Showing papers in "Inorganica Chimica Acta in 2018"

TL;DR: In this article, the structures of the nanocomposites were studied by several techniques, from electron microscopy and diffraction to X-ray powder diffraction coupled with others, to obtain an exhaustive view of LDHs structure and reactivity.

TL;DR: In this article, the synthesis and characterization of eight compounds with general formula [Cu(iminodiacetate)(diimine)(H2O)x], with x = 0 or 1, and their cytotoxic activities against tumor cells were presented.

TL;DR: In this paper, the authors discuss what is needed for proper validation and archival of single crystal X-ray crystallography data, and the difference between valid and value is discussed.

TL;DR: A short description of most commonly used chemosensor ligands for anions and metal ions viz. Zn2+, Cu2+, Ni2+, Co2+, Fe2+ and Hg2+ is given in this paper.

TL;DR: In this paper, a 2-hydroxymethyl-1,4-benzodioxane substituted phthalonitrile ligand and its non-peripherally tetra-substituted phthalocyanine derivatives with metal-free (2), zinc(II) (3), cobalt(II), nickel(III), and copper(III) (6) were synthesized.

TL;DR: In this article, a new 6-ethoxychromone-3-carbaldehyde-(3-hydroxy-2-naphthalene acyl) hydrazone (L) was designed and synthesized, which showed good selectivity and high sensitivity towards Al 3+ in the presence of most metal ions.

TL;DR: In this paper, the state of the art of the aerobic selective oxidation of 5-hydroxymetylfurfural (5-HMF) with heterogeneous catalysts in water is presented.

TL;DR: In this article, the adsorption activity of a layered two-dimensional (2D) nickel-based metal-organic framework (Ni-MOF) was investigated for the removal of the harmful methylene blue dye (MB) from water.

TL;DR: Based on an asymmetric 1-(2-carboxyethyl)-1H-1,2,4-triazole-3 carboxylic acid (H2ctp), six new MOFs have been synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy as mentioned in this paper.

TL;DR: In this paper, two pincer type Pd(II)-Schiff base complexes of the general formula [PdL 1 (PPh 3 )] 1 and [PP 3 ] 2 were synthesised by the reaction of the palladium acetate with the corresponding ligand in methanol as yellow crystalline solids in high yields.

TL;DR: In this paper, four coordination complexes, [2-mimH]2[Co(pydc)2][ClO4], H2O (1), [2]-2-6-dicarboxylic acid (PydcH2) with 2-methylimidazole (2mim) and imidazoles (imi) in 1:2M ratio and metal salts have been characterized by spectroscopic methods and single crystal X-ray diffraction technique.

TL;DR: In this paper, a new stable and powerful magnetic nanoparticle supported Schiff base-palladium(II) (MNPs@SB-Pd) nanomagnetic catalyst was synthesized.

TL;DR: In this paper, various methods to obtain two-dimensional metal-organic frameworks (2D MNS) including top-down and bottom-up are introduced and their applications in separation, catalysis and sensors are also discussed.

TL;DR: In this paper, two trans Pd (II) complexes with formulas Pd(PhCH2NH2)2Cl2 (1) and [Pd(PHCH 2NH2]2(L)2](NO3)2 (2) have been synthesized and characterized by elemental analysis, FT-IR and NMR spectroscopy, and single crystal X-ray diffractometry has been used to determine the crystal structure of 1.

TL;DR: In this paper, a condensation reaction between the selected aldehyde or ketone, and 1, 2-Phenylenediamine was investigated, and two different Schiff base ligands were prepared.

TL;DR: In this paper, a novel hydrazone 2-(2-((1E,2E)-2-(2phenylhydrazineylidene)propylidenes)hydrazinyl)pyridine and its nickel(II) and copper (II) complexes have been synthesized and characterized.

TL;DR: A series of lanthanide organic complexes, namely, EuxTb1−x (BTC) as mentioned in this paper, have been synthesized, and the overall quantum yields (Φoverall) of luminescence for complex 1 is detected to be as high as 95%, while that for complex 6 is only 8%.

TL;DR: In this paper, the authors showed that the particle size of MIL-101(Cr) decreased with increasing acetic acid concentration, which may be explained by the efficient suppression of the framework extension.

TL;DR: In this article, the host-guest complexes of macrocyclic copper and silver pyrazolates with a wide range of organic and organometallic bases possessing hydride, halide, carbonyl and π-electronic ligands are discussed.

TL;DR: In this paper, a new 1,3-oxazolidine based ligand was synthesized from the reaction of 2-amino-2-(hydroxymethyl)-1, 3-propanediol and 2-pyridinecarboxaldehyde at 110°C.

TL;DR: In this article, two series of palladium(II and platinum(II) complexes featuring esters of tetrazol-1-yl and tetrabyl-5-ylacetic acids were synthesized and their binding to calf-thymus DNA (CT DNA) and bovine serum albumin (BSA) were studied by means of experimental (CD, UV, viscometry, fluorometric and electrophoretic techniques) and theoretical methods.

TL;DR: Two pincer ligands, 2,6-bis[[(2′-methylphenyl)thio]methyl]pyridine (SNS-1) and 2, 6-bis[(2.6′-dimethylphenyl),thio]-methyl] pyridine, each possessing a central pyridyl N-donor flanked by two thioether S-Ar functionalities, were prepared and metallated with CoCl2, FeCl2·4H2O, CuCl 2·2H 2O metal salts RE

TL;DR: In this article, two Cu(II) complexes, [Cu(L1)2(py)2 (H2O] (C1) (HL1 = N-(5-(4-methylphenyl)-[1,3,4]-thiadiazole-2-yl)-naphtalenesulfonamide) and [cu(HL2)4]-2 (C2)

TL;DR: In this paper, the design and synthesis of two novel hydrazone based N, O donor Schiff-base colorimetric sensors L 1 and L 2 have been described for selective sensing of cyanide ions in 2:1 CH 3 CN-H 2 O mixture.

TL;DR: The catalytic activity of iron or ruthenium complexes in promoting the reaction stated above is described by stressing the potential and limits of each synthetic protocol.

TL;DR: In this article, a series of palladium N-heterocyclic carbene complexes with methoxyethyl on the side chain (3a-d, 4a-e, 4b) have been synthesized and fully characterized by NMR, HRMS and IR.

TL;DR: Compounds 1 and 2 are found to be remarkably less toxic for the human lung embryonic normal cell line L132 as evident from the cell viabilities in presence of these two compounds.

TL;DR: In this article, a carbazole-based fluorescent probe, 2-(9-ethyl-9H-carbazol-3-yl) isoindoline-1,3-dione, with a low detection limit (2.673 × 10−6 M) was designed and synthesized based on Gabriel reaction.

TL;DR: In this paper, the structure of organotin(IV) dithiocarbamate complexes derived from N-methyl-N-phenyldithiamine (L) and organotin have been synthesized.

TL;DR: In this paper, a review of recent developments on cyanation reactions for the synthesis of nitriles (RCN) through transition metal mediated cyanation reaction as well as by using non-metal like iodine (transition metal free system).