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Showing papers in "Applied Sciences in 2014"


Journal ArticleDOI
TL;DR: In this paper, the authors review the thermal properties of graphene, few-layer graphene and graphene nanoribbons and discuss practical applications of graphene in thermal management and energy storage, and show that the use of liquid-phase-exfoliated graphene as filler material in phase change materials is promising for thermal management of high power-density battery parks.
Abstract: We review the thermal properties of graphene, few-layer graphene and graphene nanoribbons, and discuss practical applications of graphene in thermal management and energy storage. The first part of the review describes the state-of-the-art in the graphene thermal field focusing on recently reported experimental and theoretical data for heat conduction in graphene and graphene nanoribbons. The effects of the sample size, shape, quality, strain distribution, isotope composition, and point-defect concentration are included in the summary. The second part of the review outlines thermal properties of graphene-enhanced phase change materials used in energy storage. It is shown that the use of liquid-phase-exfoliated graphene as filler material in phase change materials is promising for thermal management of high-power-density battery parks. The reported experimental and modeling results indicate that graphene has the potential to outperform metal nanoparticles, carbon nanotubes, and other carbon allotropes as filler in thermal management materials.

250 citations


Journal ArticleDOI
TL;DR: The present paper reviews the progress made towards laser driven hadron cancer therapy and what has still to be accomplished to realize its inherent enormous potential.
Abstract: It has been known for about sixty years that proton and heavy ion therapy is a very powerful radiation procedure for treating tumors. It has an innate ability to irradiate tumors with greater doses and spatial selectivity compared with electron and photon therapy and, hence, is a tissue sparing procedure. For more than twenty years, powerful lasers have generated high energy beams of protons and heavy ions and it has, therefore, frequently been speculated that lasers could be used as an alternative to radiofrequency (RF) accelerators to produce the particle beams necessary for cancer therapy. The present paper reviews the progress made towards laser driven hadron cancer therapy and what has still to be accomplished to realize its inherent enormous potential.

84 citations


Journal ArticleDOI
TL;DR: The research platform was inaugurated in October 2014 and will produce an increasing range of innovative isotopes using the proton beam of ISOLDE for fundamental studies in cancer research, for new imaging and therapy protocols in cell and animal models and for preclinical trials.
Abstract: About 50% of the 1.4 GeV CERN (European Organization for Nuclear Research, www.cern.ch) protons are sent onto targets to produce radioactive beams by online mass separation at the Isotope Separator Online Device (ISOLDE) facility, for a wide range of studies in fundamental and applied physics. CERN-MEDICIS is a spin-off dedicated to RD for fundamental studies in cancer research, for new imaging and therapy protocols in cell and animal models and for pre-clinical trials, possibly extended to specific early phase clinical studies up to Phase I trials. Five hundred megabecquerel isotope batches purified by electromagnetic mass separation combined with chemical methods will be collected on a weekly basis. A possible future upgrade with gigabecquerel pharmaceutical-grade i.e., current good manufacturing practices (cGMP) batch production capabilities is finally presented.

71 citations


Journal ArticleDOI
TL;DR: In this paper, the Kirchhoff-love plate theory is used to estimate the buckling limit of graphene bound to a substrate and the size above which a scrolled graphene sheet will never spontaneously unroll in free space.
Abstract: Graphene is an ultimate membrane that mixes both flexibility and mechanical strength, together with many other remarkable properties. A good knowledge of the elastic properties of graphene is prerequisite to any practical application of it in nanoscopic devices. Although this two-dimensional material is only one atom thick, continuous-medium elasticity can be applied as long as the deformations vary slowly on the atomic scale and provided suitable parameters are used. The present paper aims to be a critical review on this topic that does not assume a specific pre-knowledge of graphene physics. The basis for the paper is the classical Kirchhoff-Love plate theory. It demands a few parameters that can be addressed from many points of view and fitted to independent experimental data. The parameters can also be estimated by electronic structure calculations. Although coming from diverse backgrounds, most of the available data provide a rather coherent picture that gives a good degree of confidence in the classical description of graphene elasticity. The theory can than be used to estimate, e.g., the buckling limit of graphene bound to a substrate. It can also predict the size above which a scrolled graphene sheet will never spontaneously unroll in free space.

