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Showing papers in "IEEE Transactions on Dielectrics and Electrical Insulation in 2008"


Journal Article•DOI•
TL;DR: In this paper, the dielectric properties of epoxy nanocomposites with insulating nano-fillers, viz., TiO2, ZnO and AI2O3 were investigated at low filler concentrations by weight.
Abstract: The dielectric properties of epoxy nanocomposites with insulating nano-fillers, viz., TiO2, ZnO and AI2O3 were investigated at low filler concentrations by weight. Epoxy nanocomposite samples with a good dispersion of nanoparticles in the epoxy matrix were prepared and experiments were performed to measure the dielectric permittivity and tan delta (400 Hz-1 MHz), dc volume resistivity and ac dielectric strength. At very low nanoparticle loadings, results demonstrate some interesting dielectric behaviors for nanocomposites and some of the electrical properties are found to be unique and advantageous for use in several existing and potential electrical systems. The nanocomposite dielectric properties are analyzed in detail with respect to different experimental parameters like frequency (for permittivity/tan delta), filler size, filler concentration and filler permittivity. In addition, epoxy microcomposites for the same systems were synthesized and their dielectric properties were compared to the results already obtained for nanocomposites. The interesting dielectric characteristics for epoxy based nanodielectric systems are attributed to the large volume fraction of interfaces in the bulk of the material and the ensuing interactions between the charged nanoparticle surface and the epoxy chains.

566 citations


Journal Article•DOI•
TL;DR: In this article, the authors proposed an approach to estimate the arrival times of acoustic partial discharges (PD) signals in a power transformer by using robust direct solvers instead of the previously used iterative algorithms.
Abstract: The measurement of partial discharges (PD) is a non-destructive and sensitive diagnostic tool for the condition assessment of insulating systems. Two major tasks of PD measurements may be distinguished, (i) PD detection, hence providing evidence and the type of the PD and (ii) the location of the PD. The question "Where is the PD source?" is amongst others tremendously important for scheduling and starting maintenance/repair actions cost and time efficiently or to perform a risk analysis. Here the possibility to geometrically localize the flaw, by means of arrival times of acoustic PD signals, gets an extremely interesting option. Precise acoustic arrival times are consequently essential to accurately locate PD in a power transformer. The averaging of acoustic PD signals helps to enhance the acoustic sensitivity. The acoustic detection limit is lowered significantly and the determination of the arrival times is made possible for weaker PD. Supplementary steps, like automatic objective arrival time determination or additional wavelet-based de-noising further improve the overall location accuracy. A new location approach works with pseudo-times and allows for the use of robust direct solvers instead of the previously used iterative algorithms.

365 citations


Journal Article•DOI•
TL;DR: In this paper, the authors compared electric potential wells produced by a permanent dipole moment such as that of carbonyl groups (C=0) and an induced dipole consisting of MgO nanoparticles (spherical dielectrics) under a high electric field to create a trapping site for electric charge carriers.
Abstract: Space charge accumulation in low-density polyethylene film containing a small amount of MgO nanoparticles (LDPE/MgO nanocomposite film) subjected to an electric field greater than 100 kV/mm has been studied using an improved pulsed electroacoustic (PEA) system. No marked space charge accumulation was observed in LDPE/MgO nanocomposite films. To determine the mechanism of no space charge accumulation in the LDPE/MgO nanocomposite film, we compared electric potential wells produced by a permanent dipole moment such as that of carbonyl groups (C=0) and an induced dipole consisting of MgO nanoparticles (spherical dielectrics) under a high electric field to create a trapping site for electric charge carriers. The trapping depth created by the permanent dipole moment such as that of the carbonyl groups (C=0) of chemical defects is approximately 0.45 eV. However, the potential well induced by high-permittivity dielectric nanoparticles (MgO) is about 1.5 to 5.0 eV, which is much deeper than that induced by chemical defects. The suppression of space charge formation is explained using the potential well model consisting of a dipole induced by a high-permittivity dielectric nanoparticle. We explained the suppression mechanism of charge accumulation in the LDPE/MgO film that contains deep traps.

358 citations


Journal Article•DOI•
R.C. Smith1, C. Liang1, M. Landry1, J.K. Nelson1, Linda S. Schadler1 •
TL;DR: In this article, the authors present the following hypothesis for the mechanisms leading to improved properties of polymer nanocomposites with metal oxide nanoparticle fillers: the inclusion of nanoparticles provides myriad scattering obstacles and trap sites in the charge carriers' paths, effectively reducing carrier mobility and thus carrier energy.
Abstract: Polymer nanocomposites with metal oxide nanoparticle fillers exhibit enhanced electrical breakdown strength and voltage endurance compared to their unfilled or micron filled counterparts. This paper presents the following hypothesis for the mechanisms leading to improved properties. The inclusion of nanoparticles provides myriad scattering obstacles and trap sites in the charge carriers' paths, effectively reducing carrier mobility and thus carrier energy. The result is homocharge buildup at the electrodes, which increases the voltage required for further charge injection due to blocking by the homocharge. The hypothesis is supported by electroluminescence, pulsed electro acoustic analysis, thermally stimulated current measurements, a comparison of AC, DC, and impulse breakdown, as well as absorption current measurements, in silica/crosslinked polyethylene matrix composites with supporting evidence from titania/epoxy composites.

