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Showing papers in "Inorganic and Nuclear Chemistry Letters in 1977"


Journal ArticleDOI
TL;DR: In this paper, the effects of self-irradiation damage at room temperature in the americium-241 oxides were investigated using X-ray powder diffraction techniques, and the spontaneous transformation over a period of several years of the room-temperature cubic form of the sesquioxide into the hexagonal high temperature form was presented.

66 citations



Journal ArticleDOI
TL;DR: In this article, a phenomenological model is developed to explain the exponential time dependencies commonly observed for the lattice parameter, a, of actinide compounds, i.e., Δ a a = A (1− e − Bt ).

32 citations









Journal ArticleDOI
TL;DR: In this article, the Gibbs free energy of formation of ThCl4 in (LiK)Cl and a comparison with similar data obtained in (Na K)Cl were made.


Journal ArticleDOI
TL;DR: In this paper, the synthesis and characterization of red crystalline compounds corresponding to the formula [Ni(S2COR)2(P(C4H9)3)2] are reported (R = ethyl, isobutyl).

Journal ArticleDOI
TL;DR: In this article, N-donor bifunctional ligands form bridges between adjacent Ni cyanide planes, leading to rigid tridimensional structures which, in some cases, can behave as host lattices.

Journal ArticleDOI
TL;DR: In this article, a σ-bonded organoactinide complex of the type Ind 3 AnR (where Ind = η 5 C 9 H 7, An = Th or U and R = CH 3 or n−C 4 H 9 ) has been prepared.


Journal ArticleDOI
TL;DR: Bis(2-chloroethoxy)dichlorotitanium(IV) and bis(2, 2,2-trifluoroethoxy)- dichlorotite (IV) have been prepared and the presence of new band around 510-540 cm −1 in their i.r. spectra suggest them to be dimeric through alkoxy bridges.




Journal ArticleDOI
W. Massa1
TL;DR: In this article, nach einer anderen Methode auch CsMnF4 und NH4MnFs4 rein darzustellen und aufgrund der rontgeno-graphischen Pulverdaten Hinweise auf die bisher unbekannten Strukturen der AMnF5-Verbindungen zu gewinnen.






Journal ArticleDOI
TL;DR: In this article, the salting effects of Δ-(−) 589 -Ni(phen) 3 2+ on the solubility of racemic M(acac) 3 (M = Cr and Co) were investigated.


Journal ArticleDOI
TL;DR: In this paper, it was shown that metal complexes of N,N'-ethylenebis(acetylacetonimine) (I), hereafter abbreviated as M(acac)2en, react with ~-nitrobenzenediazonium tetrafluoroborate to give the substituted products.