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Showing papers in "Bulletin of the American Physical Society in 2014"


Journal Article
TL;DR: In this paper, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
Abstract: Organic-inorganic perovskites have shown promise as high-performance absorbers in solar cells, first as a coating on a mesoporous metal oxide scaffold and more recently as a solid layer in planar heterojunction architectures. Here, we report transient absorption and photoluminescence-quenching measurements to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide (CH3NH3PbI(3-x)Cl(x)) and triiodide (CH3NH3PbI3) perovskite absorbers. We found that the diffusion lengths are greater than 1 micrometer in the mixed halide perovskite, which is an order of magnitude greater than the absorption depth. In contrast, the triiodide absorber has electron-hole diffusion lengths of ~100 nanometers. These results justify the high efficiency of planar heterojunction perovskite solar cells and identify a critical parameter to optimize for future perovskite absorber development.

6,454 citations


Journal Article
TL;DR: In this article, the authors report on quantum simulations using trapped ions to investigate quantum relativistic effects and spin systems and use them to make predictions on another quantum system under investigation.
Abstract: Quantum simulation makes use of a well controlled quantum system to make predictions on another quantum system under investigation. Here, we report on quantum simulations using trapped ions to investigate quantum relativistic effects and spin systems.

885 citations



Journal Article
TL;DR: Two-dimensional tin films are QSH insulators with sizable bulk gaps of 0.3 eV, sufficiently large for practical applications at room temperature and effectively tuned by chemical functionalization and by external strain.
Abstract: The search for large-gap quantum spin Hall (QSH) insulators and effective approaches to tune QSH states is important for both fundamental and practical interests. Based on first-principles calculations we find two-dimensional tin films are QSH insulators with sizable bulk gaps of 0.3 eV, sufficiently large for practical applications at room temperature. These QSH states can be effectively tuned by chemical functionalization and by external strain. The mechanism for the QSH effect in this system is band inversion at the $\ensuremath{\Gamma}$ point, similar to the case of a HgTe quantum well. With surface doping of magnetic elements, the quantum anomalous Hall effect could also be realized.

817 citations


Journal Article
TL;DR: It is concluded that individual FAs dynamically sample rigidity by applying fluctuating pulling forces to the ECM to act as sensors to guide durotaxis, and that FAK/phosphopaxillin/vinculin signaling defines the rigidity range over which this dynamic sensing process operates.

540 citations




Journal Article
TL;DR: In this paper, the authors demonstrate a novel technology for constructing large-scale electronic systems based on graphene/molybdenum disulfide (MoS2) heterostructures grown by chemical vapor deposition.
Abstract: Two-dimensional (2D) materials have generated great interest in the past few years as a new toolbox for electronics. This family of materials includes, among others, metallic graphene, semiconducting transition metal dichalcogenides (such as MoS2), and insulating boron nitride. These materials and their heterostructures offer excellent mechanical flexibility, optical transparency, and favorable transport properties for realizing electronic, sensing, and optical systems on arbitrary surfaces. In this paper, we demonstrate a novel technology for constructing large-scale electronic systems based on graphene/molybdenum disulfide (MoS2) heterostructures grown by chemical vapor deposition. We have fabricated high-performance devices and circuits based on this heterostructure, where MoS2 is used as the transistor channel and graphene as contact electrodes and circuit interconnects. We provide a systematic comparison of the graphene/MoS2 heterojunction contact to more traditional MoS2-metal junctions, as well as a theoretical investigation, using density functional theory, of the origin of the Schottky barrier height. The tunability of the graphene work function with electrostatic doping significantly improves the ohmic contact to MoS2. These high-performance large-scale devices and circuits based on this 2D heterostructure pave the way for practical flexible transparent electronics.