65 citations


Journal ArticleDOI
TL;DR: MicroPET imaging of [11C]2a in a non-human primate (NHP) confirmed that the tracer was able to cross the BBB with rapid washout kinetics from brain regions of a healthy macaque and demonstrated good brain uptake 5 min post-injection.
Abstract: Two α-synuclein ligands, 3-methoxy-7-nitro-10H-phenothiazine (2a, Ki = 32.1 ± 1.3 nM) and 3-(2-fluoroethoxy)-7-nitro-10H-phenothiazine (2b, Ki = 49.0 ± 4.9 nM), were radiolabeled as potential PET imaging agents by respectively introducing 11C and 18F. The syntheses of [11C]2a and [18F]2b were accomplished in a good yield with high specific activity. Ex vivo biodistribution studies in rats revealed that both [11C]2a and [18F]2b crossed the blood-brain barrier (BBB) and demonstrated good brain uptake 5 min post-injection. MicroPET imaging of [11C]2a in a non-human primate (NHP) confirmed that the tracer was able to cross the BBB with rapid washout kinetics from brain regions of a healthy macaque. The initial studies suggested that further structural optimization of [11C]2a and [18F]2b is necessary in order to identify a highly specific positron emission tomography (PET) radioligand for in vivo imaging of α-synuclein aggregation in the central nervous system (CNS).

48 citations


Journal ArticleDOI
TL;DR: In this article, a review of recent advances in two-photon absorbing photochromic molecules, as potential materials for 3D optical memory, is presented, which indicates that 3D data storage processing at the molecular level is possible.
Abstract: In this review, recent advances in two-photon absorbing photochromic molecules, as potential materials for 3D optical memory, are presented. The investigations introduced in this review indicate that 3D data storage processing at the molecular level is possible. As 3D memory using two-photon absorption allows advantages over existing systems, the use of two-photon absorbing photochromic molecules is preferable. Although there are some photochromic molecules with good properties for memory, in most cases, the two-photon absorption efficiency is not high. Photochromic molecules with high two-photon absorption efficiency are desired. Recently, molecules having much larger two-photon absorption cross sections over 10,000 GM (GM= 10−50 cm4 s molecule−1 photon−1) have been discovered and are expected to open the way to realize two-photon absorption 3D data storage.

41 citations


Journal ArticleDOI
TL;DR: In this article, a semi-classical electrodynamical model is derived to describe the electrical transport along graphene, based on the modified Boltzmann transport equation, in the typical operating conditions predicted for future integrated circuits nano-interconnects, i.e., a low bias condition and an operating frequency up to 1 THz.
Abstract: A semi-classical electrodynamical model is derived to describe the electrical transport along graphene, based on the modified Boltzmann transport equation. The model is derived in the typical operating conditions predicted for future integrated circuits nano-interconnects, i.e., a low bias condition and an operating frequency up to 1 THz. A generalized non-local dispersive Ohm’s law is derived, which can be regarded as the constitutive equation for the material. The behavior of the electrical conductivity is studied with reference to a 2D case (the infinite graphene layer) and a 1D case (the graphene nanoribbons). The modulation effects of the nanoribbons’ size and chirality are highlighted, as well as the spatial dispersion introduced in the 2D case by the dyadic nature of the conductivity.

