Showing papers in "Energies in 2009"

A Fifteen Year Record of Global Natural Gas Flaring Derived from Satellite Data

Abstract: We have produced annual estimates of national and global gas flaring and gas flaring efficiency from 1994 through 2008 using low light imaging data acquired by the Defense Meteorological Satellite Program (DMSP). Gas flaring is a widely used practice for the disposal of associated gas in oil production and processing facilities where there is insufficient infrastructure for utilization of the gas (primarily methane). Improved utilization of the gas is key to reducing global carbon emissions to the atmosphere. The DMSP estimates of flared gas volume are based on a calibration developed with a pooled set of reported national gas flaring volumes and data from individual flares. Flaring efficiency was calculated as the volume of flared gas per barrel of crude oil produced. Global gas flaring has remained largely stable over the past fifteen years, in the range of 140 to 170 billion cubic meters (BCM). Global flaring efficiency was in the seven to eight cubic meters per barrel from 1994 to 2005 and declined to 5.6 m3 per barrel by 2008. The 2008 gas flaring estimate of 139 BCM represents 21% of the natural gas consumption of the USA with a potential retail market value of $68 billion. The 2008 flaring added more than 278 million metric tons of carbon dioxide equivalent (CO2e) into the atmosphere. The DMSP estimated gas flaring volumes indicate that global gas flaring has declined by 19% since 2005, led by gas flaring reductions in Russia and Nigeria, the two countries with the highest gas flaring levels. The flaring efficiency of both Russia and Nigeria improved from 2005 to 2008, suggesting that the reductions in gas flaring are likely the result of either improved utilization of the gas, reinjection, or direct venting of gas into the atmosphere, although the effect of uncertainties in the satellite data cannot be ruled out. It is anticipated that the capability to estimate gas flaring volumes based on satellite data will spur improved utilization of gas that was simply burnt as waste in previous years.

Thermochemical biomass gasification—a review of the current status of the technology

Abstract: A review was conducted on the use of thermochemical biomass gasification for producing biofuels, biopower and chemicals. The upstream processes for gasification are similar to other biomass processing methods. However, challenges remain in the gasification and downstream processing for viable commercial applications. The challenges with gasification are to understand the effects of operating conditions on gasification reactions for reliably predicting and optimizing the product compositions, and for obtaining maximal efficiencies. Product gases can be converted to biofuels and chemicals such as Fischer-Tropsch fuels, green gasoline, hydrogen, dimethyl ether, ethanol, methanol, and higher alcohols. Processes and challenges for these conversions are also summarized.

What is the Minimum EROI that a Sustainable Society Must Have

Abstract: Economic production and, more generally, most global societies, are overwhelmingly dependant upon depleting supplies of fossil fuels. There is considerable concern amongst resource scientists, if not most economists, as to whether market signals or cost benefit analysis based on today’s prices are sufficient to guide our decisions about our energy future. These suspicions and concerns were escalated during the oil price increase from 2005 – 2008 and the subsequent but probably related market collapse of 2008. We believe that Energy Return On Investment (EROI) analysis provides a useful approach for examining disadvantages and advantages of different fuels and also offers the possibility to look into the future in ways that markets seem unable to do. The goal of this paper is to review the application of EROI theory to both natural and economic realms, and to assess preliminarily the minimum EROI that a society must attain from its energy exploitation to support continued economic activity and social function. In doing so we calculate herein a basic first attempt at the minimum EROI for current society and some of the consequences when that minimum is approached. The theory of the

Transition Metal Carbides and Nitrides as Electrode Materials for Low Temperature Fuel Cells

Abstract: Transition metal carbides (TMCs) and transition metal nitrides (TMNs) have attracted attention as promising electrocatalysts that could replace noble metals of high price and limited supply. Relative to parent metals, TMC and TMN behave like noble metals for electrochemical reactions such as oxidation of hydrogen, CO and alcohols, and reduction of oxygen. When TMC and TMN are combined with other metals, the electrocatalytic synergy is often observed in electrochemical reactions. Thus, combinations with a minute amount of Pt or even non-Pt metals give performance comparable to heavily loaded Pt-based electrocatalysts for low temperature fuel cells. It appears that TMC based electrocatalysts are more active as anode catalysts for oxidation of fuels, whereas TMN based catalysts are more active for cathode catalysts for oxygen reduction and more stable.

