Institution
Vienna University of Technology
Education•Vienna, Austria•
About: Vienna University of Technology is a education organization based out in Vienna, Austria. It is known for research contribution in the topics: Laser & Context (language use). The organization has 16723 authors who have published 49341 publications receiving 1302168 citations.
Papers published on a yearly basis
Papers
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TL;DR: With the current ∼750-nm laser probe and ∼100-eV excitation, the transient recorder is capable of resolving atomic electron dynamics within the Bohr orbit time.
Abstract: In Bohr's model of the hydrogen atom, the electron takes about 150 attoseconds (1 as = 10(-18) s) to orbit around the proton, defining the characteristic timescale for dynamics in the electronic shell of atoms. Recording atomic transients in real time requires excitation and probing on this scale. The recent observation of single sub-femtosecond (1 fs = 10(-15) s) extreme ultraviolet (XUV) light pulses has stimulated the extension of techniques of femtochemistry into the attosecond regime. Here we demonstrate the generation and measurement of single 250-attosecond XUV pulses. We use these pulses to excite atoms, which in turn emit electrons. An intense, waveform-controlled, few cycle laser pulse obtains 'tomographic images' of the time-momentum distribution of the ejected electrons. Tomographic images of primary (photo)electrons yield accurate information of the duration and frequency sweep of the excitation pulse, whereas the same measurements on secondary (Auger) electrons will provide insight into the relaxation dynamics of the electronic shell following excitation. With the current approximately 750-nm laser probe and approximately 100-eV excitation, our transient recorder is capable of resolving atomic electron dynamics within the Bohr orbit time.
1,119 citations
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TL;DR: In this article, a review of the chemical aspects of the incorporation of inorganic building blocks such as silica networks, porous materials, metals, etc. into an organic polymeric matrix is presented.
1,100 citations
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University of New Mexico1, Los Alamos National Laboratory2, Novozymes3, University of Provence4, VTT Technical Research Centre of Finland5, Pacific Northwest National Laboratory6, Joint Genome Institute7, United States Department of Agriculture8, Vienna University of Technology9, Pontifical Catholic University of Chile10, Oregon State University11, Genencor12
TL;DR: This work assembled 89 scaffolds to generate 34 Mbp of nearly contiguous T. reesei genome sequence comprising 9,129 predicted gene models, providing a roadmap for constructing enhanced T.Reesei strains for industrial applications such as biofuel production.
Abstract: Trichoderma reesei is the main industrial source of cellulases and hemicellulases used to depolymerize biomass to simple sugars that are converted to chemical intermediates and biofuels, such as ethanol. We assembled 89 scaffolds (sets of ordered and oriented contigs) to generate 34 Mbp of nearly contiguous T. reesei genome sequence comprising 9,129 predicted gene models. Unexpectedly, considering the industrial utility and effectiveness of the carbohydrate-active enzymes of T. reesei, its genome encodes fewer cellulases and hemicellulases than any other sequenced fungus able to hydrolyze plant cell wall polysaccharides. Many T. reesei genes encoding carbohydrate-active enzymes are distributed nonrandomly in clusters that lie between regions of synteny with other Sordariomycetes. Numerous genes encoding biosynthetic pathways for secondary metabolites may promote survival of T. reesei in its competitive soil habitat, but genome analysis provided little mechanistic insight into its extraordinary capacity for protein secretion. Our analysis, coupled with the genome sequence data, provides a roadmap for constructing enhanced T. reesei strains for industrial applications such as biofuel production.
1,085 citations
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TL;DR: In this paper, the potential of using ERS scatterometer data for soil moisture monitoring over the Ukraine is investigated and a simple method is developed to relate the surface estimates with the profile soil moisture content.
1,072 citations
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TL;DR: The present review is devoted to summarizing the recent advances (2015–2017) in the field of metal-catalysed group-directed C–H functionalisation.
Abstract: The present review is devoted to summarizing the recent advances (2015-2017) in the field of metal-catalysed group-directed C-H functionalisation In order to clearly showcase the molecular diversity that can now be accessed by means of directed C-H functionalisation, the whole is organized following the directing groups installed on a substrate Its aim is to be a comprehensive reference work, where a specific directing group can be easily found, together with the transformations which have been carried out with it Hence, the primary format of this review is schemes accompanied with a concise explanatory text, in which the directing groups are ordered in sections according to their chemical structure The schemes feature typical substrates used, the products obtained as well as the required reaction conditions Importantly, each example is commented on with respect to the most important positive features and drawbacks, on aspects such as selectivity, substrate scope, reaction conditions, directing group removal, and greenness The targeted readership are both experts in the field of C-H functionalisation chemistry (to provide a comprehensive overview of the progress made in the last years) and, even more so, all organic chemists who want to introduce the C-H functionalisation way of thinking for a design of straightforward, efficient and step-economic synthetic routes towards molecules of interest to them Accordingly, this review should be of particular interest also for scientists from industrial R&D sector Hence, the overall goal of this review is to promote the application of C-H functionalisation reactions outside the research groups dedicated to method development and establishing it as a valuable reaction archetype in contemporary R&D, comparable to the role cross-coupling reactions play to date
1,057 citations
Authors
Showing all 16934 results
Name | H-index | Papers | Citations |
---|---|---|---|
Krzysztof Matyjaszewski | 169 | 1431 | 128585 |
Wolfgang Wagner | 156 | 2342 | 123391 |
Marco Zanetti | 145 | 1439 | 104610 |
Sridhara Dasu | 140 | 1675 | 103185 |
Duncan Carlsmith | 138 | 1660 | 103642 |
Ulrich Heintz | 136 | 1688 | 99829 |
Matthew Herndon | 133 | 1732 | 97466 |
Frank Würthwein | 133 | 1584 | 94613 |
Alain Hervé | 132 | 1279 | 87763 |
Manfred Jeitler | 132 | 1278 | 89645 |
David Taylor | 131 | 2469 | 93220 |
Roberto Covarelli | 131 | 1516 | 89981 |
Patricia McBride | 129 | 1230 | 81787 |
David Smith | 129 | 2184 | 100917 |
Lindsey Gray | 129 | 1170 | 81317 |