Showing papers in "Coordination Chemistry Reviews in 1988"

TL;DR: In this article, it was shown that ligand atom type and number, bond lengths, coordination geometry, and neighboring atoms (including other metals) all influence 113Cd chemical shifts.

TL;DR: In this paper, a variety of transition metal macrocyclic complexes can be easily reacted with N- and C-donor ligands L to form bisaxially coordinated monomers MacML2.

TL;DR: Theoretical models of exchange splittings (1) Ground state (2)Excited states (ii) Intensitymechanismsandselectionrules (a) Example (b) Mechanisms (iii) Orbital exchange parameters and exchange pathways (iv) Doubleexcitations (v) “Spin clusters as discussed by the authors.

TL;DR: In this paper, it was shown that the importance of the dipolar contribution depends strongly on the viscosity and metal ion, and that the relationship between geometry and the magnitude of the exchange interaction is needed in order to better understand the relationship of the bond pathway between the two paramagnetic centers.

TL;DR: In this paper, the chemistry of aluminum compounds containing sterically demanding aryloxide ligands is presented, in particular those of compounds derived from 2,6-di-tert-butyl-4-methylphenol (BHT-H, from the trivial name butylated hydroxytoluene).

TL;DR: In this paper, it was shown that myoglobin has a globin moiety that can protect the FeO 2 center from easy access of a water molecule and its conjugate anionic species.

TL;DR: Cas des additions oxydantes (d'hydrogene, d'halogenure d'alkyl, activation des liaisons C-H), d'eliminations reductrices, des carbonylations, des eliminations en β, des oligomerisations...

TL;DR: In this article, the preparation and chemical reduction and oxidation of pentavalent niobium and molybdenum complexes are discussed, as well as the corresponding catalytic functions.