Waseda University

About: Waseda University is a education organization based out in Tokyo, Japan. It is known for research contribution in the topics: Large Hadron Collider & Catalysis. The organization has 24220 authors who have published 46859 publications receiving 837855 citations. The organization is also known as: Waseda daigaku & Sōdai.

Photoinhibition of photosystem I

Abstract: The photoinhibition of Photosystem I (PSI) drew less attention compared with that of Photosystem II (PSII). This could be ascribed to several reasons, e.g. limited combinations of plant species and environmental conditions that cause PSI photoinhibition, the non-regulatory aspect of PSI photoinhibition, and methodological difficulty to determine the accurate activity of PSI under stress conditions. However, the photoinhibition of PSI could be more dangerous than that of PSII because of the very slow recovery rate of PSI. This article is intended to introduce such characteristics of PSI photoinhibition with special emphasis on the relationship between two photosystems as well as the protective mechanism of PSI in vivo. Although the photoinhibition of PSI could be induced only in specific conditions and specific plant species in intact leaves, PSI itself is quite susceptible to photoinhibition in isolated thylakoid membranes. PSI seems to be well protected from photoinhibition in vivo in many plant species and many environmental conditions. This is quite understandable because photoinhibition of PSI is not only irreversible but also the potential cause of many secondary damages. This point would be different from the case of PSII photoinhibition, which could be regarded as one of the regulatory mechanisms under stressed as well as non-stressed conditions.

Cross-coupling of aromatic esters and amides

Abstract: Catalytic cross-coupling reactions of aromatic esters and amides have recently gained considerable attention from synthetic chemists as de novo and efficient synthetic methods to form C–C and C–heteroatom bonds. Esters and amides can be used as diversifiable groups in metal-catalyzed cross-coupling: in a decarbonylative manner, they can be utilized as leaving groups, whereas in a non-decarbonylative manner, they can form ketone derivatives. In this review, recent advances of this research topic are discussed.

Nanoarchitectures for Mesoporous Metals.

Abstract: The field of mesoporous metal nanoarchitectonics offers several advantages which cannot be found elsewhere. These materials have been showcasing impressive enhancements of their electrochemical properties for further implementation, compared to their micro- and macroporous counterparts. Since the last few decades, various methods have been developed to achieve narrow pore size distribution with a tunable porosity and particle morphology. While hard templates offer a reliable and intuitive approach to synthesize mesoporous metals, the complexity of the technique and the use of harmful chemicals pushed several research groups to focus in other directions. For example, soft templates (e.g., lyotropic crystals, micelles assemblies) and solution phase methods (requiring to control reduction reactions) offer more and more possibilities in terms of available compositions and morphologies. Indeed, various metal (Pt, Pd, Au, Ru, etc.) can now be synthesized as dendritic, core@shell, hollow or polyhedral nanoparticles, with single- or multicomponents, alloyed or not, with unprecedented electrochemical activity.

Scaling properties of azimuthal anisotropy in Au+Au and Cu+Cu collisions at sNN=200GeV

Abstract: Differential measurements of elliptic flow (v(2)) for Au+Au and Cu+Cu collisions at root s(NN)=200 GeV are used to test and validate predictions from perfect fluid hydrodynamics for scaling of v(2) with eccentricity, system size, and transverse kinetic energy (KET). For KET equivalent to m(T)-m up to similar to 1 GeV the scaling is compatible with hydrodynamic expansion of a thermalized fluid. For large values of KET mesons and baryons scale separately. Quark number scaling reveals a universal scaling of v(2) for both mesons and baryons over the full KET range for Au+Au. For Au+Au and Cu+Cu the scaling is more pronounced in terms of KET, rather than transverse momentum.