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Showing papers in "Applied Surface Science in 1996"


Journal ArticleDOI
TL;DR: In this paper, the surface properties of Mo oxides (MoO 2 and MoO 3 ) were investigated using X-ray photoelectron spectroscopy (XPS) and two well resolved spectral lines at 232.5 and 235.6 eV were assigned to the Mo 3d 5/2, 3d 3/2 spin-orbit components, respectively.

581 citations


Journal ArticleDOI
TL;DR: In this article, the composition and thickness of thin iron-oxide films on pure iron were determined from XPS Fe 2p spectra using a generalization of Tougaard's method.

483 citations


Journal ArticleDOI
TL;DR: In this article, a stoichiometric Cu2ZnSnS4 film with the stannite structure and resistivity of 2 × 10 2 Ω · cm has been prepared by annealing polycrystalline quaternary films at 550°C, which are spray-deposited on glass substrates, in an argon gas flow containing H2S.

320 citations


Journal ArticleDOI
TL;DR: In this article, it was shown that the surface conditions chosen by Dabby and Paek are wrong and that the subsurface region is indeed hotter but only by a few degrees.

275 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the sampling depths of TEY and FY for Si L-edge and Si K-edge X-ray absorption near edge structure (XANES) spectra for SiO2 on Si substrates using total electron yield (TEY) and fluorescence yield (FY) techniques.

230 citations


Journal ArticleDOI
TL;DR: In this article, thermal stable, thin TaN diffusion barriers to prevent intermixing of Cu wiring with the Si substrate were developed by reactively sputtering Ta in a nitrogen atmosphere using a radio-frequency sputtering method.

221 citations


Journal ArticleDOI
TL;DR: The mode of corrosion inhibition of pure iron due to 1-phenyl-5-mercapto-1,2,3,4-tetrazole (PMT) in molar HCl is studied through weight loss and electrochemical steady-state experiments as discussed by the authors.

153 citations


Journal ArticleDOI
TL;DR: In this paper, a special solution of gas dynamics equations that describes the expansion of an ellipsoidal gas cloud into vacuum is employed to explain the apparent "rotation" of the cloud, the so called "flip-over effect".

145 citations


Journal ArticleDOI
TL;DR: In this paper, a binary reaction for Al2O3 chemical vapor deposition (2Al(CH3)3 + 3H2O → Al 2O3 + 6CH4) was separated into two half-reactions.

140 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the UV-photoablation behavior of glasses and oxide ceramics and found that nanosecond laser pulses lead to plasma mediated ablation in the high fluence regime, whereas the femtosecond ablation process is induced by two photon absorption.

128 citations


Journal ArticleDOI
Peter Hess1
TL;DR: In this paper, a novel method has been developed for the determination of mechanical and elastic properties of thin films such as film thickness, density, Young's modulus and Poisson's ratio.

Journal ArticleDOI
TL;DR: In this article, a pseudopotential plane wave theory is used to study the electronic and optical properties of a thousand atom hydrogen passivated Si quantum dots, wires and films, including band gap vs. shape, total electronic density of state and optical absorption spectra.

Journal ArticleDOI
TL;DR: In this article, a systematic study of nonlinear interaction of various transparent dielectric materials with laser-pulses in the intensity range of up to 1013 W cm−2 is presented.

Journal ArticleDOI
TL;DR: In this paper, the processes of target heating and ablation of pure metals (for instance Fe) during irradiation by 30 ns laser pulses at 248 nm were described, and the temperature profile in the target and the ablated material can be obtained.

Journal ArticleDOI
TL;DR: Porosity has already resulted in significant performance gains, or might do so in the future as mentioned in this paper, and the performance of a variety of porous Si-based discrete optoelectronic devices has been reviewed.

Journal ArticleDOI
TL;DR: In this article, the atomic layer epitaxy (ALE) approach is used to create conditions for monoatomic layer buildup through saturated surface reactions, which has been successfully applied in commercial manufacturing of thin film electroluminescent displays.

Journal ArticleDOI
TL;DR: In this paper, the state of the art of thin-film photovoltaics is reviewed and the different deposition processes are analyzed in view of material quality and scalability, and the formation and analysis of these junctions is described and ways for new developments and material combinations are shown.

Journal ArticleDOI
TL;DR: In this paper, the authors show for a coherent epitaxy that three conditions are necessary and sufficient to rationalize the problem: (i) the perfect wetting condition of Bauer's criterion expressed in terms of long range forces, (ii) an elastic misfit energy of the so produced layers, and (iii) elastic striction energy induced in the substrate by appearing islands.

Journal ArticleDOI
Z.-F. Pei1, V. Ponec1
TL;DR: In this article, a series of adsorbents, known as good catalysts for the selective hydrogenation of carboxylic acids to corresponding aldehydes, were studied.

Journal ArticleDOI
TL;DR: In this paper, the growth by pulsed-laser deposition of ZnO thin films for the eventual incorporation into piezo-electric actuators and other sensors being developed at the University of Twente is investigated.

Journal ArticleDOI
TL;DR: In this article, the surface electronic states were characterized by surface normal UV photoemission to determine whether the electron affinity was positive or negative, and the results suggest the potential of nitride based cold cathode electron emitters.

Journal ArticleDOI
TL;DR: In this article, it was shown that the barrier heights in ideal metal-semiconductor contacts are determined by the continuum of the metal-induced gap states (MIGS), and that these theoretical data predict the slope parameters S x to vary proportional to (ϵ ∞ − 1) 2 ϵ i where ϵ is the electronic contribution to the static dielectric constant of the semiconductor.

Journal ArticleDOI
TL;DR: In this article, a model for the segregation behavior at the surfaces of polycrystalline thin films of I-III-VI 2 -chalcopyrites (I = Cu; III = In, Ga; VI = Se) is presented.

Journal ArticleDOI
TL;DR: In this paper, the atomically smooth SrTiO3(100) surface having one unit cell high steps and atomically flat terraces was obtained by selective etching of SrO atomic layer in a NH4FHF solution.

Journal ArticleDOI
TL;DR: In this paper, the layer by layer growth of Al 2 O 3 from trimethylaluminium (TMA) and water vapour by atomic layer epitaxy (ALE) has been studied on porous large surface area silica.

Journal ArticleDOI
TL;DR: In this paper, combined diagnostic measurements are employed to characterize the penetration of energetic ablation plumes through background gases during a key transitional regime in which the ion flux is observed (with fast ion probes) to split into distinct fast and slowed components.

Journal ArticleDOI
TL;DR: In this paper, a model using thermal evaporation and inverse Bremsstrahlung processes is presented to show that plasma shielding occurs at approximately 0.3 GW/cm2, in agreement with experimental data for change in the mass ablation rate.

Journal ArticleDOI
TL;DR: In this article, the formation of the first monolayer of CdSe on Au(111) is described, where the first step in the ECALE cycle is the creation of an atomic layer of Se via UPD.

Journal ArticleDOI
TL;DR: In this article, the binding energies of photoelectron peaks observed for the transition metal ions were recorded and the observed surface segregation of certain elements were interpreted in terms of kinetic and thermodynamic factors.

Journal ArticleDOI
TL;DR: In this paper, the early stages of precipitation in an Al 1.1Cu1.7Mg alloy were studied using APFIM, transmission electron microscopy (TEM), and microbeam electron diffraction.