University of Wisconsin-Madison

About: University of Wisconsin-Madison is a education organization based out in Madison, Wisconsin, United States. It is known for research contribution in the topics: Population & Gene. The organization has 108707 authors who have published 237594 publications receiving 11883575 citations.

Transaction Cost Analysis: Past, Present, and Future Applications

Abstract: Over the past decade, transaction cost analysis (TCA) has received considerable attention in the marketing literature. Marketing scholars have made important contributions in extending and refining...

Analysis of the geometry of the hydroxymethyl radical by the “different hybrids for different spins” natural bond orbital procedure

Abstract: We have carried out ab initio UHF/6-31G* calculations on the hydroxymethyl radical, CH 2 OH, and have found the equilibrium structure to be nearly planar with barriers to internal rotation occurring at staggered and eclipsed geometries, in good agreement with experiment. The electronic structure of the radical was analyzed via the “different hybrids for different spins” natural bond orbital (DHDS NBO) procedure, which finds separate Lewis structures for each of the spin systems. The α spin Lewis structure resembles that of the anion; the β spin Lewis structure resembles the corresponding cation. This simple picture, in conjunction with Bent's rule, allows one to understand the principal electronic factors which dictate the structure of the radical CH 2 group and its torsional and inversion potentials. Charge transfer between oxygen non-bonding orbitals and the empty radical orbital in the β spin system is the dominant interaction determining the torsional potential. Smaller hyperconjugative interactions in the α spin system resemble interactions in closed-shell molecules and directly oppose the effect of radical hyperconjugation, thus illustrating the central idea that open-shell potential energy features result from competition between the two different spin systems.

Managers as Initiators of Trust: An Exchange Relationship Framework for Understanding Managerial Trustworthy Behavior

Abstract: In many approaches to interpersonal and organizational trust, researchers focus on employees' perceptions that their managers are trustworthy. We turn the tables, however, and examine the antecedents of managerial trustworthy behavior and the challenge of initiating trust. Drawing on agency and social exchange theories, we present an exchange relationship framework that identifies organizational, relational, and individual factors that encourage or constrain managerial trustworthy behavior.