A Review of Water Management in Polymer Electrolyte Membrane Fuel Cells

Abstract: At present, despite the great advances in polymer electrolyte membrane fuel cell (PEMFC) technology over the past two decades through intensive research and development activities, their large-scale commercialization is still hampered by their higher materials cost and lower reliability and durability. In this review, water management is given special consideration. Water management is of vital importance to achieve maximum performance and durability from PEMFCs. On the one hand, to maintain good proton conductivity, the relative humidity of inlet gases is typically held at a large value to ensure that the membrane remains fully hydrated. On the other hand, the pores of the catalyst layer (CL) and the gas diffusion layer (GDL) are frequently flooded by excessive liquid water, resulting in a higher mass transport resistance. Thus, a subtle equilibrium has to be maintained between membrane drying and liquid water flooding to prevent fuel cell degradation and guarantee a high performance level, which is the essential problem of water management. This paper presents a comprehensive review of the state-of-the-art studies of water management, including the experimental methods and modeling and simulation for the characterization of water management and the water management strategies. As one important aspect of water management, water flooding has been extensively studied during the last two decades. Herein, the causes, detection, effects on cell performance and mitigation strategies of water flooding are overviewed in detail. In the end of the paper the emphasis is given to: (i) the delicate equilibrium of membrane drying

Closing the Global Energy and Nutrient Cycles through Application of Biogas Residue to Agricultural Land – Potential Benefits and Drawback

Abstract: Anaerobic digestion is an optimal way to treat organic waste matter, resulting in biogas and residue. Utilization of the residue as a crop fertilizer should enhance crop yield and soil fertility, promoting closure of the global energy and nutrient cycles. Consequently, the requirement for production of inorganic fertilizers will decrease, in turn saving significant amounts of energy, reducing greenhouse gas emissions to the atmosphere, and indirectly leading to global economic benefits. However, application of this residue to agricultural land requires careful monitoring to detect amendments in soil quality at the early stages.

Global Assessment of High-Altitude Wind Power

Abstract: The available wind power resource worldwide at altitudes between 500 and 12,000 m above ground is assessed for the first time. Twenty-eight years of wind data from the reanalyses by the National Centers for Environmental Prediction and the Department of Energy are analyzed and interpolated to study geographical distributions and persistency of winds at all altitudes. Furthermore, intermittency issues and global climate effects of large-scale extraction of energy from high-altitude winds are investigated.

Transesterification of Vegetable Oils with Ethanol and Characterization of the Key Fuel Properties of Ethyl Esters

Abstract: The transesterification reactions of four different vegetable oils (sunflower, rapeseed, olive oil and used frying oil) with ethanol, using sodium hydroxide as catalyst, were studied. The ester preparation involved a two-step transesterification reaction, followed by purification. The effects of the mass ratio of catalyst to oil (0.25 – 1.5%), the molar ratio of ethanol to oil (6:1 – 12:1), and the reaction temperature (35 – 90 °C) were studied for the conversion of sunflower oil to optimize the reaction conditions in both stages. The rest of the vegetable oils were converted to ethyl esters under optimum reaction parameters. The optimal conditions for first stage transesterification were an ethanol/oil molar ratio of 12:1, NaOH amount (1% wt/wt), and 80 °C temperature, whereas the maximum yield of ethyl esters reached 81.4% wt/wt. In the second stage, the yield of ethyl esters was improved by 16% in relation with the one-stage transesterification, which was obtained under the following optimal conditions: catalyst concentration 0.75% and ethanol/oil molar ratio 6:1. The fuel properties of the esters were measured according to EN test methods. Based on the experimental results one can see that the ethyl esters do not differ significantly from methyl esters. Moreover, the results showed that the values of density, viscosity, and higher heating value of ethyl esters were similar to those of automotive and heavy duty engine diesel fuel. However, the CFPP values were higher, which may contribute to potential difficulties in cold starts. On the other hand, the flash points, which were higher than those of diesel fuel constituted a safety guarantee from the point of view of handling and storage.

