Wuhan University

About: Wuhan University is a education organization based out in Wuhan, China. It is known for research contribution in the topics: Population & Feature extraction. The organization has 92849 authors who have published 92882 publications receiving 1691049 citations. The organization is also known as: WHU & Wuhan College.

Opening Two-Dimensional Materials for Energy Conversion and Storage: A Concept

Abstract: The development of two-dimensional (2D) materials is experiencing a renaissance since the adventure of graphene. 2D materials typically exhibit strong in-plane covalent bonding and weak out-of-plane van der Waals interactions through the interlayer gap. Opening 2D materials is an effective way to alter the physical and chemical properties, such as band gap, conductivity, optical property, thermoelectric property, photovoltaic property and superconductivity. A larger interlayer distance means more accessible active sites for catalysis, an ion-accessible surface in the interlayer space, which may greatly enhance the performance of 2D materials for energy conversion and storage. Moreover, opening 2D materials by intercalation can change the band filling state and the Fermi level. This review mainly focuses on the opening of 2D materials and their subsequent applications in energy conversion and storage fields, expecting to promote the development of such a new class of materials, namely expanded 2D materials. The exciting progresses of these expanded materials made in both energy conversion and storage devices including solar cells, thermoelectric devices, electrocatalyst, supercapacitors and rechargeable batteries, is presented and discussed in depth. Furthermore, prospects and further developments in these exciting fields of the expanded 2D materials are also commented.

Salt Stress Reduces Root Meristem Size by Nitric Oxide-Mediated Modulation of Auxin Accumulation and Signaling in Arabidopsis

Abstract: The development of the plant root system is highly plastic, which allows the plant to adapt to various environmental stresses. Salt stress inhibits root elongation by reducing the size of the root meristem. However, the mechanism underlying this process remains unclear. In this study, we explored whether and how auxin and nitric oxide (NO) are involved in salt-mediated inhibition of root meristem growth in Arabidopsis (Arabidopsis thaliana) using physiological, pharmacological, and genetic approaches. We found that salt stress significantly reduced root meristem size by down-regulating the expression of PINFORMED (PIN) genes, thereby reducing auxin levels. In addition, salt stress promoted AUXIN RESISTANT3 (AXR3)/INDOLE-3-ACETIC ACID17 (IAA17) stabilization, which repressed auxin signaling during this process. Furthermore, salt stress stimulated NO accumulation, whereas blocking NO production with the inhibitor Nω-nitro-l-arginine-methylester compromised the salt-mediated reduction of root meristem size, PIN down-regulation, and stabilization of AXR3/IAA17, indicating that NO is involved in salt-mediated inhibition of root meristem growth. Taken together, these findings suggest that salt stress inhibits root meristem growth by repressing PIN expression (thereby reducing auxin levels) and stabilizing IAA17 (thereby repressing auxin signaling) via increasing NO levels.