321 citations


Journal Article•DOI•
TL;DR: In this article, the influence of water absorption on the dielectric properties of epoxy resin and epoxy micro-composites and nano composites filled with silica has been studied.
Abstract: In this research, the influence of water absorption on the dielectric properties of epoxy resin and epoxy micro-composites and nano-composites filled with silica has been studied. Nanocomposites were found to absorb significantly more water than unfilled epoxy. However, the microcomposite absorbed less water than unfilled epoxy: corresponding to the reduced proportion of the epoxy in this composite. The glass transition temperatures (Tg) of all the samples were measured by both differential scanning calorimetry and dielectric spectroscopy. The Tg decreased as the water absorption increased and, in all cases, corresponded to a drop of approximately 20 K as the humidity was increased from 0% to 100%. This implied that for all the samples, the amount of water in the resin component of the composites was almost identical. It was concluded that the extra water found in the nanocomposites was located around the surface of the nanoparticles. This was confirmed by measuring the water uptake, and the swelling and density change, as a function of humidity as water was absorbed. The water shell model, originally proposed by Lewis and developed by Tanaka, has been further developed to explain low frequency dielectric spectroscopy results in which percolation of charge carriers through overlapping water shells was shown to occur. This has been discussed in terms of a percolation model. At 100% relative humidity, water is believed to surround the nanoparticles with a thickness of approximately 5 monolayers. A second layer of water is proposed that is dispersed but sufficiently concentrated to be conductive; this may extend for approximately 25 nm. If all the water had existed in a single layer surrounding a nanoparticle, this layer would have been approximately 3 to 4 nm thick at 100%. This "characteristic thickness" of water surrounding a given size of nanoparticle appeared to be independent of the concentration of nanoparticles but approximately proportional to water uptake. Filler particles that have surfaces that are functionalized to be hydrophobic considerably reduce the amount of water absorbed in nanocomposites under the same conditions of humidity. Comments are made on the possible effect on electrical aging.

268 citations


Journal Article•DOI•
TL;DR: In this paper, the authors investigated the basic electric properties of nano-sized magnesium oxide (MgO) / low-density polyethylene (LDPE) nanocomposite under DC voltage application, the volume resistivity, the space charge distribution and the breakdown strength were investigated.
Abstract: To understand basic electric properties of nano-sized magnesium oxide (MgO) / low-density polyethylene (LDPE) nanocomposite under DC voltage application, the volume resistivity, the space charge distribution and the breakdown strength were investigated. By the addition of nano-sized MgO filler, both the DC breakdown strength and the volume resistivity of LDPE increased. At the average DC electric field of about 85 kV/mm and more, a positive packet space charge was observed in LDPE without MgO nano-filler, whereas a little homogeneous space charge was observed in MgO/LDPE nanocomposite material at the front of electrode. From these results, it is confirmed that the addition of MgO nano-filler leads to the improvement of DC electrical insulating properties of LDPE.

229 citations


Journal Article•DOI•
TL;DR: In this paper, the displacement law of Fourier transformation (DSF) was used to increase the detection threshold, to improve the localization accuracy and to perform on-line measurements of Partial Discharge (PD) in noisy environments.
Abstract: The paper provides essentially a summary of PD measurements applying the UHF range in order to increase the detection threshold, to improve the localization accuracy and to perform on-line measurements of Partial Discharge (PD) in noisy environments. The electromagnetic UHF technique offers good signal to noise ratios, because external PD signals and disturbances can be shielded effectively. A new developed method allows the localization of PD in gas-insulated substations (GIS) by frequency domain measurements. The basic idea is the displacement law of Fourier transformation. The interference phenomena of superposed signals from two sensors give information about the time delay of the sensor signals. On-site PD measurements are made at cable connectors by means of monopole antennas housed in a barrel sleave, while the cable is in service. Thus a sensitive PD measurement even in noisy environment is possible. PD measurements on several 72 kV cable connectors were performed in an unshielded laboratory. On-site measurements during operation showed the great potential for condition assessment. For decoupling sensitive UHF PD signals from the inner of a power transformer tank UHF sensors applied through drain/oil valves are used. Experimental studies indicate that all relevant types of PD possibly occurring within a transformer emit high frequency spectra to be detected with UHF sensors. Furthermore in laboratory experiments and on-site measurements very moderate UHF signal attenuations have been observed.