A Preliminary Investigation of Energy Return on Energy Investment for Global Oil and Gas Production

Abstract: Economies are fueled by energy produced in excess of the amount required to drive the energy production process. Therefore any successful society’s energy resources must be both abundant and exploitable with a high ratio of energy return on energy invested (EROI). Unfortunately most of the data kept on costs of oil and gas operations are in monetary, not energy, terms. Fortunately we can convert monetary values into approximate energy values by deriving energy intensities for monetary transactions from those few nations that keep both sets of data. We provide a preliminary assessment of EROI for the world’s most important fuels, oil and gas, based on time series of global production and estimates of energy inputs derived from monetary expenditures for all publicly traded oil and gas companies and estimates of energy intensities of those expenditures. We estimate that EROI at the wellhead was roughly 26:1 in 1992, increased to 35:1 in 1999, and then decreased to 18:1 in 2006. These trends imply that global supplies of petroleum available to do economic work are considerably less than estimates of gross reserves and that EROI is declining over time and with increased annual drilling levels. Our global estimates of EROI have a pattern similar to, but somewhat higher than, the United States, which has better data on energy costs but a more depleted resource base.

Ethanol, Corn, and Soybean Price Relations in a Volatile Vehicle-Fuels Market

Abstract: The rapid upward shift in ethanol demand has raised concerns about ethanol’s impact on the price level and volatility of agricultural commodities. The popular press attributes much of this volatility in commodity prices to a price bubble in ethanol fuel and recent deflation. Market economics predicts not only a softening of demand to high commodity prices but also a positive supply response. This volatility in ethanol and commodity prices are investigated using cointegration, vector error corrections (VECM), and multivariate generalized autoregressive conditional heteroskedascity (MGARCH) models. In terms of derived demand theory, results support ethanol and oil demands as derived demands from vehicle-fuel production. Gasoline prices directly influence the prices of ethanol and oil. However, of greater significance for the fuel versus food security issue, results support the effect of agricultural commodity prices as market signals which restore commodity markets to their equilibriums after a demand or supply event (shock). Such shocks may in the short-run increase agricultural commodity prices, but decentralized freely operating markets will mitigate the persistence of these shocks. Results indicate in recent years there are no long-run relations among fuel (ethanol, oil and gasoline) prices and agricultural commodity (corn and soybean) prices.

Strategies for Lowering Solid Oxide Fuel Cells Operating Temperature

Abstract: Lowering the operating temperature of solid oxide fuel cells (SOFCs) to the intermediate range (500–700 oC) has become one of the main SOFC research goals High operating temperatures put numerous requirements on materials selection and on secondary units, limiting the commercial development of SOFCs The present review first focuses on the main effects of reducing the operating temperature in terms of materials stability, thermo-mechanical mismatch, thermal management and efficiency After a brief survey of the state-of-the-art materials for SOFCs, attention is focused on emerging oxide-ionic conductors with high conductivity in the intermediate range of temperatures with an introductory section on materials technology for reducing the electrolyte thickness Finally, recent advances in cathode materials based on layered mixed ionic-electronic conductors are highlighted because the decreasing temperature converts the cathode into the major source of electrical losses for the whole SOFC system It is concluded that the introduction of alternative materials that would enable solid oxide fuel cells to operate in the intermediate range of temperatures would have a major impact on the commercialization of fuel cell technology

A Review of Ultrahigh Efficiency III-V Semiconductor Compound Solar Cells: Multijunction Tandem, Lower Dimensional, Photonic Up/Down Conversion and Plasmonic Nanometallic Structures