439 citations



Journal Article
TL;DR: In this article, the current-induced motion of skyrmions in the presence of geometrical boundaries is very different from that in an infinite plane, and it is shown that in a channel of finite width, transverse confinement results in steady-state characteristics of the SKyrmion velocity as a function of current that are similar to those of domain walls in ferromagnets, whereas the transient behaviour depends on the initial distance of the skyrmsion from the boundary.
Abstract: Magnetic skyrmions--vortex-like swirling spin structures with a quantized topological number that are observed in chiral magnets--are appealing for potential applications in spintronics because it is possible to control their motion with ultralow current density. To realize skyrmion-based spintronic devices, it is essential to understand skyrmion motions in confined geometries. Here we show by micromagnetic simulations that the current-induced motion of skyrmions in the presence of geometrical boundaries is very different from that in an infinite plane. In a channel of finite width, transverse confinement results in steady-state characteristics of the skyrmion velocity as a function of current that are similar to those of domain walls in ferromagnets, whereas the transient behaviour depends on the initial distance of the skyrmion from the boundary. Furthermore, we show that a single skyrmion can be created by an electric current in a simple constricted geometry comprising a plate-shaped specimen of suitable size and geometry. These findings could guide the design of skyrmion-based devices in which skyrmions are used as information carriers.

423 citations


Journal Article
TL;DR: In this article, the motion of a macroscopic mechanical oscillator was entangled with a propagating electrical signal and one half of the entangled state was stored in the oscillator.
Abstract: When two physical systems share the quantum property of entanglement, measurements of one system appear to determine the state of the other. This peculiar property is used in optical, atomic, and electrical systems in an effort to exceed classical bounds when processing information. We extended the domain of this quantum resource by entangling the motion of a macroscopic mechanical oscillator with a propagating electrical signal and by storing one half of the entangled state in the mechanical oscillator. This result demonstrates an essential requirement for using compact and low-loss micromechanical oscillators in a quantum processor, can be extended to sense forces beyond the standard quantum limit, and may enable tests of quantum theory.

Journal Article
TL;DR: Ferroelectricity in BaTiO3 crystals is used to tune the sharp metamagnetic transition temperature of epitaxially grown FeRh films and electrically drive a transition between antiferromagnetic and ferromagnetic order with only a few volts, just above room temperature, correspond to a magnetoelectric coupling larger than previous reports by at least one order of magnitude.
Abstract: Controlling magnetism by means of electric fields is a key issue for the future development of low-power spintronics1. Progress has been made in the electrical control of magnetic anisotropy2, domain structure3,4, spin polarization5,6 or critical temperatures7,8. However, the ability to turn on and o robust ferromagnetism at room temperature and above has remained elusive. Here we use ferroelectricity in BaTiO3 crystals to tune the sharp metamagnetic transition temperature of epitaxially grown FeRh films and electrically drive a transition between antiferromagnetic and ferromagnetic order with only a few volts, just above room temperature. The detailed analysis of the data in the light of first-principles calculations indicate that the phenomenon is mediated by both strain and field e ects from the BaTiO3. Our results correspond to a magnetoelectric coupling larger than previous reports by at least one order of magnitude and open new perspectives for the use of ferroelectrics in magnetic storage and spintronics.

Journal Article
TL;DR: In this paper, a light-emitting diodes based on vertical heterojunctions composed of n-type monolayer MoS2 and p-type silicon was realized.
Abstract: Two-dimensional (2D) materials are a new type of materials under intense study because of their interesting physical properties and wide range of potential applications from nanoelectronics to sensing and photonics. Monolayers of semiconducting transition metal dichalcogenides MoS2 or WSe2 have been proposed as promising channel materials for field-effect transistors. Their high mechanical flexibility, stability, and quality coupled with potentially inexpensive production methods offer potential advantages compared to organic and crystalline bulk semiconductors. Due to quantum mechanical confinement, the band gap in monolayer MoS2 is direct in nature, leading to a strong interaction with light that can be exploited for building phototransistors and ultrasensitive photodetectors. Here, we report on the realization of light-emitting diodes based on vertical heterojunctions composed of n-type monolayer MoS2 and p-type silicon. Careful interface engineering allows us to realize diodes showing rectification and light emission from the entire surface of the heterojunction. Electroluminescence spectra show clear signs of direct excitons related to the optical transitions between the conduction and valence bands. Our p–n diodes can also operate as solar cells, with typical external quantum efficiency exceeding 4%. Our work opens up the way to more sophisticated optoelectronic devices such as lasers and heterostructure solar cells based on hybrids of 2D semiconductors and silicon.