37 citations


Journal ArticleDOI
TL;DR: In the pursuit towards attaining sustainability, arrays of greener pathways are being carved to address the needs of the diverse chemical universe as discussed by the authors, which is defined as "the utilization of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture, and application of chemical products".
Abstract: In the pursuit towards attaining sustainability, arrays of greener pathways are being carved to address the needs of the diverse chemical universe. The evolving area of green and sustainable chemistry envisions minimum hazard as the performance criterion while designing new chemical processes. Green Chemistry is defined as "the utilization of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture, and application of chemical products" [1]. Sustainable processes are being sought to explore alternatives to conventional chemical syntheses and transformations. Among several thrust areas for achieving this target includes: the utility of alternative feedstocks, preferably from renewable materials or waste from other industries; unconventional efficient reaction conditions and eco-friendly reaction media to accomplish the desired chemical transformations with minimized by-products or waste generation, and ideally avoiding the use of conventional volatile organic solvents, wherever possible. Other avenues for achieving this objective are to explore the generation of efficient catalytic processes, particularly magnetically retrievable nano-catalysts [1,2,3,4]. In addition to greener synthesis, the recyclability and reuse aspects for catalytic systems are extremely significant particularly when it boils down to the use of endangered elements and precious catalysts. Several friendlier applications in catalysis have been advanced via magnetically recoverable and recyclable nano-catalysts for oxidation, reduction, and multi-component condensation reactions [1,2,3,4] and this has made a terrific impact on the development of green chemical pathways [1]. The greener preparation of nanoparticles has been exemplified via the use of vitamins B1, B2, C, and tea [5] and wine polyphenols [6], beet juice [7] and other agricultural residues which function both as reducing and capping agents. This avoids the need to deploy toxic reducing agents, such as borohydrides or hydrazines and empowers simple and aqueous green synthetic methods to produce bulk quantities of nano-catalysts without the requirement for large amounts of insoluble templates [8]. [...]

30 citations


Journal ArticleDOI
TL;DR: In this article, the terahertz plasmon dispersion of a multilayer system consisting of graphene on dielectric and/or plasma thin layers is systematically investigated.
Abstract: The terahertz plasmon dispersion of a multilayer system consisting of graphene on dielectric and/or plasma thin layers is systematically investigated. We show that graphene plasmons can couple with other quasiparticles such as phonons and plasmons of the substrate; the characteristics of the plasmon dispersion of graphene are dramatically modified by the presence of the coupling effect. The resultant plasmon dispersion of the multilayer system is a strong function of the physical parameters of the spacer and the substrate, signifying the importance of the substrate selection in constructing graphene-based plasmonic devices.

28 citations


Journal ArticleDOI
TL;DR: In this article, a confidence measure scheme in a bimodal camera setup for automatically selecting visible-light or a thermal infrared in response to natural environmental changes is introduced, where two efficient segmentation algorithms, one dedicated to the visible light spectrum and another to the thermal infrared spectrum, are implemented.
Abstract: This paper introduces a confidence measure scheme in a bimodal camera setup for automatically selecting visible-light or a thermal infrared in response to natural environmental changes. The purpose of the setup is to robustly detect people in dynamic outdoor scenarios under very different conditions. For this purpose, two efficient segmentation algorithms, one dedicated to the visible-light spectrum and another one to the thermal infrared spectrum, are implemented. The segmentation algorithms are applied to five different video sequences recorded under very different environmental conditions. The results of the segmentation in both spectra allow one to establish the best-suited confidence interval thresholds and to validate the overall approach. Indeed, the confidence measures take linguistic values LOW, MEDIUM and HIGH, depending on the reliability of the results obtained in visible-light, as well as in thermal infrared video.

24 citations


Journal ArticleDOI
TL;DR: A new embodiment of the external-beam radiation therapy robotic system delivering very high-energy electron/photon beams with an energy of 50–250 MeV is proposed; it is more compact, less expensive, and has a simpler operation and higher performance in comparison with the current radiation therapy system.
Abstract: We present a new external-beam radiation therapy system using very-high-energy (VHE) electron/photon beams generated by a centimeter-scale laser plasma accelerator built in a robotic system. Most types of external-beam radiation therapy are delivered using a machine called a medical linear accelerator driven by radio frequency (RF) power amplifiers, producing electron beams with an energy range of 6–20 MeV, in conjunction with modern radiation therapy technologies for effective shaping of three-dimensional dose distributions and spatially accurate dose delivery with imaging verification. However, the limited penetration depth and low quality of the transverse penumbra at such electron beams delivered from the present RF linear accelerators prevent the implementation of advanced modalities in current cancer treatments. These drawbacks can be overcome if the electron energy is increased to above 50 MeV. To overcome the disadvantages of the present RF-based medical accelerators, harnessing recent advancement of laser-driven plasma accelerators capable of producing 1-GeV electron beams in a 1-cm gas cell, we propose a new embodiment of the external-beam radiation therapy robotic system delivering very high-energy electron/photon beams with an energy of 50–250 MeV; it is more compact, less expensive, and has a simpler operation and higher performance in comparison with the current radiation therapy system.