Abstract: Solar cells are a promising renewable, carbon-free electric energy resource to address the fossil fuel shortage and global warming. Energy conversion efficiencies around 40% have been recently achieved in laboratories using III-V semiconductor compounds as photovoltaic materials. This article reviews the efforts and accomplishments made for higher efficiency III-V semiconductor compound solar cells, specifically with multijunction tandem, lower-dimensional, photonic up/down conversion, and plasmonic metallic structures. Technological strategies for further performance improvement from the most efficient (Al)InGaP/(In)GaAs/Ge triple-junction cells including the search for 1.0 eV bandgap semiconductors are discussed. Lower-dimensional systems such as quantum well and dot structures are being intensively studied to realize multiple exciton generation and multiple photon absorption to break the conventional efficiency limit. Implementation of plasmonic metallic nanostructures manipulating photonic energy flow directions to enhance sunlight absorption in thin photovoltaic semiconductor materials is also emerging.

Energy inputs in food crop production in developing and developed nations.

Abstract: Detailed energy outputs and inputs were assessed for the following crops, cultured in the U.S. and developing countries: corn, wheat, rice, soy, potato, cassava, tomato, citrus and apple. In addition, the labor input for each crop was analyzed.

Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes

Abstract: Solid oxide fuel cells (SOFC) have the advantage of being able to operate with fuels other than hydrogen. In particular, liquid fuels are especially attractive for powering portable applications such as small power generators or auxiliary power units, in which case the direct utilization of the fuel would be convenient. Although liquid fuels are easier to handle and transport than hydrogen, their direct use in SOFC can lead to anode deactivation due to carbon formation, especially on traditional nickel/yttria stabilized zirconia (Ni/YSZ) anodes. Significant advances have been made in anodic materials that are resistant to carbon formation but often these materials are less electrochemically active than Ni/YSZ. In this review the challenges of using liquid fuels directly in SOFC, in terms of gas-phase and catalytic reactions within the anode chamber, will be discussed and the alternative anode materials so far investigated will be compared.

Air Gasification of Agricultural Waste in a Fluidized Bed Gasifier: Hydrogen Production Performance

Abstract: Recently, hydrogen production from biomass has become an attractive technology for power generation. The main objective pursued in this work is to investigate the hydrogen production potential from agricultural wastes (coconut coir and palm kernel shell) by applying the air gasification technique. An experimental study was conducted using a bench-scale fluidized bed gasifier with 60 mm diameter and 425 mm height. During the experiments, the fuel properties and the effects of operating parameters such as gasification temperatures (700 to 900°C), fluidization ratio (2 to 3.33 m/s), static bed height (10 to 30 mm) and equivalence ratio (0.16 to 0.46) were studied. It was concluded that substantial amounts of hydrogen gas (up to 67 mol%) could be produced utilizing agricultural residues such as coconut and palm kernel shell by applying this fluidization technique. For both samples, the rise of temperature till 900°C favored further hydrocarbon reactions and allowed an increase of almost 67 mol% in the release of hydrogen. However, other parameters such as fluidizing velocity and feed load showed only minor effects on hydrogen yield. In conclusion, agricultural waste can be assumed as an alternative renewable energy source to the fossil fuels, and the environmental pollution originating from the disposal of agricultural residues can be partially reduced.

Experimental Study on Forced Convective Heat Transfer with Low Volume Fraction of CuO/Water Nanofluid

Abstract: The present work is an experimental study of steady state convective heat transfer of de-ionized water with a low volume fraction (0.003% by volume) of copper oxide (CuO) nanoparticles dispersed to form a nanofluid that flows through a copper tube. The effect of mass flow rate ranging from (0.0113 kg/s to 0.0139 kg/s) and the effect of inlet temperatures at 10 0 C and 17 0 C on the heat transfer coefficient are studied on the entry region under laminar flow condition. The results have shown 8% enhancement of the convective heat transfer coefficient of the nanofluid even with a low volume concentration of CuO nanoparticles. The heat transfer enhancement was increased considerably as the Reynolds number increased. Possible reasons for the enhancement are discussed. Nanofluid thermo-physical properties and chaotic movement of ultrafine particles which accelerate the energy exchange process are proposed to be the main reasons for the observed heat transfer enhancement. A correlation for convective heat transfer coefficient of nanofluids, based on transport property and