Journal Article
TL;DR: An alternate ‘k-walk’ theory for directed tree networks is developed, and it is rigorously proved that one node can control a set of target nodes if the path length to each target node is unique.
Abstract: Controlling large natural and technological networks is an outstanding challenge. It is typically neither feasible nor necessary to control the entire network, prompting us to explore target control: the efficient control of a preselected subset of nodes. We show that the structural controllability approach used for full control overestimates the minimum number of driver nodes needed for target control. Here we develop an alternate ‘k-walk’ theory for directed tree networks, and we rigorously prove that one node can control a set of target nodes if the path length to each target node is unique. For more general cases, we develop a greedy algorithm to approximate the minimum set of driver nodes sufficient for target control. We find that degree heterogeneous networks are target controllable with higher efficiency than homogeneous networks and that the structure of many real-world networks are suitable for efficient target control.


Journal Article
TL;DR: In this article, a real-space visualization of the formation of hydrogen bonding in 8-hydroxyquinoline (8-hq) molecular assemblies on a Cu(111) substrate, using noncontact atomic force microscopy (NC-AFM).
Abstract: Imaging Hydrogen Bonds The decoration of atomic force microscope tips with terminal CO molecules has afforded much higher resolution of the bonding of adsorbed molecules. Zhang et al. (p. 611, published online 26 September) show that this method, in combination with density function theory calculations, can image and characterize hydrogen-bonding contacts formed between 8-hydroxyquinoline molecules adsorbed on the (111) surface of copper under cryogenic conditions. At room temperature, a different bonding configuration was revealed that was the result of the molecules dehydrogenating on the copper surface and coordinating with surface copper atoms. An atomic force microscope tip bearing a single carbon monoxide molecule was used to resolve hydrogen-bonding contacts between molecules. We report a real-space visualization of the formation of hydrogen bonding in 8-hydroxyquinoline (8-hq) molecular assemblies on a Cu(111) substrate, using noncontact atomic force microscopy (NC-AFM). The atomically resolved molecular structures enable a precise determination of the characteristics of hydrogen bonding networks, including the bonding sites, orientations, and lengths. The observation of bond contrast was interpreted by ab initio density functional calculations, which indicated the electron density contribution from the hybridized electronic state of the hydrogen bond. Intermolecular coordination between the dehydrogenated 8-hq and Cu adatoms was also revealed by the submolecular resolution AFM characterization. The direct identification of local bonding configurations by NC-AFM would facilitate detailed investigations of intermolecular interactions in complex molecules with multiple active sites.

Journal Article
TL;DR: In this paper, a network of atomic clocks using non-local entangled states is proposed to achieve unprecedented stability and accuracy in time-keeping, as well as being secure against internal or external attack.
Abstract: A proposed network of atomic clocks—using non-local entangled states—could achieve unprecedented stability and accuracy in time-keeping, as well as being secure against internal or external attack.

Journal Article
TL;DR: In this article, the authors report on the observation of nearest-neighbor magnetic correlations emerging in the many-body state of a thermalized Fermi gas in an optical lattice.
Abstract: Fermionic Quantum Magnetism Optical lattices loaded with cold atoms have been used successfully as quantum simulators of condensed matter systems; however, in the case of fermionic quantum magnetism, achieving low enough temperatures has been a major obstacle. Greif et al. (p. 1307, published online 23 May; see the Perspective by Porto) selectively tuned the exchange interactions in an optical lattice of fermions, forcing a redistribution of entropy such that in the low-entropy subsystem the effective temperature was sufficiently low enough to lead to magnetic correlations. A redistribution of entropy in an optical lattice loaded with atoms leads to magnetic correlations. [Also see Perspective by Porto] Quantum magnetism originates from the exchange coupling between quantum mechanical spins. Here, we report on the observation of nearest-neighbor magnetic correlations emerging in the many-body state of a thermalized Fermi gas in an optical lattice. The key to obtaining short-range magnetic order is a local redistribution of entropy, which allows temperatures below the exchange energy for a subset of lattice bonds. When loading a repulsively interacting gas into either dimerized or anisotropic simple cubic configurations of a tunable-geometry lattice, we observe an excess of singlets as compared with triplets consisting of two opposite spins. For the anisotropic lattice, the transverse spin correlator reveals antiferromagnetic correlations along one spatial axis. Our work facilitates addressing open problems in quantum magnetism through the use of quantum simulation.