Journal ArticleDOI
TL;DR: In this paper, the Gewald reaction was used to synthesize 2-aminothiophenes using high speed ball milling conditions, and it was shown that using thermal heat in tandem with the mixer/mill significantly increases the rate of reaction.
Abstract: Herein, we report on the solvent-free synthesis of 2-aminothiophenes via the Gewald reaction. Utilizing high speed ball milling conditions, we discovered the Gewald reaction can be catalytic in base, and conducted under aerobic conditions. Using thermal heat in tandem with the mixer/mill significantly increases the rate of reaction.

Journal ArticleDOI
TL;DR: In this paper, a review focusing on intra-and interlayer electron-phonon interactions and phonon self-energy renormalizations in twisted and AB-stacked bilayer graphene (2LG) is presented.
Abstract: Department of Physics and Astronomy, The University of Alabama, Tuscaloosa, AL 35487, USA* Author to whom correspondence should be addressed; E-Mail: paulo.t.araujo@ua.edu;Tel.: +1-205-348-2878; Fax: +1-205-348-5051.Received: 12 March 2014; in revised form: 8 April 2014 / Accepted: 8 April 2014 /Published: 29 April 2014Abstract: This review focuses on intra- and interlayer (IL) electron-phonon interactionsand phonon self-energy renormalizations in twisted and AB-stacked bilayer graphene (2LG)composed either only of

Journal ArticleDOI
TL;DR: A shift-peristrophic multiplexing technique that uses spherical reference waves is proposed, and it is experimentally verified that this method efficiently increases the data capacity.
Abstract: Holographic data storage is a promising technology that provides very large data storage capacity, and the multiplexing method plays a significant role in increasing this capacity. Various multiplexing methods have been previously researched. In the present study, we propose a shift-peristrophic multiplexing technique that uses spherical reference waves, and experimentally verify that this method efficiently increases the data capacity. In the proposed method, a series of holograms is recorded with shift multiplexing, in which the recording material is rotated with its axis perpendicular to the material’s surface. By iterating this procedure, multiplicity is shown to improve. This method achieves more than 1 Tbits/inch2 data density recording. Furthermore, a capacity increase of several TB per disk is expected by maximizing the recording medium performance.

Journal ArticleDOI
TL;DR: In this article, the effect of the calcination conditions on the catalytic activity for N2O decomposition of 2.5% RhOx/CeO2 catalysts has been investigated.
Abstract: The effect of the calcination conditions on the catalytic activity for N2O decomposition of 2.5% RhOx/CeO2 catalysts has been investigated. Ramp and flash calcinations have been studied (starting calcinations at 25 or 250/350 °C, respectively) both for cerium nitrate and ceria-impregnated rhodium nitrate decomposition. The cerium nitrate calcination ramp has neither an effect on the physico-chemical properties of ceria, observed by XRD, Raman spectroscopy and N2 adsorption, nor an effect on the catalysts performance for N2O decomposition. On the contrary, flash calcination of rhodium nitrate improved the catalytic activity for N2O decomposition. This is attributed to the smaller size of RhOx nanoparticles obtained (smaller than 1 nm) which allow a higher rhodium oxide-ceria interface, favoring the reducibility of the ceria surface and stabilizing the RhOx species under reaction conditions.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated four-wave mixing in hydrogen gas using a gas cell and a hollow fiber for the generation of high-energy, multicolor femtosecond (fs) optical pulses.
Abstract: We investigate four-wave mixing in hydrogen gas using a gas cell and a hollow fiber for the generation of high-energy, multicolor femtosecond (fs) optical pulses. Both a hydrogen-filled gas cell and hollow fiber lead to the generation of multicolor fs pulses in a broad spectral range from the deep ultraviolet to the near infrared. However, there is a difference in the energy distribution of the multicolor emission between the gas cell and the hollow fiber. The hydrogen-filled gas cell generates visible pulses with higher energies than the pulses created by the hollow fiber. We have generated visible pulses with energies of several tens of microjoules. The hydrogen-filled hollow fiber, on the other hand, generates ultraviolet pulses with energies of a few microjoules, which are higher than the energies of the ultraviolet pulses generated in the gas cell. In both schemes, the spectral width of each emission line supports a transform-limited pulse duration shorter than 15 fs. Four-wave mixing in hydrogen gas therefore can be used for the development of a light source that emits sub-20 fs multicolor pulses in a wavelength region from the deep ultraviolet to the near infrared with microjoule pulse energies.

