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Showing papers in "Inorganic and Nuclear Chemistry Letters in 1980"



Journal ArticleDOI
TL;DR: In this article, it was shown that even when tin envirnoments are averaged by intramolecular rearrangement, the number of tin atoms in the molecule can be deduced from the ll9sn NMR because of the fortuitous presence of ll 9sn-ll 7sn coupling.

28 citations



Journal ArticleDOI
TL;DR: In this paper, air-equilibrated suspensions of 238 Pu and 239 Pu compounds in dilute salt solutions produced HNO 3 at a rate which increased with the H + concentration.

25 citations


Journal ArticleDOI
TL;DR: Reduction potentials for twenty-three beta-substituted free base porphyrins are reported, along with substituent partial potentials and correlations are made with Porphyrin basicity and reactivity as discussed by the authors.

24 citations



Journal ArticleDOI
TL;DR: In this article, the crystal and molecular structure of a lithium picrate complex of benzo-15-crown-5 was reported, which is the first x-ray crystallographic study of a lithlum cation system.

22 citations


Journal ArticleDOI
TL;DR: The solid electrolytes Li2+2xZn1−xGeO4 (LISICON) are solid solutions between the HTLi3PO4 type and the olivine type as discussed by the authors.

22 citations


Journal ArticleDOI
TL;DR: In this paper, a high-temperature conproportionation of molybdenum with its pentachloride or tetrabromide was obtained in the presence of sodium halide.

20 citations


Journal ArticleDOI
TL;DR: A 1:1 adduct between chlorotriphenyltin and cis-1,2-bis(diphenylphosphinyl)ethylene has been synthesized and characterized in this paper.

18 citations




Journal ArticleDOI
TL;DR: In this article, the properties of oxamic acid complexes with Zn(II), Cd(II) and Hg(II ) were investigated using analytical, conductometric and IR spectral data.


Journal ArticleDOI
TL;DR: The electrochemical oxidation of gallium or cobalt in the presence of CH3CN + (C6H5)3P + HX (X  Cl, Br, I) or CoCl42− in good crystalline form was studied in this paper.




Journal ArticleDOI
TL;DR: CfAs and CfSb exhibit the NaCl-type, cubic structure with lattice parameters of 5.809 A and 6.166 A, respectively as mentioned in this paper, and the six-coordinate crystal radius of californium in both compounds was calculated to be 0.912 A.




Journal ArticleDOI
TL;DR: The selectivity properties of polymeric Schiff bases derived from 5,5′-methylene-bis-salicylaldehyde in complexing with different metal ions have been investigated as discussed by the authors.

Journal ArticleDOI
TL;DR: In this paper, the binuclear structure of [Cr(O2CCH3)2(OH2)]2 is destroyed in liquid ammonia from which Cr(NH3)4(O 2CCH 3)2 has been isolated.

Journal ArticleDOI
TL;DR: In this article, einen Komplex mit Uran in einem Oxidationszustand von weniger als + 3 darzustellen, erhielt man durch Einwirkung von K-cyclopentadienid auf UCl4 in THF unter Ruckflus in Gegenwart von metallischem Na nach einer Reaktionsdauer von 5 Tagen bis zum Verbrauch des Na and einer Fortsetzung der Reaktion fur weitere 5 T

Journal ArticleDOI
TL;DR: In this article, the properties of XHgCN (X = Cl, Br, I, OAc, CF 3 SO 3, SCN, SPh, SEt and Ph) have been determined and discussed.


Journal ArticleDOI
TL;DR: In this paper, the isoelectronic-isolobal description of units in boranes, metalloboranes and metallo-clusters is examined with self-consistent charge calculations.