Wichita State University

About: Wichita State University is a education organization based out in Wichita, Kansas, United States. It is known for research contribution in the topics: Population & Poison control. The organization has 4988 authors who have published 9563 publications receiving 253824 citations. The organization is also known as: WSU & Fairmount College.

Structural analysis of unpromoted Fe-based Fischer-Tropsch catalysts using X-ray absorption spectroscopy

Abstract: The structure of unpromoted precipitated Fe catalysts was determined by Mossbauer emission and X-ray absorption spectroscopies after use in the Fischer–Tropsch synthesis (FTS) reaction in well-mixed autoclave reactors for various periods of time. X-ray absorption near-edge spectroscopy (XANES), extended X-ray absorption fine structure (EXAFS) analysis, and Mossbauer spectroscopy showed consistent trends in the structural evolution of these catalysts during reaction. The nearly complete formation of Fe carbides during initial activation in CO was followed by their gradual re-oxidation to form Fe3O4 with increasing time-on-stream. Fe3O4 became the only detectable Fe compound after 450 h. The observed correlation between FTS rates and Fe carbide concentration, and the unexpected re-oxidation of the catalysts as CO conversion decreased, suggest that the deactivation of Fe catalysts in FTS reactions parallels the conversion of Fe carbides to Fe3O4. It appears that the CO activation steps responsible for replenishing carbidic surface species and for removing chemisorbed oxygen are selectively inhibited by deactivation of surface sites, leading to the oxidation of Fe carbide even in the presence of a reducing reactant mixture. © 2001 Elsevier Science B.V. All rights reserved.

Effects of temperature on the toxicity of m-parathion, chlorpyrifos, and pentachlorobenzene to Chironomus tentans

Abstract: This study examined the influence of temperature (10, 20, and 30 degrees C) on the acute toxicity and accumulation of two organophosphate (OP) insecticides and a narcotic chemical to the midge (Chironomus tentans). OP insecticides used in this study included chlorpyrifos and m-parathion, and pentachlorobenzene was the chosen narcotic. Chlorpyrifos was the most toxic chemical tested, followed by m-parathion and then pentachlorobenzene. A positive correlation was found between temperature and toxicity for each of the chemicals tested. A reverse trend was noted for total OP insecticide body residues with decreased concentrations found at the higher temperatures. Pentachlorobenzene body residues remained constant at all temperatures. All three chemicals showed increased uptake rates at 20 and 30 degrees C in comparison to 10 degrees C. The noted decrease in midge body residues at the higher temperatures for the OP insecticides was contributed to increased biotransformation and elimination rates at the higher temperatures. Overall, temperature had a greater influence on OP toxicity than for pentachlorobenzene, and this may be due to accelerated biotransformation of the OPs to more toxic o-analog metabolites at the higher temperatures.http://link.springer-ny. com/link/service/journals/00244/bibs/37n4p542.html

Mentally retarded individuals--a population at risk?

Abstract: When comparing the aging process of mentally retarded (MR) persons with the nondisabled population, researchers have established an earlier lower limit for the onset of old age for MR persons and a higher mortality rate. The reason for early senescence has not been successfully resolved, but the finding that cardiovascular disorders are the most prevalent form of disease among elderly MR persons suggests a relationship between lifestyles and higher mortality rate. Indeed, studies that evaluated the cardiovascular fitness (CVF) of MR individuals demonstrated substandard levels of fitness. The results of these studies, however, are not conclusive due to variation in test methodologies, motivational factors, and issues of test validity and reliability. Training studies which have purported to determine trainability of this population have also shown confusing results, perhaps attributed to the same protocol inconsistencies. Therefore, the purposes of this article are 1) to review previous methods of evaluating CVF of MR adults and determine whether testing methodologies invalidate the results of these studies, 2) to review training studies involving adult MR individuals and determine whether this population is capable of improving their CVF, and 3) to identify areas where further research is needed to fully describe the functional cardiovascular characteristics of MR adults.

Cardiovascular Fitness and Body Composition of Youth with and without Mental Retardation

Abstract: The purpose of this study was to compare the aerobic fitness and body mass index (BMI) of children and adolescents (8-18 yr) with and without mild mental retardation (MR). Sample size of participants with MR but without Down syndrome was 169 males and 99 females. Sample size of participants without MR was 289 males and 317 females. Analysis was made by gender and age: children (8-10 yr); early adolescents (11-14 yr); and late adolescents (15-18 yr). The 20-m shuttle run test (20 MST) was used to assess field test performance and predicted aerobic fitness. For all age groups, females and males without MR ran significantly more laps and had a significantly higher predicted aerobic fitness (VO2peak: ml $$ kg-1 $$ min-1) than their peers with MR. Additionally, participants with MR tended to have higher BMI than their peers without MR. The results of this study indicate that children and adolescents with MR have lower exercise capacity, lower aerobic fitness, and higher BMIs than their peers without MR.

Performance Based Budgeting

Abstract: Performance Based Budgetingis the next volume in the ASPA Classics series. It covers the most influential, paramount research articles published on public budgeting and finance. The book will surely be of great interest and use to anyone concerned with public budgeting, and anyone enrolled in, or teaching, a course on this topic in an MPA program or a doctoral program in public administration, public affairs, political science, or economics/public finance.