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Showing papers in "Inorganica Chimica Acta in 2022"


Journal ArticleDOI
TL;DR: A series of luminescent ternary terbium complexes based on fluorinated ligand 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione (TFNB) and other auxiliary ligands were synthesized and explored as mentioned in this paper .

42 citations


Journal ArticleDOI
TL;DR: Two penta-coordinated multinuclear copper(II) complexes, [Cu 2 (L)( µ -OAc)]·MeOH ( 1 ) and [Cu 4 (L) 2 Cl 2 ]·EtOH·CH 2 Cl2 ( 2 ) have been synthesized and characterized structurally as discussed by the authors .

39 citations


Journal ArticleDOI
TL;DR: In this paper , a series of terbium heteroleptic complexes with heteroaromatic auxiliary ligands and 1,3-diketones were synthesized and a comprehensive study of thermal and electrochemical properties of complexes was done.

36 citations


Journal ArticleDOI
TL;DR: In this article , a bis(salamo)-like fluorogenic chemosensor (BDS) was designed for recognition Cu2+ ions through fluorescence "off" in DMSO/H2O (v/v = 9:1) Tris-HCl (pH = 7.26) buffer system to form a 1:2 BDS-Cu2+ complex.

36 citations


Journal ArticleDOI
TL;DR: In this article , two octahedral homopolynuclear Ni(II) complexes, [Ni 2 (L)(OAc)(MeOH)]·CH 3 CN·MeOH ( 1 ) and [Ni 4 (L) 2 (acac) 2(EtOH) 2 ]·2CH 3CN ( 2 ) have been synthesized and characterized structurally.

35 citations


Journal ArticleDOI
TL;DR: A dual-channel single-armed salamo-like chemical sensor PAS was synthesized based on 2-hydroxy-5-methylisophthalaldehyde for selective fluorometric detection of Fe 3+ ions and colorimetric recognition of Cu 2+ ions as discussed by the authors .

35 citations


Journal ArticleDOI
TL;DR: In this paper , four Schiff base ligands, namely ((1E)-1-(1-(6-chloro-2-oxo- 2H-chromen-3-yl)ethylidene) thiosemicarbazide) (HL2), ((1 E)-1-1-( 1-(7-hydroxy-2)-oxo)-2h-chromens-3yl) methylidene), (HL3) and (1E-1- 1-(1-7)-hydroxy)-2 -oxo -2H-methylidene, (HL4) have been prepared, and the direct reaction of these ligands with [RuCl2(η6p-cymene)]2 yielded the new cationic ruthenium(II) arene complexes (C I - C IV).

31 citations


Journal ArticleDOI
TL;DR: In this article , a series of octacoordinated samarium complexes with fluorinated diketone and N donor auxiliary ligands have been synthesized and investigated spectroscopically.

30 citations


Journal ArticleDOI
TL;DR: In this paper , neutral homotrinuclear complexes were obtained in the reactions of a new non-symmetric salamo-like ligand H2L (5-(N,N′-diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]phenolnaphthol) with the respective salts of M(OAc)2·2H2O (M = Zn(II) and Ni(II)), respectively.

30 citations


Journal ArticleDOI
Y. La, Yuan-Ji Yan, Lu-Lu Gan, Li Xu, Wen-Kui Dong 
TL;DR: In this article , a N2O3-donor aldehyde-appended salamo-like ligand H2L has been designed and synthesized successfully, and can be used to prepare [{Cu(L)}2] (1) and [Cu3(L)2(EtOH)2]·2ClO4 (2) with different nuclearity and extraordinary structures by changing the reaction conditions (various counter-anions and solvent molecules).

27 citations


Journal ArticleDOI
Hadi Kargar1
TL;DR: In this paper , a nuclear zinc(II) Schiff base complexes were synthesized through the reaction of ONNO tetradentate Schiff base ligands derived from the condensation of 2,2-dimethyl-1,3-propanediamine and 5-chlorosalicylaldehyde or 5-bromosalicityylaldehyde with zinc acetylacetonate salt.

Journal ArticleDOI
TL;DR: In this paper, a nuclear zinc(II) Schiff base complexes were synthesized through the reaction of ONNO tetradentate Schiff base ligands derived from the condensation of 2,2-dimethyl-1,3-propanediamine and 5-chlorosalicylaldehyde or 5-bromosalicityylaldehyde with zinc acetylacetonate salt.