181 citations


Journal Article•DOI•
TL;DR: In this article, the decay of surface charges on polymeric insulators in air and SF6 is studied, and three mechanisms, by volume and surface resistivity of the insulator as well as by neutralization from the gas, are investigated.
Abstract: The decay of surface charges on polymeric insulators in air and SF6 is studied. Surface charges decay by three mechanisms, by volume and surface resistivity of the insulator as well as by neutralization from the gas. These mechanisms are investigated. In particular the mechanism of gas neutralization is explained in detail. It is shown that within a certain volume ions generated by natural radiation lead to a neutralization of surface charges on specimens and can contribute significantly to surface charge decay. Relevant gas parameters like ion pair generation, ion mobility and ion-ion recombination coefficient are given for air and SF6. The decay of surface charges generated by corona discharge is simulated by taking the three mechanisms into consideration. The intention of the simulation is to quantify the effect of the individual mechanisms of the decay of surface charges and to provide the patterns needed to interpret the experimental result given in part II of this study.

174 citations


Journal Article•DOI•
L.E. Lundgaard1, W. Hansen1, S. Ingebrigtsen1•
TL;DR: In this paper, acid catalyzed ageing of oil impregnated kraft paper has been studied experimentally and five carboxylic acids (formic, acetic, laevulinic, stearic and naphtenic acid) have been added to mineral oil to reach a neutralization value of 0.4 mg KOH/g.
Abstract: Acid catalyzed ageing of oil impregnated kraft paper has been studied experimentally. Five different carboxylic acids (formic, acetic, laevulinic, stearic and naphtenic acid) have been added to mineral oil to arrive at a neutralization value of 0.4 mg KOH/g. Thereafter, kraft paper of two different humidities has been allowed to equilibrate with the oil. The results show that the lower the molecular weight of the carboxylic acids is the more is absorbed by the paper. Furthermore, a clear synergy for the paper ageing rates between moisture and the lower molecular weight acids is found, while for the higher molecular weight acids almost no effects were found. It is concluded that present techniques for measuring acidity of oils do not reflect these detailed conditions. It is suggested to introduce a new measuring technique for neutralization value where water rinsing is used to identify the content of low molecular weight, water soluble acids.

173 citations


Journal Article•DOI•
TL;DR: In this article, a series of experiments have been performed under controlled laboratory conditions with preset moisture content, and at controlled high temperature ageing, and the results were analyzed with the view of separately understanding the impacts of thermal ageing and moisture on the condition of oil and paper insulation in a transformer.
Abstract: Properties of oil and paper in a transformer degrade primarily due to thermal ageing and moisture ingress. Dielectric diagnostic tests, such as Recovery Voltage (RV), and Polarizations and Depolarization Current (PDC) measurement are currently being explored as potential tools for insulation condition assessment. A modern chemical analysis tool for paper molecular weight (MW) measurement, Gel Permeation Chromatography (GPC) or the more accurately described Size Exclusion Chromatography (SEC) promises to be useful in assessing ageing condition. However, the issue of separately assessing the impacts of ageing and moisture on oil and paper has been a key issue for many years. In the current research project, a series of experiments have been performed under controlled laboratory conditions with preset moisture content, and at controlled high temperature ageing. Whereas RV and PDC measurement results were found to be more sensitive to the moisture content of the oil and paper insulation, the MW distribution measurement by SEC provided a trend of insulation thermal ageing. This paper first provides a brief description of RVM, PDC and SEC procedures followed by a description of the experimental techniques adopted. Results are then analysed with the view of separately understanding the impacts of thermal ageing and moisture on the condition of oil and paper insulation in a transformer.