How many lithium ions can be inserted onto fused C6 aromatic ring systems

Abstract: A fundamental and persistent problem in the study of carbonbased electrode materials for lithium ion batteries is the question of how many lithium ions can be inserted onto a C6 aromatic ring. Although different empirical models of Lix/C6 (x< 3) have been proposed, the question remains unresolved. Herein we employ 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTCDA), an aromatic compound containing a naphthalene ring system (fused C6 aromatic rings), to demonstrate that each carbon in a C6 ring can accept a Li ion to form a Li6/C6 additive complex through a reversible electrochemical lithium addition reaction. This process results in Li ion insertion capacities of up to nearly 2000 mAhg , depending on the exact molecular structure. This value is several times higher than any other organic electrode material previously reported and can be fully released under certain conditions. Our experiments and theoretical calculations indicate that the anhydride groups on the sides of the aromatic system are crucial for this process, which provides a promising strategy for the design of novel high-performance organic electrode materials. Organic molecules are intriguing candidates for electrode materials for use in rechargeable Li ion batteries. The application of such species has aroused much interest recently, owing to the obvious advantages of such a system: no need for rare metals, low safety risks compared to transition metal oxides, and design flexibility at the molecular level. However, organic molecules are usually considered to possess relatively poor specific energies and cycling properties, as compared to those of inorganic materials, and these factors greatly limit their practical application. Recently, studies on aromatic carbonyl derivatives showed that organic materials can possess outstanding electrochemical performance comparable to, or even superior to, inorganic materials. Furthermore, the wide diversity of organic redox systems, as well as the excellent flexibility in their molecular design, suggest even greater prospects for these materials, and this has inspired the exploration of new organic Li ion insertion systems with improved performance. Aromatic C6 rings are the basic structural units of graphite and other carbon-based electrode materials, which are the most commonly used anodes in commercial Li ion batteries owing to their high electric conductivity and low cost. It has traditionally been believed that each C6 ring can accept one Li ion to form an intercalated Li/C6 complex, giving a relatively low theoretical capacity of 372 mAhg . Recently, studies on graphene, nanographene, and their derivatives reveal that, through the reduction of size and dimensionality, these materials exhibit unique electric and electrochemical properties superior to those of conventional graphitic materials; thus, these materials are currently a hot research topic. In studies of electrode materials for Li ion batteries, these derivatives also exhibit high reversible capacities of up to almost twice the theoretical value of graphite, although the detailed mechanism is still unclear. This leads to a fundamental question in the study of carbonbased electrode materials: How many Li ions can actually be inserted onto each C6 aromatic ring? Multi-ring aromatics (for example, naphthalene, NTCDA, perylene, etc.) and their derivatives have planar C6 ring structures similar to graphene or nanographene. NTCDA is a typical example; it has a naphthalene-like ring structure consisting of two C6 rings fused together along with two cyclic anhydride groups (Figure 1a). NTCDA is a well-known organic semiconductor with good crystallinity and has been extensively studied for use in molecular electric devices. It provides an ideal model to study Li ion insertion onto C6 rings owing to the minimal number of C6 rings it possesses, which guarantees the necessary insolubility of the electrode materials in the commonly used electrolyte solution (ethylene carbonate/dimethyl carbonate/LiPF6) for Li ion batteries. NTCDA also possesses the necessary degree of conductivity for electron transport among molecules. We investigated the electrochemical Li ion insertion/deinsertion properties of NTCDA using model test cells with Li metal as the counter electrode. The working electrode consisted of NTCDA, acetylene black (AB), and polytetrafluoroethylene binders in a weight ratio of about 60:35:5. The cells were initially cycled by discharging (Li ion insertion) and charging (Li ion deinsertion) repeatedly in a potential range of 0.001–3.0 V vs. Li/Li at a moderate current rate of 100 mAg . Figure 1b shows selected discharge/charge curves (the 1st, 2nd, 3rd, and 8th cycles) for NTCDA. Figure 1c shows the corresponding discharge and charge capacities of NTCDA versus the cycle number. The first discharge and charge capacities are 1273 and 724 mAhg , respectively, showing a coulombic efficiency [*] X. Han, G. Qing, T. Sun State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology Wuhan, 430070 (China) E-mail: suntaolei@iccas.ac.cn

Bright quantum dots emitting at ∼1,600 nm in the NIR-IIb window for deep tissue fluorescence imaging.

Abstract: With suppressed photon scattering and diminished autofluorescence, in vivo fluorescence imaging in the 1,500- to 1,700-nm range of the near-IR (NIR) spectrum (NIR-IIb window) can afford high clarity and deep tissue penetration. However, there has been a lack of NIR-IIb fluorescent probes with sufficient brightness and aqueous stability. Here, we present a bright fluorescent probe emitting at ∼1,600 nm based on core/shell lead sulfide/cadmium sulfide (CdS) quantum dots (CSQDs) synthesized in organic phase. The CdS shell plays a critical role of protecting the lead sulfide (PbS) core from oxidation and retaining its bright fluorescence through the process of amphiphilic polymer coating and transferring to water needed for imparting aqueous stability and compatibility. The resulting CSQDs with a branched PEG outer layer exhibited a long blood circulation half-life of 7 hours and enabled through-skin, real-time imaging of blood flows in mouse vasculatures at an unprecedented 60 frames per second (fps) speed by detecting ∼1,600-nm fluorescence under 808-nm excitation. It also allowed through-skin in vivo confocal 3D imaging of tumor vasculatures in mice with an imaging depth of ∼1.2 mm. The PEG-CSQDs accumulated in tumor effectively through the enhanced permeation and retention effect, affording a high tumor-to-normal tissue ratio up to ∼32 owing to the bright ∼1,600-nm emission and nearly zero autofluorescence background resulting from a large ∼800-nm Stoke’s shift. The aqueous-compatible CSQDs are excreted through the biliary pathway without causing obvious toxicity effects, suggesting a useful class of ∼1,600-nm emitting probes for biomedical research.