Journal ArticleDOI
TL;DR: The influence of three types of halogen-substituted Eβ-methyl-β-nitrostyrenes to overcome bacterial activity that is currently a significant health threat was studied in this paper.
Abstract: The influence of three types of halogen-substituted E-β-methyl-β-nitrostyrenes (such as Compounds B, D, H) to overcome bacterial activity that is currently a significant health threat was studied. The evaluations of their bio-potency was measured and related to their structure and activity relationships for the purposes of serving to inhibit and overcoming resistant microorganisms. In particular, fluorine-containing β-nitrostyrenes were found to be highly active antimicrobial agents. The addition of the β-bromo group enhanced the antibacterial activity significantly. Our work has illustrated that halogen substituents at both the 4-position in the aromatic ring and also at the β-position on the alkene side chain of nitropropenyl arenes enhanced the antimicrobial activity of these compounds.

Journal ArticleDOI
TL;DR: Experimental results show that the new distributed block-based image compression method based on the principles of compressed sensing achieves better results than existing CS- based image coding methods.
Abstract: In this paper, a new distributed block-based image compression method based on the principles of compressed sensing (CS) is introduced. The coding and decoding processes are performed entirely in the CS measurement domain. Image blocks are classified into key and non-key blocks and encoded at different rates. The encoder makes use of a new adaptive block classification scheme that is based on the mean square error of the CS measurements between blocks. At the decoder, a simple, but effective, side information generation method is used for the decoding of the non-key blocks. Experimental results show that our coding scheme achieves better results than existing CS-based image coding methods.

Journal ArticleDOI
TL;DR: In this article, Raman spectroscopy and imaging are used to determine the main location of each carbon isotope in thin layers graphite (TLG) synthesis on a polycrystalline nickel film deposited on SiO2 (300 nm thick)/Si(100) and annealing at moderate temperatures (450-600 °C).
Abstract: The mechanism of thin layers graphite (TLG) synthesis on a polycrystalline nickel film deposited on SiO2 (300 nm thick)/Si(100) has been investigated by 13C implantation of four equivalent graphene monolayers and annealing at moderate temperatures (450–600 °C). During this process, the implanted 13C segregates to the surface. Nuclear Reaction Analyses (NRA) are used for the first time in the topic of graphene synthesis to separate the isotopes and to determine the 12C and 13C concentrations at each step. Indeed, a significant part of carbon in the TLG also comes from residual 12C carbon absorbed into the metallic matrix. Raman spectroscopy and imaging are used to determine the main location of each carbon isotope in the TLG. The Raman mappings especially emphasize the role of 12C previously present at the surface that first diffuses along grain boundaries. They play the role of nucleation precursors. Around them the implanted 13C or a mixture of bulk 12C–13C aggregate and further precipitate into graphene-like fragments. Graphenization is effective at around 600 °C. These results point out the importance of controlling carbon incorporation, as well as the importance of preparing a uniform nickel surface, in order to avoid heterogeneous nucleation.