164 citations


Journal Article•DOI•
TL;DR: In this paper, the authors report the trends of dielectric permittivities and tan delta (loss tangent) of epoxy nanocomposites with single nano-fillers of Al2O3 and TiO2 at low filler concentrations over a frequency range of 1 MHz-1 GHz.
Abstract: To achieve a compact and reliable design of electrical equipment for the present day requirements, there is an urgent need for better and smart insulating materials and in this respect, the reported enhancements in dielectric properties obtained for polymer nanocomposites seems to be very encouraging. To further understand the dielectric behavior of polymer nanocomposites, this experimental work reports the trends of dielectric permittivities and tan delta (loss tangent) of epoxy nanocomposites with single nano-fillers of Al2O3 and TiO2at low filler concentrations (0.1%, 0.5%, 1% & 5%) over a frequency range of 1 MHz-1 GHz. Results show that the nanocomposites demonstrate some very different dielectric characteristics when compared to those for polymer microcomposites. Unlike the usual expectations of increasing permittivity with increasing filler concentration in polymer microcomposites, it has been seen that up to a certain nano-filler concentration and depending on the permittivity of the nano-filler, the permittivities of the epoxy nanocomposites are less than that of the unfilled epoxy at all the measured frequencies. This suggests that there is a very strong dependence of the filler concentration and nano-filler permittivity on the final permittivity of the nanocomposites at all these frequencies. But, in the case of tan delta behavior in nanocomposites, significant effects of filler concentrations were not observed with both Al2O3 and TiO2 fillers. Tan delta values in nanocomposites with Al2O3 fillers are found to be marginally lower at all filler concentrations when compared with the value for unfilled epoxy. But, in TiO2Oepoxy nanocomposites, although the variations in tan delta are not significant with respect to unfilled epoxy, some interesting trends are observed with respect to the frequencies of measurement.

Journal Article•DOI•
TL;DR: In this paper, the frequency accelerated partial discharge (PD) aging of epoxy nanocomposite with 5 wt % additions of clay was investigated in terms of PD erosion depth, and it was found that the change in the erosion depth is far smaller in specimens with clay than those without clay.
Abstract: Frequency accelerated partial discharge (PD) aging of epoxy nanocomposite with 5 wt % additions of clay was investigated in comparison with that of epoxy without clay in terms of PD erosion depth. It was found that the change in the erosion depth is far smaller in specimens with clay than those without clay. The newly developed organic modification and solubilization methods give comparable PD resistance characteristics. The latter would be more resistant to PD's than the former, if specimens were prepared properly. It was clarified that nano-micro mixed composites were superior to the single nanocomposite. Nano segmentation with some interaction zone effect is proposed as a mechanism of improvement in PD resistance.

Journal Article•DOI•
TL;DR: A wide variety of high dielectric constant (k) composite materials which have been developed and evaluated for embedded capacitor application are reviewed in this paper, where new insights into the effect of unique properties of the nanoparticle filler, filler modification and the dispersion between filler and polymer matrix on the dielectrics of the nanocomposites are discussed in details.
Abstract: In this paper, a wide variety of high dielectric constant (k) composite materials which have been developed and evaluated for embedded capacitor application are reviewed. Current research efforts toward achieving high dielectric performance including high-k and low dielectric loss for polymer composites are presented. New insights into the effect of unique properties of the nanoparticle filler, filler modification and the dispersion between filler and polymer matrix on the dielectric properties of the nanocomposites are discussed in details.

Journal Article•DOI•
TL;DR: In this article, the results of space charge evolution in cross-linked polyethylene power cables under dc electrical field at a uniform temperature and during external voltage polarity reversal are presented, showing that the mirror effect is a steady state effect that is due to cross-interface currents that depend only on the interface field and not its polarity.
Abstract: The results of space charge evolution in cross-linked polyethylene power cables under dc electrical field at a uniform temperature and during external voltage polarity reversal are presented in the paper. A mirror image charge distribution was observed in the steady state, but the pre-existing field altered the way in which the steady state charge distribution was formed from that obtaining when the cable was first polarized. Polarity reversing charge was generated in the middle of the insulation and moved towards the appropriate electrodes under the influence of a field in excess of the maximum applied field. Our results show that the mirror effect is a steady state effect that is due to cross-interface currents that depend only on the interface field and not its polarity. Measurements on cable sections with an elevated mean temperature and temperature gradient show that the interface currents are temperature dependent, and that differences between the activation energies of the interface and bulk currents can eliminate, and possibly even invert the polarity of the space charge distribution.

Journal Article•DOI•
TL;DR: In this paper, the relationship between electrical tree propagation and the material morphology in XLPE cable insulation has been studied by researching the structure and growth characteristics of a double structure electrical tree.
Abstract: This paper presents our experiments and analysis of the electrical tree growing characteristics. The relationship between electrical tree propagation and the material morphology in XLPE cable insulation has been studied by researching the structure and growth characteristics of a double structure electrical tree. It has been found that, due to the influence of uneven congregating state, difference in crystalline structure, and the existence of residual stress in semi-crystalline polymer, five types of electrical tree structures (branch, bush, bine-branch, pine-branch, and mixed configurations) would propagate in XLPE cable insulation. Three basic treeing propagation phases (initiation, stagnation, and rapid propagating phases) are presented in electrical tree propagating process. If initiation phase is very active, the single branch tree will propagate while if this phase is weak then the bush tree will occur more easily. There would be a clear double structure of electrical tree when it grows at submicroscopic structure uneven region of the material. A new parameter, the expansion coefficient is introduced to describe the electrical tree propagation characteristics. In addition, two other coefficients being used to describe our experimental results are dynamic fractal dimension and growth rate of electrical tree.