Journal ArticleDOI
TL;DR: In this paper , the azocoumarin ligand behaves as a neutral bi-dentate ligand and coordinates to the metal ions through the azo Nitrogen and carbonyl Oxygen.

Journal ArticleDOI
TL;DR: In this article, a salamo-type fluorescence probe H2L was synthesized by a series of reactions and corroborated by single-crystal X-ray crystallography and 1H NMR spectra.

Journal ArticleDOI
TL;DR: Two new discrete compounds with the formula [Ni(3,5,6-tcpa)(2,2′-bipy)Cl] (1) and [Ni2(3.5, 6-tcPA)2(2, 2′-Bipy)-2(ox)]·2EtOH (2) have been co-synthesized under solvothermal conditions in the same medium.

Journal ArticleDOI
TL;DR: In this paper , three new nickel(II, copper(II), and zinc(II) complexes were synthesized and characterized by treating symmetrical tetradentate Schiff base ligand (H 2 L ) with Ni(OAc) 2 4H 2 O, Cu(O Ac) 2 ·H 2 OD, and Zn(O AC) 2 −2H O O OD salts, respectively.

Journal ArticleDOI
TL;DR: In this paper , a salamo-type fluorescence probe H 2 L was synthesized by a series of reactions and corroborated by single-crystal X-ray crystallography and 1 H NMR spectra.

Journal ArticleDOI
TL;DR: Two new discrete compounds with the formula [Ni(3,5,6-tcpa)(2,2′-bipy)Cl] have been co-synthesized under solvothermal conditions in the same medium as discussed by the authors .

Journal ArticleDOI
TL;DR: In this paper , a series of luminous europium complexes were synthesized with general formula Eu(DAM) 3 L; DAM symbolizes diacetylmethane and L refers to the substituted 1,10-phenathroline derivatives.

Journal ArticleDOI
TL;DR: In this article, a review of composites of TiO2 with other metal oxides and their utilization for the removal of hazards has attracted the interest of scientific community, where the addition of tin oxide favors the formation of the rutile phase and morphology is also affected.

Journal ArticleDOI
TL;DR: In this article, the authors provide a more specific focus on the design of antimicrobial nanocomposites based on Ag, Cu and Fe nanoparticles supported on silica and titania.

Journal ArticleDOI
TL;DR: In this paper , the effect of nickel impurity on photocatalytic activity of ZnO nanocatalysts in degradation of methylene blue (MB) was also investigated.

Journal ArticleDOI
TL;DR: In this article , a review of composites of TiO2 with other metal oxides and their utilization for the removal of hazards has attracted the interest of scientific community, where the addition of tin oxide favors the formation of the rutile phase and morphology is also affected.

Journal ArticleDOI
TL;DR: In this paper , a salamo-based fluorescent sensor H3L was synthesized and characterized by IR, 1H NMR and ESI-MS, which showed that the fluorescence spectra and UV-Vis absorption spectra of H3l changed with the addition of Cu2+ and Arg respectively.

Journal ArticleDOI
TL;DR: In this paper , a pyridine-decorated half-salamo-like ligand (HL) was designed and synthesized by a one-pot method and the structural features were determined by single crystal X-ray diffraction analyses.

Journal ArticleDOI
TL;DR: A series of N -benzyl substituted indole-based thiosemicarbazone (TSC) ligands (L4-L6) and their corresponding Pd(II) complexes ( 4 - 6 ) were synthesized along with unsubstituted indole derivatives ( 1 - 3 ).

Journal ArticleDOI
TL;DR: In this paper , the authors provide a more specific focus on the design of antimicrobial nanocomposites based on Ag, Cu and Fe nanoparticles supported on silica and titania.

Journal ArticleDOI
TL;DR: In this paper, a pyridine-decorated half-salamo-like ligand (HL) was designed and synthesized by a one-pot method and the structural features were determined by single crystal X-ray diffraction analyses.

Journal ArticleDOI
TL;DR: In this article , the modus operandi of transition metal atoms in biology is analyzed in various settings: in the active sites of proteins, in the physiological solutions, and incorporated in metallodrug scaffolds.

Journal ArticleDOI
TL;DR: In this paper, the modus operandi of transition metal atoms in biology has been analyzed in various settings: in the active sites of proteins, in the physiological solutions, and incorporated in metallodrug scaffolds.