Wichita State University

About: Wichita State University is a education organization based out in Wichita, Kansas, United States. It is known for research contribution in the topics: Population & Poison control. The organization has 4988 authors who have published 9563 publications receiving 253824 citations. The organization is also known as: WSU & Fairmount College.

Control of Markovian jump discrete-time systems with norm bounded uncertainty and unknown delay

Abstract: This paper studies the problem of control for discrete time delay linear systems with Markovian jump parameters. The system under consideration is subjected to both time-varying norm-bounded parameter uncertainty and unknown time delay in the state, and Markovian jump parameters in all system matrices. We address the problem of robust state feedback control in which both robust stochastic stability and a prescribed H/sub /spl infin// performance are required to be achieved irrespective of the uncertainty and time delay. It is shown that the above problem can be solved if a set of coupled linear matrix inequalities has a solution.

Intermolecular and supramolecular photoinduced electron transfer processes of fullerene–porphyrin/phthalocyanine systems

Abstract: The attainment of a better understanding of the dependence of photoinduced electron transfer reaction rates on the molecular structures of the donor and acceptor entities results in improving the capture and storage of solar energy. Here, the intermolecular and supramolecular electron transfer processes from electron donors (porphyrins (P), chlorophylls (Chl), phthalocyanines (Pc) and naphthalocyanines (Nc)) and their metal derivatives to electron acceptors (fullerenes such as C 60 and C 70 ) studied by nanosecond and picosecond laser flash photolysis techniques in polar and nonpolar solvents are reviewed. For intermolecular systems in polar solvents, photoinduced electron transfer takes place via the excited triplet states of C 60 /C 70 or via the excited triplet states of P/Pc/Nc, yielding solvated radical ions in polar solvents; thus, the back electron transfer rates are generally slow. In the case of the supramolecular dyads and triads formed by axial coordination, hydrogen bonding, crown ether complexation, or rotaxane formation, the photoinduced charge separation takes place mainly from the excited singlet state of the donor; however, the back electron transfer rates are generally quite fast. The relations between structures and photochemical reactivities of these novel supramolecular systems are discussed in relation to the efficiency of charge separation and charge recombination.