Journal Article•DOI•
TL;DR: A detailed study of the effect of ageing, temperature and moisture on frequency and time domain spectroscopic measurements carried out on oil-impregnated pressboard samples as well as on a distribution transformer under controlled laboratory conditions is reported in this article.
Abstract: For reliable operation of power transformers, the condition of the insulation system is essential. This paper reports on a detailed study of the effect of ageing, temperature and moisture on frequency and time domain spectroscopic measurements carried out on oil-impregnated pressboard samples as well as on a distribution transformer under controlled laboratory conditions. Because field measurements are generally performed after de-energizing the transformer, extreme care is required in interpreting the results due to inherent temperature instabilities. To avoid large thermal variations that may affect the results, a customized adiabatic room was built around the transformer for measurements above the ambient. Capacitance ratio and direct current conductivity deduced from the spectroscopic measurements, helped to interpret the data. Because, low frequency measurements techniques are time consuming, alternative to a transfer of time domain data into frequency domain data was investigated.

Journal Article•DOI•
TL;DR: In this paper, the effect of preprocessing the alumina nanoparticles before preparation of the composite was investigated, and a direct correlation was observed between the improvement of the resistance of a composite to surface degradation and the ability of the pre-processed nanoparticles to form strong bonds with the neighboring epoxy.
Abstract: Insulating materials in power apparatus are often exposed to surface discharges in the course of normal operation, resulting in deterioration of the material surface. In an earlier work, the authors have shown that the inclusion of nanometric particles (Al2O3) improves the ability of a polymeric dielectric (epoxy) to resist degradation when exposed to surface discharges. In the current work, the effect of pre-processing the alumina nanoparticles before preparation of the composite, is investigated. Laser Surface Profilometry (LSP) was used to measure the degradation of the composite specimens after exposure to surface discharges. The use of a surfactant, viz. Sodium Dodecyl Sulfate (SDS) was found to be ineffective. However, the simple action of heating the nanoparticles before use, improved the resistance of the bulk composite to surface discharges. Further, the particles were functionalized using 3-glycidoxy-propyltrimethoxysilane (GPS). This process greatly enhanced the ability of the nanocomposite to resist surface degradation. In fact, best results were obtained when the particles were first heated and then coated with GPS. Fourier Transform Infra-Red (FTIR) spectroscopy and other techniques were used to investigate chemical changes at the particle-epoxy interfaces. A direct correlation was observed between the improvement of the resistance of the composite to surface degradation and the ability of the pre-processed nanoparticles to form strong bonds with the neighboring epoxy. Effect of pre-processing particles of larger dimensions (platelets) was negligible compared to nanoparticles, indicating the possible importance of the interfacial surface to volume ratio of the fillers.

Journal Article•DOI•
TL;DR: In this article, the decay of surface charges on polymeric insulators in air and SF6 is studied and the influence of the test setup and particularly the size of the storage volumes on the charge decay is shown.
Abstract: The decay of surface charges on polymeric insulators in air and SF6 is studied. Surface charge decay by three mechanisms, i.e. by volume and surface resistivity of the insulator as well as charge neutralization by gas ions has been simulated individually in part I. In this part the simulations of the surface charge decay are verified by experiments with insulating plates made of polytetrafluorethylen (PTFE), silicone rubber (SIR) and epoxy resin (EP). The surface charge distribution is generated by corona discharge and the charge decay is simulated by taking all three mechanisms into consideration. The influence of the test setup and particularly the size of the storage volumes on the charge decay are shown in air and SF6.

Journal Article•DOI•
TL;DR: In this paper, the authors used Weibull and Gaussian distributions to estimate the breakdown voltage of synthetic esters, a natural ester and a mineral oil to evaluate the compatibility of ester oils with existing transformer insulation.
Abstract: Recent decades have seen the rapid and successful deployment of ester oils as transformer dielectrics. When evaluating the compatibility of ester oils with existing transformer insulation designs, it is essential to not only compare the mean breakdown voltages of the oils, but also to consider the role of dispersion and thus the withstand voltage levels (with the acceptable breakdown likelihood). Insulation designers sometimes estimate the withstand voltage of mineral oil from the dispersion of the data, assuming that the breakdown voltages of the oil follow a parametric distribution. However, there is a lack of discussion as to whether this method would be suitable for estimating the withstand voltages of ester oils. This paper uses samples of breakdown voltages of a synthetic ester, a natural ester and a mineral oil to analyze their distributions, and discusses the applicability of using Weibull and Gaussian distributions to estimate the withstand voltages of the esters. It is found that the distributions of ester breakdown voltages, in particular the lowest breakdown voltage, are similar to those of mineral oil. Consequently there is evidence that from the ac withstand voltage point of view the tested esters are compatible for the use in power transformers.

