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Showing papers in "Industrial & Engineering Chemistry Process Design and Development in 2020"

Journal Article•
Reaction Mechanism Dominated by the Hard–Soft Acid–Base Theory for the Oxidation of CH₂Cl₂ and CH₃Br over a Titanium Oxide-Supported Ru Catalyst

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Lirong Lv, Sheng Wang, Ya Ding, Lei Zhang, Yang Gao, Shudong Wang 
01 Jan 2020-Industrial & Engineering Chemistry Process Design and Development
TL;DR: In this paper, the divergent behaviors were elucidated for CH₂Cl and CH‚Br oxidation over TiO‚ and Ru/TiO ‚, concluding that the adsorption and activation of halogenated volatile organic compounds were strongly dependent on the hard-soft acid base theory.
Abstract: In this study, the divergent behaviors were elucidated for CH₂Cl₂ and CH₃Br oxidation over TiO₂ and Ru/TiO₂. Possible reaction mechanisms were elucidated. It was concluded that the adsorption and activation of halogenated volatile organic compounds were strongly dependent on the hard–soft acid–base theory.

2 citations