Journal Article
TL;DR: The large potential of CuInSexS2−x quantum dots as active materials for the realization of low-cost, robust and efficient photovoltaics as well as a platform for investigating various advanced concepts derived from the unique physics of the nanoscale size regime are demonstrated.
Abstract: Solution-processed semiconductor quantum dot solar cells offer a path towards both reduced fabrication cost and higher efficiency enabled by novel processes such as hot-electron extraction and carrier multiplication. Here we use a new class of low-cost, low-toxicity CuInSexS2-x quantum dots to demonstrate sensitized solar cells with certified efficiencies exceeding 5%. Among other material and device design improvements studied, use of a methanol-based polysulfide electrolyte results in a particularly dramatic enhancement in photocurrent and reduced series resistance. Despite the high vapour pressure of methanol, the solar cells are stable for months under ambient conditions, which is much longer than any previously reported quantum dot sensitized solar cell. This study demonstrates the large potential of CuInSexS2-x quantum dots as active materials for the realization of low-cost, robust and efficient photovoltaics as well as a platform for investigating various advanced concepts derived from the unique physics of the nanoscale size regime.

Journal Article
TL;DR: In this paper, the authors combine controlled unitary processes with engineered dissipation to deterministically produce and stabilize an approximate Bell state of two trapped-ion quantum bits (qubits), independent of their initial states.
Abstract: Entangled states are a key resource in fundamental quantum physics, quantum cryptography and quantum computation. Introduction of controlled unitary processes—quantum gates—to a quantum system has so far been the most widely used method to create entanglement deterministically. These processes require high-fidelity state preparation and minimization of the decoherence that inevitably arises from coupling between the system and the environment, and imperfect control of the system parameters. Here we combine unitary processes with engineered dissipation to deterministically produce and stabilize an approximate Bell state of two trapped-ion quantum bits (qubits), independent of their initial states. Compared with previous studies that involved dissipative entanglement of atomic ensembles or the application of sequences of multiple time-dependent gates to trapped ions, we implement our combined process using trapped-ion qubits in a continuous time-independent fashion (analogous to optical pumping of atomic states). By continuously driving the system towards the steady state, entanglement is stabilized even in the presence of experimental noise and decoherence. Our demonstration of an entangled steady state of two qubits represents a step towards dissipative state engineering, dissipative quantum computation and dissipative phase transitions. Following this approach, engineered coupling to the environment may be applied to a broad range of experimental systems to achieve desired quantum dynamics or steady states. Indeed, concurrently with this work, an entangled steady state of two superconducting qubits was demonstrated using dissipation.

Journal Article
TL;DR: A unified model of how charge carriers travel in conjugated polymer films is proposed and it is shown that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolescular aggregation is sufficient for efficient long-range charge transport.
Abstract: Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials.

Journal Article
TL;DR: In this article, the authors used coherent band structure effects to control phonon thermal conductance with the help of periodically nanostructured phononic crystals, which not only leads to negligible bulk phonon scattering but also increases the wavelength of the dominant thermal phonons by more than two orders of magnitude compared to room temperature.
Abstract: Controlling thermal transport has become relevant in recent years. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centres in the material (nanoparticles, impurities, etc). Here we take another approach and demonstrate that one can also use coherent band structure effects to control phonon thermal conductance, with the help of periodically nanostructured phononic crystals. We perform the experiments at low temperatures below 1 K, which not only leads to negligible bulk phonon scattering, but also increases the wavelength of the dominant thermal phonons by more than two orders of magnitude compared to room temperature. Thus, phononic crystals with lattice constants ≥1 μm are shown to strongly reduce the thermal conduction. The observed effect is in quantitative agreement with the theoretical calculation presented, which accurately determined the ballistic thermal conductance in a phononic crystal device.

Journal ArticleDOI
TL;DR: In this paper, the photoluminescence (PL) evolves from very high intensity to complete quenching, accompanied by gradual reduction and broadening of MoS2 Raman modes, indicative of distortion of the MoS 2 lattice after oxygen bombardment.
Abstract: By creating defects via oxygen plasma treatment, we demonstrate optical properties variation of single-layer MoS2. We found that, with increasing plasma exposure time, the photoluminescence (PL) evolves from very high intensity to complete quenching, accompanied by gradual reduction and broadening of MoS2 Raman modes, indicative of distortion of the MoS2 lattice after oxygen bombardment. X-ray photoelectron spectroscopy study shows the appearance of the Mo6+ peak, suggesting the creation of MoO3 disordered regions in the MoS2 flake. Finally, using band structure calculations, we demonstrate that the creation of MoO3 disordered domains upon exposure to oxygen plasma leads to a direct-to-indirect bandgap transition in single-layer MoS2, which explains the observed PL quenching.