Journal Article•DOI•
TL;DR: In this paper, the frequency dependence of partial discharges in a disc-shaped cavity is investigated and a charge consistent model is presented and used to dynamically simulate the sequence of PDs in the cavity.
Abstract: In this paper partial discharges (PD) in a disc-shaped cavity are measured at variable frequency (0.01 - 100 Hz) of the applied voltage. The measured PD phase and magnitude distributions, as well as the number of PDs per voltage cycle, changed with the varying frequency. A charge consistent model is presented and used to dynamically simulate the sequence of PDs in the cavity. The simulation results show that the properties of the cavity surface, mainly the surface conductivity and the surface emission of electrons, change with the varying applied frequency. This is interpreted as an effect of the difference in time between consecutive PDs at different applied frequencies. This is the second of two papers addressing the frequency dependence of PD in a cavity. The first paper described how the PD frequency dependence changes with the applied voltage amplitude, the cavity size and the cavity location.

Journal Article•DOI•
TL;DR: In this paper, a knowledge-based decision support system is proposed to provide engineers with a comprehensive diagnosis of the defects responsible for partial discharge activity detected in oil-filled power transformers.
Abstract: The abstraction of meaningful diagnostic information from raw condition monitoring data in domains where diagnostic expertise and knowledge is limited and constantly evolving presents a significant research challenge. Expert diagnosis and location of partial discharges in high voltage electrical plant is one such domain. This paper describes the functionality of a knowledge-based decision support system capable of providing engineers with a comprehensive diagnosis of the defects responsible for partial discharge activity detected in oil-filled power transformers. Plant data captured from partial discharge (PD) sensors can be processed to generate phase-resolved partial discharge (PRPD) patterns. This paper proposes a means of abstracting the salient features characterizing the observed PRPD patterns. Captured knowledge describing the visual interpretation of these patterns can be applied for defect diagnosis and location. The knowledge-based PRPD pattern interpretation system can support on-line plant condition assessment and defect diagnosis by presenting a comprehensive diagnosis of PD activity detected and classification of the defect source. The paper also discusses how the system justifies its diagnosis of the PD activity to offer the expert greater confidence in the result, a feature generally absent in 'black-box' pattern recognition techniques. The incremental approach exhibited by the system reflects that of a PD expert's visual interpretation of the PRPD pattern. The paper describes how this functional system design has evolved from the approach taken by PD experts to the visual interpretation of PRPD patterns.

Journal Article•DOI•
TL;DR: In this article, the authors investigated the use of CF3I, which has lower Global Warming Potential (GWP), as a substitute gas for SF6 in gas insulated switchgear and gas circuit breakers.
Abstract: Our research has investigated the use of CF3I, which has lower Global Warming Potential (GWP), as a substitute gas for SF6. The use of pure CF3I in gas insulated switchgear (GIS) and gas circuit breakers (GCB) is difficult because liquid CF3I has a high boiling point. We have therefore mixed CF3I with CO2 or N2. By investigating the decomposed gas after a current interruption, we have shown that the iodine density from CF3I-CO2(30%-70%) is about 1/3 of that of pure CF3I. In addition, no fluorine was detected from the gas mixture. Our investigation of the breakdown voltage characteristics has shown that the dielectric strength of CF3I-CO2 (30%-70%) is about 0.75 to 0.80 times that of SF6. In breaker terminal fault (BTF) and short line fault (SLF) interruption, CF3I-CO2 is superior to CF3I-N2. Because of the high boiling point of CF3I, the proportion of CF3I should be small. In BTF interruption, the performance approximates to that of pure CF3I when the proportion of CF3I exceeds 30%. Similarly, the SLF interruption performance approximates to that of pure CF3I when the proportion of CF3I exceeds 20%.

Journal Article•DOI•
TL;DR: In this article, the authors measured DC and ac impedance measurements in air and in vacuum on samples of low density polyethylene to which nano-sized and micro-sized ZnO particles and a dispersant had been added.
Abstract: DC conductivity and ac impedance measurements were made in air and in vacuum on samples of low density polyethylene to which nano-sized and micro-sized ZnO particles and a dispersant had been added. The samples were 150-200 mum thick. The temperature range was 30-70degC. The temperature dependence of the vacuum dc conductivity in samples containing the dispersant and 10% w/w nanosized ZnO followed an Arrhenius relationship closely, the conductivity being 1-2 orders of magnitude lower than that of a sample containing dispersant only. The addition of 10% w/w microsized ZnO had very little effect on the dc conductivity. The ac measurements were made in the frequency range 10 mHz-1 MHz. Addition of nanoparticles increased the ac conductivity at higher frequencies but decreased it at lower frequencies, the cross-over frequency increasing with increasing temperature. The real part of the relative permittivity of samples with nanoparticles was increased relative to that of samples containing dispersant only, at all temperatures, but the corresponding values in samples with microparticles were unchanged, within experimental error. Space charge profiles were obtained using the laser-intensity-modulation-method (LIMM). Space charge densities of order 300 Cm-3 were measured in the bulk near the electrodes, several hours after poling at field strengths around 30 kV/mm.

