCBs, little information is available on PBDEs. In this study, juvenile carp were exposed to a diet spiked with a cocktail of four BDE congeners (2,4,4'-tribromoDE [BDE 28], 2,2',4,4'-tetrabromoDE [BDE 47], 2,2',4,4',5-pentabromoDE [BDE 99], and 2,2',4,4',5,5'hexabromoDE [BDE 153]) for 60 d followed by a 40-d depuration period. As a positive control, three PCB congeners with similar log K(ow), values (2,2',5,5'-tetrachlorobiphenyl [PCB 52], 2,2',4,4', 5,5'-hexachlorobiphenyl [PCB 153], and 2,2',3,4,4',5,5'-heptachlorobiphenyl [PCB 180]) were included in the cocktail to compare their assimilation and fate with the model BDE congeners. Concentrations of BDEs and PCBs were monitored in whole-fish tissues and liver tissues over the duration of the experiment. In addition, blood serum samples were taken and pooled among replicates to determine if any phenolic metabolites of BDE and PCBs were formed. Rapid assimilation of BDE 47 was observed relative to all other BDE and PCB congeners, whereas apparently no accumulation of BDE 99 occurred over the course of the experiment. Assimilation efficiencies for BDE 47 suggest that approximately 100% of the BDE 47 exposure was absorbed by carp tissues after 60 d. However, based on the time course of BDE 47 assimilation, it is improbable that all BDE 47 was assimilated; more likely, production of BDE 47 in carp tissues occurred as a result of debromination of higher-brominated compounds, possibly BDE 99. The net assimilation efficiencies of BDE 28 and BDE 153 were also apparently low (20 and 4%, respectively) relative to the three PCBs (40% assimilated) examined in this study. The low assimilation efficiency and high depuration rates for BDEs suggest a higher potential for biotransformation. While all three PCB compounds displayed very similar assimilation and depuration rates, three of the four BDE compounds displayed significantly different assimilation rates among BDE congeners and relative to the PCBs. This study suggests that BDEs have significantly different fate dynamics relative to PCBs in wild carp and likely other species of fish.

Temporal change in genetic structure and effective population size in steelhead trout (Oncorhynchus mykiss).

Abstract: There is a wealth of published molecular population genetic studies, however, most do not include historic samples and thus implicitly assume temporal genetic stability. We tested for changes in genetic diversity and structure in three populations of steelhead trout (Oncorhynchus mykiss) from a northern British Columbia watershed using seven microsatellite loci over 40 years. We found little change in genetic diversity (mean allele numbers and observed and expected heterozygosity), despite large variation in the estimated numbers of steelhead returning to the watershed over the same time period. However, the temporal stability in genetic diversity is not reflected in population structure, which appears to be high among populations, yet significantly variable over time. The neighbour-joining tree showed that, overall, two of the populations (Zymoetz and Kispiox) clustered separately from the third (Babine); a finding which was not consistent with their geographical separation. The clustering pattern was also not temporally consistent. We used the temporal method to estimate the effective number of breeders (Nb ) for the three populations; our values (Nb = 17-102) were low for the large and presumed vigorous populations of steelhead trout sampled. The low Nb values were also not consistent with the generally high genetic diversity estimates, suggesting the possibility of intermittent gene flow among the three populations. The use of temporal analyses in population genetic samples should be a priority; first, to verify observed patterns in contemporary data, and second, to build a dataset of temporal analyses to allow generalizations to be made concerning temporal genetic stability and effective population size in natural populations.

Laser-induced breakdown spectroscopy (LIBS): an overview of recent progress and future potential for biomedical applications.

Abstract: The recent progress made in developing laser-induced breakdown spectroscopy (LIBS) has transformed LIBS from an elemental analysis technique to one that can be applied for the reagentless analysis of molecularly complex biological materials or clinical specimens. Rapid advances in the LIBS technology have spawned a growing number of recently published articles in peer-reviewed journals which have consistently demonstrated the capability of LIBS to rapidly detect, biochemically characterize and analyse, and/or accurately identify various biological, biomedical or clinical samples. These analyses are inherently real-time, require no sample preparation, and offer high sensitivity and specificity. This overview of the biomedical applications of LIBS is meant to summarize the research that has been performed to date, as well as to suggest to health care providers several possible specific future applications which, if successfully implemented, would be significantly beneficial to humankind.