Journal ArticleDOI
TL;DR: In this article, X-ray fluorescence analysis of tailings at the Three Kids Mine show they contain high levels of: Pb (15,300 mg/ kg), As (3690 mg/kg), and Mn (153,000 mg/k).
Abstract: Active and abandoned mines may present health risks, especially to children, from environmental exposure to airborne chemical elements, such as Pb, As, and Mn. X-ray fluorescence analysis of tailings at the Three Kids Mine show they contain high levels of: Pb (15,300 mg/kg), As (3690 mg/kg), and Mn (153,000 mg/kg). Soil was sampled along eight transects, radiating from the dried tailings ponds. Concentrations of Mn and Pb to the NE are at background concentrations at 4.8 km, and, As and Sr at 3.2 km from the mine. Going SW to the City of Henderson, all elements are at background at 1.6 cm, with the closest houses at 1.8 km. The United States Environmental Protection Agency (USEPA) Regional Screening Levels (RSLs) are exceeded for Pb, As and Mn at 0.8 km on all transects except one. The RSLs are exceeded for Pb, As and Mn on the NE transects at 1.6 km. Future home sites are on a NE transect between 0.4 km and 2.3 km downwind from the tailings ponds, in an area highly impacted by tailings which exceed the USEPA RSLs. This research demonstrates that there has been the farthest transport of tailings offsite by the prevailing winds to the NE; the closest currently-built homes have not received measurable tailings dust because they are upwind; and that precautions must be taken during the proposed remediation of the mine to restrict dust-transport of Pb, As, and Mn to avoid human exposure and ecological damage.

Journal ArticleDOI
TL;DR: An undersampling technique is presented that allows the reconstruction of the sparse information that is transmitted through Orthogonal Frequency Division Multiplexing (OFDM) modulation and it will be shown that up to 1/4 of the samples can be omitted from the sampling process and substituted by others on the side of the receiver for the successful reconstruct of the original data.
Abstract: Several techniques have been proposed that attempt to reconstruct a sparse signal from fewer samples than the ones required by the Nyquist theorem. In this paper, an undersampling technique is presented that allows the reconstruction of the sparse information that is transmitted through Orthogonal Frequency Division Multiplexing (OFDM) modulation. The properties of the Discrete Fourier Transform (DFT) that is employed by the OFDM modulation, allow the estimation of several samples from others that have already been obtained on the side of the receiver, provided that special relations are valid between the original data values. The inherent sparseness of the original data, as well as the Forward Error Correction (FEC) techniques employed, can assist the information recovery from fewer samples. It will be shown that up to 1/4 of the samples can be omitted from the sampling process and substituted by others on the side of the receiver for the successful reconstruction of the original data. In this way, the size of the buffer memory used for sample storage, as well as the storage requirements of the Fast Fourier Transform (FFT) implementation at the receiver, may be reduced by up to 25%. The power consumption of the Analog Digital Converter on the side of the receiver is also reduced when a lower sampling rate is used.

Journal ArticleDOI
TL;DR: In this paper, the surface and bulk changes in a Nafion membrane as a result of IL-cation doping were studied by X-ray photoelectron spectroscopy (XPS), contact angle, differential scanning calorimetry (DSC), and impedance spectrography (IS) measurements performed with dry samples after 24 hours in contact with the IL-cations BMIM+ and TMPA+.
Abstract: Surface and bulk changes in a Nafion membrane as a result of IL-cation doping (1-butyl-3-methylimidazolium tetrafluoroborate or BMIM+BF4 and phenyltrimethylammonium chloride or TMPA+Cl−) were studied by X-ray photoelectron spectroscopy (XPS), contact angle, differential scanning calorimetry (DSC) and impedance spectroscopy (IS) measurements performed with dry samples after 24 h in contact with the IL-cations BMIM+ and TMPA+. IL-cations were selected due to their similar molecular weight and molar volume but different shape, which could facilitate/obstruct the cation incorporation in the Nafion membrane structure by proton/cation exchange mechanism. The surface coverage of the Nafion membrane by the IL-cations was confirmed by XPS analysis and contact angle, while the results obtained by the other two techniques (DSC and IS) seem to indicate differences in thermal and electrical behaviour depending on the doping-cation, being less resistive the Nafion/BMIM+ membrane. For that reason, determination of the ion transport number was obtained for this membrane by measuring the membrane or concentration potential with the samples in contact with HCl solutions at different concentrations. The comparison of these results with those obtained for the original Nafion membrane provides information on the effect of IL-cation BMIM+ on the transport of H+ across wet Nafion/BMIM+ doped membranes.