Electricity Consumption and GHG Emissions in GCC Countries

Abstract: CO2, N2O, and CH4 are the three most widespread Greenhouse Gases (GHGs). Electricity consumption and the related CO2-equivalent gas emissions resulting from oil and gas combustion for the six countries that comprise the Cooperation Council for the Arab States of the Gulf [Kingdom of Saudi Arabia (KSA), Kuwait, Bahrain, Oman, United Arab Emirates (UAE) and Qatar; also referred to as the Gulf Cooperation Council, GCC)] have been compared. The analysis of the relevant data shows that GCC countries contribute significantly to the global CO2 emissions, and that the majority of their emissions are concentrated in the energy extraction and conversion sectors, mainly from oil drilling and electricity production. Some analysis is offered as to the reasons behind the excessive increase in the electrical demand that is obviously linked to a non-rational pattern of electricity consumption.

Early ideas in underground coal gasification and their evolution

Abstract: This article follows the development of early UCG (underground coal gasification) ideas. Historical facts are discussed mainly from the technological perspective and early experiments in UCG are analyzed. Our search for the first successful UCG experiment brings to light a new finding, which was commonly overlooked in previous reviews. We also outline the key role that engineer and inventor A. G. Betts played in introducing technologies utilizing unmined coal; his original ideas are visible in the first successful UCG experiments and in modern UCG technology.

A Simple Interpretation of Hubbert’s Model of Resource Exploitation

Abstract: The well known “Hubbert curve” assumes that the production curve of a crude oil in a free market economy is “bell shaped” and symmetric. The model was first applied in the 1950s as a way of forecasting the production of crude oil in the US lower 48 states. Today, variants of the model are often used for describing the worldwide production of crude oil, which is supposed to reach a global production peak (“peak oil”) and to decline afterwards. The model has also been shown to be generally valid for mineral resources other than crude oil and also for slowly renewable biological resources such as whales. Despite its widespread use, Hubbert’s modelis sometimes criticized for being arbitrary and its underlying assumptions are rarely examined. In the present work, we use a simple model to generate the bell shaped curve curve using the smallest possible number of assumptions, taking also into account the “Energy Return to Energy Invested” (EROI or EROEI) parameter. We show that this model can reproduce several historical cases, even for resources other than crude oil, and provide a useful tool for understanding the general mechanisms of resource exploitation and the future of energy production in the world’s economy.

Energy Utilization and Environmental Aspects of Rice Processing Industries in Bangladesh

Abstract: In this study, the energy utilization and environmental aspects of the rice processing industries in Bangladesh was analyzed. Rice husk, a milling by-product of rice, is used as a source of thermal energy to produce steam for parboiling of raw rice. The rice is mostly dried on a concrete floor under the sunshine. In mechanical drying, rice husks are used as a source of primary energy. In Bangladesh, the annual estimated energy used in 2000 for the drying of rice by sunshine was 10.7 million GJ and for drying and parboiling by rice husks it was 48.2 million GJ. These amounts will increase to 20.5 and 92.5 million GJ in 2030, respectively. Electrical energy consumption for mechanical drying and milling of rice was calculated as 1.83 million GJe and 3.51 million GJe in 2000 and in 2030, respectively. Biogenic carbon dioxide emission from burning of rice husk is renewed every year by the rice plant. Both the biogenic and non-biogenic carbon dioxide emissions in 2000 were calculated as 5.7 and 0.4 million tonnes, respectively, which will increase to 10.9 and 0.7 million tonnes in 2030. The demand of energy for rice processing increases every year, therefore, energy conservation in rice processing industries would be a viable option to reduce the intensity of energy by increasing the efficiency of rice processing systems which leads to a reduction in emissions and an increased supply of rice husk energy to other sectors as well.