Journal Article•DOI•
TL;DR: In this paper, the effect of inclusion of nanometric particles on the ability of a polymeric dielectric to resist degradation when exposed to surface discharges was investigated, and the degradation was greater for unfilled epoxy specimens than that for filled ones.
Abstract: Recent research has indicated that dielectric properties of polymer insulating materials might be improved by the inclusion of nanosized particles dispersed in the polymer matrix. Insulating materials in power apparatus are often exposed to surface discharges in the course of normal operation. Surface degradation due to continued exposure to such discharges may cause deterioration of the surface, and could ultimately lead to catastrophic failure. The current work investigates the effect of inclusion of nanometric particles on the ability of a polymeric dielectric to resist degradation when exposed to surface discharges. The dielectric material used was epoxy resin, while nanosized alumina (Al2O3) and titania (TiO2) were used as fillers. Surface discharge tests were carried out on the specimens. The degraded surfaces were studied using a scanning electron microscope (SEM). Surface roughness measurements were made using a laser surface profilometer (LSP). It was observed that the degradation was greater for unfilled epoxy specimens than that for filled ones. Atomic force microscopy (AFM) and energy dispersive X-ray analysis (EDX) were used to identify surface changes in the dielectric material due to degradation. It has been conclusively shown that addition of even very small volume fractions of nanoparticles increases the resistance of the material to degradation due to surface discharges. A possible mechanism for surface degradation in nanocomposites has been proposed.

Journal Article•DOI•
TL;DR: Experimental results show that the dc PD detection system developed with artificial intelligence methodologies is practical and effective, and several methods to improve separability of the grouping technique are given, including threshold value grouping, marginal coordinates grouping based on 2D parameters plane and grouping using ETFM preprocessed by wavelet denosing.
Abstract: In this paper, a digital dc PD pulse detection system with bandwidth of 10 kHz - 40 MHz is introduced, which was developed using some artificial intelligence methodologies. Focus is made on digital detection, grouping and classification of random pulse signals generated by PD phenomena at dc voltage. Digital detection is developed only resorting to a band-pass filter, a high-speed digitizer (100 MS/s) and a PC with data processing software. Grouping is realized with feature extraction of pulse waveshapes using equivalent time-frequency method (ETFM), making the 2D parameters plane or 3D parameters space, then using the unsupervised clustering Fuzzy C-Means (FCM) method to achieve fast separation for pulse sequence. And classification resorts to least square support vector machine (LS-SVM) based on a fingerprint, which is derivate form 2D histograms of basic parameters, the discharge magnitude q and the time between discharges Deltat of each sub-group. Field application is made for typical defects of oil-paper insulation under dc voltage. At last, several methods to improve separability of the grouping technique are also given for some special cases, including threshold value grouping, marginal coordinates grouping based on 2D parameters plane and grouping using ETFM preprocessed by wavelet denosing. Experimental results show that the dc PD detection system developed with artificial intelligence methodologies is practical and effective.

Journal Article•DOI•
TL;DR: In this article, the effect of nanofillers on the bulk and surface structures of polyamide/mica nanocomposites was investigated and it was revealed from X-ray diffraction and permittivity measurements that the nanofiller loading increases crystallinity of the resin and restricts the molecular motion.
Abstract: Degradation profiles induced by partial discharges and those induced by oxygen plasmas are compared for polyamide/mica nanocomposites. Both the resistances to partial discharges and to plasmas improve with an increase in nanofiller content. On the other hand, the partial discharge resistance is not improved if mum-sized glass fibers are added to polyamide. In order to investigate these phenomena, the superior resistance mechanism of nanocomposites is discussed, focusing on the effects of the nanofillers on the bulk and surface structures of the resin. It was revealed from X-ray diffraction and permittivity measurements that the nanofiller loading increases crystallinity of the resin and restricts the molecular motion. This should enhance the resistance to degradation. Furthermore, observation results by scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction revealed that the nanofillers had piled up themselves to form a layered structure on the sample surface in an early stage of degradation. Such a structure acts as a barrier against impact of charged particles and diffusion of gases such as oxygen, which should contribute to the improvement of resistance to degradation as its direct effect and also as its indirect effect by suppressing the oxidation of resin. Moreover, it was also revealed from scanning electron microscopy that the nanofillers impede the growth of surface cavities by partial discharges drastically.