Journal ArticleDOI
TL;DR: In this paper, volume phase gratings, recorded in a photosensitive polymer by two-beam interference exposure, are studied by means of optical microscopy, with periods in the order of 10 μm down to 130 nm.
Abstract: Volume phase gratings, recorded in a photosensitive polymer by two-beam interference exposure, are studied by means of optical microscopy. Transmission gratings and reflection gratings, with periods in the order of 10 μm down to 130 nm, were investigated. Mapping of holograms by means of imaging in sectional view is introduced to study reflection-type gratings, evading the resolution limit of classical optical microscopy. In addition, this technique is applied to examine so-called parasitic gratings, arising from interference from the incident reference beam and the reflected signal beam. The appearance and possible avoidance of such unintentionally recorded secondary structures is discussed.

Journal ArticleDOI
TL;DR: In this article, a convenient network transformation method, exploiting different circuit transformations, for deriving linear sinusoidal oscillators from biquadratic band pass filters is proposed, which can be applied to any band pass filter.
Abstract: Network transformations are the techniques to obtain new functional schemes from available circuits. They are systematic methodologies, since each transformation technique can be applied to many circuits to obtain the desired functions or characteristics. A convenient network transformation method, exploiting different circuit transformations, for deriving linear sinusoidal oscillators from biquadratic band pass filters is proposed. This method with generality can be applied to any band pass filter. The oscillation frequency of the new obtained oscillator is identical to the center frequency of the original band pass filter, and the useful properties of the selected band pass filter can be retained. Two examples are illustrated to confirm the feasibility of the proposed approach. The workability of the obtained oscillators is verified with PSPICE simulations.

Journal ArticleDOI
TL;DR: In this article, the electromagnetic properties of pyrolytic carbon (PyC) films with thicknesses from 9 nm to 110 nm were studied both experimentally and theoretically, and a remarkably high absorption loss of up to 50% of incident power, along with chemical stability, makes PyC films attractive for electromagnetic interference shielding in space and airspace communication systems, as well as in portable electronic devices occupying this frequency slot.
Abstract: We studied electromagnetic properties of pyrolytic carbon (PyC) films with thicknesses from 9 nm to 110 nm. The PyC films consisted of randomly oriented and intertwined graphene flakes with a typical size of a few nanometers were synthesized by chemical vapor deposition (CVD) at 1100 °C on a quartz substrate. The reflectance and transmittance of these films in Ka-band, 26–37 GHz, were studied both experimentally and theoretically. The discovered remarkably high absorption loss of up to 50% of incident power, along with chemical stability, makes PyC films attractive for electromagnetic (EM) interference shielding in space and airspace communication systems, as well as in portable electronic devices occupying this frequency slot. Since, in practical applications, the PyC film should be employed for coating of dielectric surfaces, two important issues to be addressed are: (i) which side (front or back) of the substrate should be covered to ensure maximum absorption losses; and (ii) the frequency dependence of absorbance/transmittance/reflectance of binary PyC/quartz structures in the Ka-band.