Investigation of the performance of a heat pump using waste water as a heat source.

Abstract: In this research, a water-water heat pump system using waste water as a heat source, a type that is not often used in Turkey and the World, was experimentally modeled. The experiments were performed under the conditions of simulated waste water temperature values of 20 °C, 30 °C and 40 °C. Inlet and outlet water temperatures of the evaporator and condenser, water flow rates in the evaporator and condenser circuits, pressures at the compressor inlet and outlet and power consumption of the system were measured. The heating coefficients of performance were calculated based on the measurements. It was found that the maximum temperature in the energy storage tank was about 50.6 °C. For the heat source temperatures of 20 °C, 30 °C and 40 °C, the heating coefficients of the performance of the system became 3.36, 3.43 and 3.69, respectively, 6 min. after the start time of the experiments and then they were decreased to 1.87, 1.83 and 1.77 with increasing water temperature in the condenser tank. The mean uncertainty value of the measurement parameters was found to be about ±2.47%. Finally, for the purpose of meeting hot water need as well as floor heating system requirements, it is seen that energy quality level of a waste low grade temperature heat source can be increased by using a heat pump system.

Enhanced Oil Recovery (EOR) by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

Abstract: An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane), model oil (n-C10, SA, toluene and 0.35 wt % asphaltene) and crude oil (10 wt % asphaltene) obtained from the Middle East. Stearic acid (SA) is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection ( 3 years) oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO2 flooding of asphaltenic oil at combined temperatures and pressures of 50 °C/90 bar and 70 °C/120 bar (no significant difference between the two cases, about 1%) compared to 80 °C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO2 flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure.

Methanol Electro-Oxidation on Pt-Ru Alloy Nanoparticles Supported on Carbon Nanotubes

Abstract: Carbon nanotubes (CNTs) have been investigated in recent years as a catalyst support for proton exchange membrane fuel cells. Improved catalyst activities were observed and attributed to metal-support interactions. We report a study on the kinetics of methanol electro-oxidation on CNT supported Pt-Ru alloy nanoparticles. Alloy catalysts with different compositions, Pt53Ru47/CNT, Pt69Ru31/CNT and Pt77Ru23/CNT, were prepared and investigated in detail. Experiments were conducted at various temperatures, electrode potentials, and methanol concentrations. It was found that the reaction order of methanol electro-oxidation on the PtRu/CNT catalysts was consistent with what has been reported for PtRu alloys with a value of 0.5 in methanol concentrations. However, the electro-oxidation reaction on the PtRu/CNT catalysts displayed much lower activation energies than that on the Pt-Ru alloy catalysts unsupported or supported on carbon black (PtRu/CB). This study provides an overall kinetic evaluation of the PtRu/CNT catalysts and further demonstrates the beneficial role of CNTs.

Reaction Engineering of Direct Coal Liquefaction

Abstract: Direct coal liquefaction has been studied and practiced since the 1930s. It was used in Germany during World War II to produce synthetic fuels when there was no oil allowed into the country. Since then, it has been studied in the United States and many different technologies have been investigated. Since the US is rich in coal resources, this is one way to be energy independent. Most of the development activity occurred in the 1980s and numerous technologies were studied, the most notable of these being H-Coal, Exxon Donor Solvent, Solvent Refined Coal, and Two Stage Liquefaction. The key elements of these technologies, particularly the reaction/reactor scheme, are discussed in this review.

Esterification of fatty acids with short-chain alcohols over commercial acid clays in a semi-continuous reactor.

Abstract: Production of fatty acid esters from stearic, oleic, and palmitic acids and short-chain alcohols (methanol, ethanol, propanol, and butanol) for the production of biodiesel was investigated in this work. A series of montmorillonite-based clays catalysts (KSF, KSF/0, KP10, and K10) were used as acidic catalysts. The influence of the specific surface area and the acidity of the catalysts on the esterification rate were investigated. The best catalytic activities were obtained with KSF/0 catalyst. The esterification reaction has been carried out efficiently in a semi-continuous reactor at 150°C temperature higher than the boiling points of water and alcohol. The reactor used enabled the continuous removal of water and esterification with hydrated alcohol (ethanol 95%) without affecting the original activity of the clay.

Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System

Abstract: The reported patent-pending system comprises a novel biohydrogen reactor with a gravity settler for decoupling of SRT from HRT. The biohydrogenator was operated for 100 days at 37 °C, hydraulic retention time 8 h and solids retention time ranging from 2.2–2.5 days. The feed was a corn-syrup waste generated as a byproduct from an industrial facility for bioethanol production located in southwestern Ontario, Canada. The system was initially started up with a synthetic feed containing glucose at concentration of 8 g/L and other essential inorganics. Anaerobicaly-digested sludge from the St. Mary’s wastewater treatment plant (St. Mary, Ontario, Canada) was used as the seed, and was heat treated at 70 °C for 30 min to inhibit methanogens. After 10 days, when the hydrogen production was steady, the corn-syrup waste was introduced to the system. Glucose was the main constituent in the corn-syrup; its concentration was varied over a period of 90 days from 8 to 25 g/L. The change in glucose concentration was used to study the impact of variable organic loading on the stability of hydrogen production in the biohydrogenator. Hydrogen production rate increased from 10 L H2/L·d to 34 L H2/L·d with the increase of organic loading rate (OLR) from 26 to 81 gCOD/L·d, while a maximum hydrogen yield of 430 mL H2/gCOD was achieved in the system with an overall average of 385 mL H2/gCOD.

Changing Energy Requirements in the Mediterranean Under Changing Climatic Conditions

Abstract: This study investigates the impacts of climate change on energy requirements in the Mediterranean. Energy requirements, especially for space heating and cooling, are closely linked to several weather variables, mainly air temperature. The analysis is based on daily temperature outputs from several regional climate models run at a resolution of 25 km × 25 km in the framework of EU project ENSEMBLES using the A1B emissions scenario. The impacts of changes in temperature on energy requirements are investigated using the concept of degree days, defined as the difference of mean air temperature from a base temperature. Base temperature should be chosen to coincide with the minimum energy consumption. In this way, changes in heating and cooling requirements between the reference and the future period are calculated and areas about to undergo large changes identified. These changes are calculated between a 30-year reference period 1961-1990 and a near future period 2021-2050 taking the ensemble mean of all regional climate models. The near-term future has been chosen instead of the frequently used end-of-the-century period to assist policy makers in their planning. In general, a decrease in energy requirements is projected under future milder winters and an increase under hotter summers.

North American Natural Gas Supply Forecast: The Hubbert Method Including the Effects of Institutions

Abstract: In this article, the U.S. and southern Canadian natural gas supply market is considered. An important model for oil and natural gas supply is the Hubbert curve. Not all regions of the world are producing oil or natural gas following a Hubbert curve, even when price and market conditions are accounted for. One reason is that institutions are affecting supply. We investigate the possible effects of oil and gas market institutions in North America on natural gas supply. A multi-cycle Hubbert curve with inflection points similar to the Soviet Union’s oil production multi-cycle Hubbert curve is used to determine North American natural gas discovery rates and to analyze how market specific institutions caused the inflection points. In addition, we analyze the latest shale natural gas projections critically. While currently, unconventional resources of natural gas suggest that North American natural gas production will increase without bound, the model here suggests a peak in North American natural gas supplies could happen in 2013.

Hydrogen as Future Energy Carrier: The ENEA Point of View on Technology and Application Prospects

Abstract: Hydrogen and fuel cells should reduce costs and increase reliability and durability to compete in the energy market. A considerable long term effort is necessary for research, development and demonstration of adequate solutions; important programs in this sense are carried out in the main industrialized countries, with the involvement of many industries, research structures and stakeholders. In such framework a relevant role is played in Italy by ENEA (Italian Agency for New Technologies, Energy and Environment). In the paper the main aspects related to the possible hydrogen role in the future society are addressed, according to ENEA perspectives.