Journal Article
TL;DR: In this paper, a three-qubit quantum error correction protocol was proposed to demonstrate the robustness of the encoded state against applied errors, paving the way towards extended quantum networks and surface-code quantum computing based on multi-qubits nodes.
Abstract: Quantum registers of nuclear spins coupled to electron spins of individual solid-state defects are a promising platform for quantum information processing. Pioneering experiments selected defects with favourably located nuclear spins with particularly strong hyperfine couplings. To progress towards large-scale applications, larger and deterministically available nuclear registers are highly desirable. Here, we realize universal control over multi-qubit spin registers by harnessing abundant weakly coupled nuclear spins. We use the electron spin of a nitrogen-vacancy centre in diamond to selectively initialize, control and read out carbon-13 spins in the surrounding spin bath and construct high-fidelity single- and two-qubit gates. We exploit these new capabilities to implement a three-qubit quantum-error-correction protocol and demonstrate the robustness of the encoded state against applied errors. These results transform weakly coupled nuclear spins from a source of decoherence into a reliable resource, paving the way towards extended quantum networks and surface-code quantum computing based on multi-qubit nodes.

Journal Article
TL;DR: This work shows that a recently developed, ultrabright femtosecond electron source makes it possible to monitor the molecular motions in the organic salt (EDO-TTF)2PF6 as it undergoes its photo-induced insulator-to-metal phase transition, and establishes the potential of ultrab right femtosingcond electron sources for probing the primary processes governing structural dynamics with atomic resolution in labile systems relevant to chemistry and biology.

Journal Article
TL;DR: A resource theory, analogous to the theory of entanglement, is developed that is relevant for fault-tolerant stabilizer computation and introduces two quantitative measures for the amount of non-stabilizer resource, including the sum of the negative entries of the discrete Wigner representation of a quantum state.

Journal Article
TL;DR: In this article, a blue pigment called copper phthalocyanine, commonly used in paints and dyes, appears to satisfy this requirement and can be easily processed into a thin-film form of the type used for device fabrication.
Abstract: Spintronics devices, which exploit the intrinsic spin of electrons as well as their charge, require precise control and read-out of electron spins. For organic semiconductors to find use in spintronic applications, it is desirable to identify molecules that possess long spin relaxation times. This paper establishes that copper phthalocyanine, a blue pigment commonly used in paints and dyes, appears to satisfy this requirement. It is inexpensive and can be easily processed into a thin-film form of the type used for device fabrication, making it a candidate material system for spin-based quantum information processing and other spintronic applications.


Journal Article
TL;DR: In this article, a phase-field method is used to solve for the moving boundary with physical membrane properties, and the authors explore the phase diagram of cell motility by varying myosin II activity and adhesion strength.
Abstract: Cell migration is a pervasive process in many biology systems and involves protrusive forces generated by actin polymerization, myosin dependent contractile forces, and force transmission between the cell and the substrate through adhesion sites. Here we develop a computational model for cell motion that uses the phase-field method to solve for the moving boundary with physical membrane properties. It includes a reaction-diffusion model for the actin-myosin machinery and discrete adhesion sites which can be in a “gripping” or “slipping” mode and integrates the adhesion dynamics with the dynamics of the actin filaments, modeled as a viscous network. To test this model, we apply it to fish keratocytes, fast moving cells that maintain their morphology, and show that we are able to reproduce recent experimental results on actin flow and stress patterns. Furthermore, we explore the phase diagram of cell motility by varying myosin II activity and adhesion strength. Our model suggests that the pattern of the actin flow inside the cell, the cell velocity, and the cell morphology are determined by the integration of actin polymerization, myosin contraction, adhesion forces, and membrane forces.

Journal Article
TL;DR: In this paper, an ultracold atom experiment investigates the behavior of one-dimensional strongly correlated fermions with a tunable number of spin components, and the results show that strongly correlated Fermions have a similar behavior as strongly correlated many-body systems.
Abstract: The physics of one-dimensional many-body systems is rich but still insufficiently understood. An ultracold atom experiment investigates the behaviour of one-dimensional strongly correlated fermions with a tunable number of spin components.