Journal ArticleDOI
TL;DR: In this article, the authors studied the high-order Raman spectra when the Raman medium is pumped with linearly chirped pulses and showed that linear Raman scattering from two-photon dressed states can lead to the generation of these extra peaks.
Abstract: High order Raman generation has received considerable attention as a possible method for generating ultrashort pulses. A large number of Raman orders can be generated when the Raman-active medium is pumped by two laser pulses that have a frequency separation equal to the Raman transition frequency. High order Raman generation has been studied in the different temporal regimes, namely: adiabatic, where the pump pulses are much longer than the coherence time of the transition; transient, where the pulse duration is comparable to the coherence time; and impulsive, where the bandwidth of the ultrashort pulse is wider than the transition frequency. To date, almost all of the work has been concerned with generating as broad a spectrum as possible, but we are interested in studying the spectra of the individual orders when pumped in the transient regime. We concentrate on looking at extra peaks that are generated when the Raman medium is pumped with linearly chirped pulses. The extra peaks are generated on the low frequency side of the Raman orders. We discuss how linear Raman scattering from two-photon dressed states can lead to the generation of these extra peaks.

Journal ArticleDOI
TL;DR: In this article, the main aspects of multicolored femtosecond pulse generation using cascaded four-wave mixing (CFWM) in transparent bulk materials are introduced and discussed.
Abstract: This paper introduces and discusses the main aspects of multicolored femtosecond pulse generation using cascaded four-wave mixing (CFWM) in transparent bulk materials. Theoretical analysis and semi-quantitative calculations, based on the phase-matching condition of the four-wave mixing process, explain the phenomena well. Experimental studies, based on our experiments, have shown the main characteristics of the multicolored pulses, namely, broadband spectra with wide tunability, high stability, short pulse duration and relatively high pulse energy. Two-dimensional multicolored array generation in various materials are also introduced and discussed.

Journal ArticleDOI
TL;DR: In this paper, an optical modulator at a frequency of 90 THz was demonstrated, which has the capability to modulate any laser beam in the optical region of the spectrum.
Abstract: We demonstrate an optical modulator at a frequency of 90 THz that has the capability to modulate any laser beam in the optical region of the spectrum. The modulator is constructed by placing deuterium molecules inside a high-finesse cavity and driving a vibrational transition with two continuous-wave laser beams. The two beams, the pump and the Stokes, are resonant with the cavity. The high intra-cavity intensities that build up drive the molecules to a coherent state. This molecular coherence can then be used to modulate an independent laser beam, to produce frequency up-shifted and down-shifted sidebands. The beam to be modulated is not resonant with the cavity and thus the sidebands are produced in a single pass.

Journal ArticleDOI
TL;DR: The paper shows that the ordering of the MFIR stages, in combination with the scaling methods, have an important impact on the round-off noise.
Abstract: The paper analyzes the effects of round-off noise on Multiplicative Finite Impulse Response (MFIR) filters used to approximate the behavior of pole filters. General expressions to calculate the signal to round-off noise ratio of a cascade structure of Finite Impulse Response (FIR) filters are obtained and applied on the special case of MFIR filters. The analysis is based on fixed-point implementations, which are most common in digital signal processing algorithms implemented in Field-Programmable Gate-Array (FPGA) technology. Three well known scaling methods, i.e., L2 bound; infinity bound and absolute bound scaling are considered and compared. The paper shows that the ordering of the MFIR stages, in combination with the scaling methods, have an important impact on the round-off noise. An optimal ordering of the stages for a chosen scaling method can improve the round-off noise performance by 20 dB.

Journal ArticleDOI
TL;DR: In this paper, the authors proposed a re-planning operation method using Tabu Search for direct current (DC) smart house with photovoltaic (PV), solar collector (SC), battery and heat pump system.
Abstract: This paper proposes the re-planning operation method using Tabu Search for direct current (DC) smart house with photovoltaic (PV), solar collector (SC), battery and heat pump system. The proposed method is based on solar radiation forecasting using reported weather data, Fuzzy theory and Recurrent Neural Network. Additionally, the re-planning operation method is proposed with consideration of solar radiation forecast error, battery and inverter losses. In this paper, it is assumed that the installation location for DC smart house is Okinawa, which is located in Southwest Japan. The validity of proposed method is confirmed by comparing the simulation results.