Showing papers in "Inorganica Chimica Acta in 2011"

TL;DR: The main challenge for the future will be to achieve photolytic liberation of carbon monoxide by near-IR excitation in the phototherapeutic window of the cell, and different ways how this goal might be achieved are discussed.

TL;DR: In this paper, the molecular structures of ligand and its copper(II) complex have been determined by single crystal X-ray diffraction technique, and the structure of the complex is stabilized by intermolecular π-π stacking and C-H⋯π interactions.

TL;DR: In this article, the structure of 1H-benzimidazol-2-ylmethyl)-(4-nitro-phenyl)-amine (L) and its Pd-II and Pt-II complexes have been elucidated using a variety of physico-chemical techniques.

TL;DR: In this paper, the characters of the electronic transitions are visualized and analyzed using electron density redistribution maps, and the reduced and excited states can be approximately formulated as [(ReCl)-Cl-I(CO)(3)(N,N-center dot)] and /[ReCl]-Cl-II(CO)(3) n,N center dot)], respectively.

TL;DR: In this paper, the synthesis and characterization of Pd(II) complexes with the general formula cis-[Pd(L-O,S)2] (HL=N,N-diethyl-N′-benzoylthiourea, N, N-diisobutyl N′-butyl-n′-Benzoy-lthIourea or N,Ndiisopropyl N''-benziourea) were reported.

TL;DR: In this article, a tridentate Schiff base ligand, 2-pyridyl-N-(2′-methylthiophenyl)methyleneimine (pmtpm) was synthesized and characterized by various spectroscopic methods and by X-ray crystallography.

TL;DR: In this paper, the influence of carboxylate anions with different flexibility on the construction of different network topology in the self-assembly process has been discussed, and the thermal stabilities and the voltammetric behavior of complexes 1-4 have been reported.

TL;DR: The biologically important pyridoxinato(1−) ligand (anionic vitamin B6) showed the rare phenolate-hydroxymethyl chelation plus bridging mode through the pyridine-nitrogen atom towards zinc(II) to give the one-dimensional (1D) coordination polymer {(acetato-κO)-aqua-μ-[2-methyl-3-oxy-4,5-di(hydroxmethyl)pyridine)-κN:O,O′]zinc(II)}·monohydrate

TL;DR: In this article, the authors have demonstrated profound influence of solvent in ion selectivity, in acetonitrile-chloroform they formed complexes with Hg 2+, Pb 2+, Cu 2+ and Ni 2+.

TL;DR: Two copper(II) complexes with L 1 and L 2 ligands, respectively, have been synthesized and characterized and the interaction of both the complexes with DNA has been studied to explore their poten-tial biological activity.

TL;DR: In this article, the lutidinium boro-formate salt [LutH+][HC( O)OB(C6F5)3−] was fully characterized including an X-ray crystal structure and independent synthesis from formic acid and lutidine-tris(pentafluorophenyl)borane.

TL;DR: Using the click protocol, the new ligands 1-(cyclohexyl)-4-(2-pyridyl)-1,2,3-triazole (1), 1-(trifluoromethyl phenyl), 4-(2,pyridine), 1, 2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,20,21,22,23,24,25,26,27,28,30,31,

TL;DR: In this article, a detailed account on mononuclear vinyl ruthenium complexes of the type RuCl(CH CHR′)(CO)(PR 3 ) 2 L 2 (μ-CH CH-bridge-CHCH) is presented.

TL;DR: In this article, the properties and properties of three ion pair compounds [C5H7N2]3[BiCl6] (1), [C10H10N2]-2[Bi2Cl10] (3) have been described.

TL;DR: In this paper, six new cis-dioxomolybdenum(VI) complexes of chiral Schiff-base ligands, derived from condensation of various amino alcohols and substituted salicylaldehydes, have been prepared and characterized by NMR,IR, ESI-MS and single crystal X-ray diffraction techniques.

TL;DR: In this paper, two mixed ligand silver(I) complexes of formulae {Ag(tpp)3(asp)](dmf)} were synthesized and characterized by elemental analyses, spectroscopic techniques and X-ray crystallography at ambient conditions.

TL;DR: In this article, several nickel bis(dithiolene) complexes with strong and broad absorptions in the Near-IR (NIR) region (700-1100 nm) were synthesized by using green and simple synthetic routes.

TL;DR: In this paper, the zinc(II) complexes of thiones having the general formula [ZnL2Cl2] were prepared by reacting ZnCl2 with the corresponding thions.

TL;DR: In this article, the synthesis of two new sodium perchlorate adducts (1:2 and 1:3) with copper(II) "ligand-complexes" is reported.

TL;DR: In this article, a pyrene and rhodamine-6G functionalized simple chemosensor L is studied toward sensing of metal ions in solution extensively, which shows selective color change from colorless to pink in the presence of Hg 2+ in acetonitrile.

TL;DR: In this article, the reaction of thiosemicarbazones of salicylaldehyde, 2-hydroxyacetophenone and 2hydroxynaphthaldehyde with Ni(ClO4)2·6H2O, using 2,2′-bipyridine as coligand, afforded three dinuclear complexes (1a, 1b and 1c).

TL;DR: In this paper, an azocoupling of diazonium salt of 2-hydroxyaniline with 1-phenylbutane-1,3-dione (H2L) was presented.

TL;DR: Several mononuclear copper complexes 1(a,b) and 2(a-b) supported over sterically demanding [NNO] ligands, such as N-(aryl)-2-[(pyridin-2-ylmethyl)amino]acetamide [aryl = 2,6-diethylphenyl (1) and mesityl (2)], exhibit catecholase-like activity in performing the aerial oxidation of 3,5-di-t-butylcatehol (3,5)-DTBC) to 3

TL;DR: In this paper, a ruthenium(II) complex, [Ru(bpy)2(Htip)]Cl2, has been synthesized and characterized by 1H NMR spectroscopy, elemental analysis, and mass spectrometry.

TL;DR: In this paper, the 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone (H 2 -Nap-ptsc) was reacted with square planar complexes of the type [MCl 2 (EPh 3 ) 2 ] (where M = Ni or Pd; E = P or As) and octahedral [RuHCl(CO)(PPh 3 ] 3 ].

TL;DR: In this article, a new NNS tridentate ligand, S-allyl-3-(2-pyridyl-methylene)dithiocarbazate (HL) has been prepared.

TL;DR: In this paper, Ni(II) thiosemicarbazone complexes containing triphenylphosphine were synthesized and characterized by elemental analysis, IR, electronic and 1H NMR spectroscopy.

TL;DR: In this article, the Negishi ferrocenylation of dibromothiadiazole with FcZnCl (2) and FcC CH (4) was used as a two-fold Negishi catalyst.

TL;DR: Complex (1) displayed the best cytotoxicity and can be pointed out as a promising substrate to be subject of further investigations.

TL;DR: A series of 2,6-bis(imino) pyridyl iron(III) complexes of the general formula [2,6-(ArN=CMe)(2)C(5)H(3)N] FeCl(3)] have been investigated in 1,3-butadiene polymerization as mentioned in this paper.