Journal Article•DOI•
TL;DR: In this article, a cross-equipment evaluation of partial discharge detection techniques for typical power apparatuses including gas insulated switchgear, oil-immersed transformers, and power cables is presented.
Abstract: Partial discharge (PD) measurement allows detection of insulation defects in various electric power apparatus before an insulation failure occurs. It can also improve the reliability of the insulation performance of apparatus, and support rational and economical design, lifetime prediction, and nondestructive inspection. Historically speaking, PD detection methods have evolved in each category of apparatus and power cables. However, there does not seem to exist what we call universality in PD detection technology that is available to all kinds of power equipment. This article specifically describes features, similarities, and differences of partial discharge measurement and diagnosis technologies for electric power apparatus used in transmission and distribution. The main task of this article lies in not simply reviewing PD measurement and diagnosis techniques but trying a cross-equipment evaluation. First, this article deals with similarities and differences among partial discharge detection techniques for typical power apparatuses including gas insulated switchgear, oil-immersed transformers, and power cables. In particular electrical measurement technology and electromagnetic measurement technology are compared selectively. The second subject is to describe signal-processing technologies, and discuss similarities and differences among equipment in terms of noise removal, location identification, and foreign particle identification. Finally, judgment methods and judgment criteria for equipment diagnoses as a whole are analyzed and described. These discussions are expected to clarify the positioning of the partial discharge measurement technologies for various equipment among all electric power apparatus, and support technological development in the future.

Journal Article•DOI•
TL;DR: In this paper, the attenuation of UHF signals within power transformers is investigated, and the so-called Sensitivity Check might show in future a relation between unconventionally measured UHF quantities to the apparent charge level in pico Coulomb.
Abstract: The reliability of electrical energy networks depends on the quality and availability of electrical equipment like power transformers. Local failures inside their insulation may lead to catastrophic breakdowns and might cause high outage and penalty costs. To prevent these destructive events power transformers are e.g. tested for partial discharge (PD) activity before commissioning and currently also during service. The current work deals with the electromagnetic PD detection method, also known as UHF method. The disadvantage of the UHF method is still the missing possibility for a calibration or at least a verification of the sensitivity. The so-called Sensitivity Check might show in future a relation between unconventionally measured UHF quantities to the apparent charge level in pico Coulomb. An important aspect is the attenuation of UHF signals within power transformers which is investigated in this paper.

Journal Article•DOI•
TL;DR: In this article, partial discharges in disc-shaped cavities in polycarbonate are measured at variable frequency (0.01-100 Hz) of the applied voltage, and it is suggested that the PD frequency dependence is governed by the statistical time lag of PD and the surface charge decay in the cavity.
Abstract: In this paper partial discharges (PD) in disc-shaped cavities in polycarbonate are measured at variable frequency (0.01-100 Hz) of the applied voltage. The advantage of PD measurements at variable frequency is that more information about the insulation system may be extracted than from traditional PD measurements at a single frequency (usually 50/60 Hz). The PD activity in the cavity is seen to depend on the applied frequency. Moreover, the PD frequency dependence changes with the applied voltage amplitude, the cavity diameter, and the cavity location (insulated or electrode bounded). It is suggested that the PD frequency dependence is governed by the statistical time lag of PD and the surface charge decay in the cavity. This is the first of two papers addressing the frequency dependence of PD in a cavity. In the second paper a physical model of PD in a cavity at variable applied frequency is presented.

Journal Article•DOI•
TL;DR: In this paper, the authors evaluated different time-of-arrival algorithms in order to determine which method yields most accurate location under different circumstances, including sensitivity to noise, pulse shape and effect of load impedance.
Abstract: Accurate location of the origins of partial discharges in power cable systems, based on arrival times, is imperative for the identification and assessment of defects. This paper evaluates different time-of-arrival algorithms in order to determine which method yields most accurate location under different circumstances. These methods are based on trigger level, Akaike Information Criterion, energy criterion, Gabor's signal centroid and phase in frequency domain. Several criteria are defined by which the algorithms are evaluated. These criteria include the sensitivity to noise, pulse shape and effect of load impedance. The sensitivity of the methods upon varying these quantities is evaluated analytically and by means of simulations. Further, the methods are tested on a medium-voltage cable system by injecting PD pulses in a cable with one joint. Each algorithm is applied to the measured pulses and the resulting location is compared with the known joint location. From the results the energy criterion method and the phase method show the best performance.