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Showing papers in "International Journal of Biological Macromolecules in 2008"


Journal ArticleDOI
TL;DR: The main chemical modifications of chitosan that have been proposed in the literature are reviewed and a wide range of derivatives with a broad range of applications are presented.

705 citations


Journal ArticleDOI
TL;DR: Fucoidan, a group of sulfated heteropolysaccharide, was extracted from Laminaria japonica, an important economic alga species in China as mentioned in this paper.

633 citations


Journal Article
TL;DR: In this paper, a series of alkene-functional polymers were synthesized by controlled polymerization techniques in order to investigate and compare the efficiency and orthogonality of both photochemically and thermally initiated thiol−ene click coupling reactions.

364 citations


Journal ArticleDOI
TL;DR: Hydrolyzed fucoidans, from sporophyll of Undaria pinnatifida, were used to determine the effects of molecular weight (Mw) and hydrolysis conditions on cancer cell growth and suggest that anticancer activity of fu coidans could be significantly enhanced by lowering their Mw only when they are depolymerized by mild condition.

208 citations


Journal ArticleDOI
TL;DR: Compared with other commercially available hydrocolloids like xanthan gum, guar gum and locust gum ZW3 EPS showed much better emulsifying capability and was glucogalactan in nature.

199 citations


Journal ArticleDOI
TL;DR: Ultra-fine gelatin fibers were successfully fabricated by electrospinning from the solutions of Nile tilapia skin-extracted gelatin in either acetic acid or formic acid aqueous solutions, and a combination between smooth and beaded fibers was observed.

184 citations


Journal ArticleDOI
TL;DR: Analyses of fluorescence spectra, viscosity measurements and molecular modeling of IOC-DNA interactions indicate that IOC is a minor groove binder of ct-DNA and preferentially binds to AT rich regions.

183 citations


Journal ArticleDOI
TL;DR: These polysaccharides showed significant activation of phenylalanine-ammonia lyase (PAL), lipooxygenase (LOX) and glutathione-S-transferase (GST) defence enzyme activities in tobacco plants.

175 citations


Journal ArticleDOI
TL;DR: CLEA of subtilisin has good stability in nonpolar organic solvents and it has high thermal stability up to 60 degrees C and therefore can be used as a catalyst for the biotransformation of compounds which are not soluble in aqueous medium.

157 citations


Journal ArticleDOI
TL;DR: The chemical modification of chitin and chitosan by phosphorylation is expected to be biocompatible and is able to promote tissue regeneration and be able to bring new or improved properties.

156 citations


Journal ArticleDOI
TL;DR: Results of X-ray diffraction analyses indicated that the intensity of diffraction peak at 19 degrees of PVA became lower and broader with increasing the amount of GA in the CS/PVA/GA ternary blend film.

Journal ArticleDOI
TL;DR: Preliminary immunological tests in vitro showed CPP could stimulate concanavalin A (ConA)- or lipopolysaccharide (LPS)-induced lymphocyte proliferation in a dose-dependent manner.

Journal ArticleDOI
TL;DR: The laminated films exhibited higher ultimate tensile strength (UTS) than the single whey protein films (260% and 200% in the Whey-zein-glycerol and whey-ZEin-olive oil films, respectively).

Journal ArticleDOI
TL;DR: Dynamic viscoelastic properties of collagen solutions with concentrations of 0.5-1.5% (w/w) were characterized by means of oscillatory rheometry at temperatures ranging from 20 to 32.5 degrees C and showed a shear-thinning flow behavior.

Journal ArticleDOI
TL;DR: Chitinous material isolated from the mycelium of seven species of Basidiomycetes to evaluate the possibility of using fungal biomass as a source of chitin and chitosan characterised for its purity, degree of acetylation and crystallinity.

Journal ArticleDOI
TL;DR: The structure of aggregates formed by the globular protein beta-lactoglobulin (beta-lg) after heat induced denaturation was studied using light scattering and size exclusion chromatography and the influence of varying the pH above the iso-electric point was investigated in the absence of added salt.

Journal ArticleDOI
TL;DR: High yield and high degree of substitution (DS) and the solubility of the polymer was improved and the P-chitosan showed less thermal stability and crystallinity than the chitan, due to the phosphorylation.

Journal ArticleDOI
TL;DR: Fish scales, which are hitherto discarded as waste, were collected and cleaned thoroughly, hydrolyzed under controlled acidic conditions, neutralized and made in to a sheet, i.e., fish scale collagen sheet (FCS), characterized for its infrared spectroscopy, thermo-gravimetric analysis, scanning electron microscopy, and mechanical properties.

Journal ArticleDOI
TL;DR: The potential application of the CS/PEGDA film as wound dressing material was evaluated in vitro by using mouse fibroblasts (L929) as reference cell lines, indirect cytotoxicity assessment indicated that CS/ PEGDA films were nontoxic to L929 cell.

Journal ArticleDOI
TL;DR: The results showed that modified sAPSs inhibited IBDV to infect CEF significantly in comparison with non-modified APS(t), which indicated that sulfated modification could enhance the antiviral activity of the APS, by which it would be expected to develop a new-type antiviral drug.

Journal ArticleDOI
TL;DR: Correlation analysis indicated that most structural parameters were positively correlated with thermal properties with few exceptions, whereas the content of fraction fa' ("'" stands for molar-based chain length ratio) was negatively correlated with the thermal properties.

Journal ArticleDOI
TL;DR: The interaction between xanthan and selected bivalent cations was studied by means of conductometry, viscometry, and nuclear magnetic resonance spectroscopy to propose a possible structure of a chelate-like complex which involves the pyruvate units at the terminal ends of the side chains as the main binding sites.

Journal ArticleDOI
TL;DR: The results suggested that the spruce AcGGM and GGM are potentially important as additives with immuno-potentiating and antioxidant properties in food products and pharmaceutical formulations.

Journal ArticleDOI
TL;DR: Results demonstrated that L. barbarum polysaccharides administration significantly increases glycogen level and anti-oxidant enzyme activities, and decreased malondialdehyde level and creatine kinase activities in skeletal muscle.

Journal ArticleDOI
Y. Maeda1, Rangasamy Jayakumar1, H. Nagahama1, T. Furuike1, Hiroshi Tamura1 
TL;DR: It seems that the beta-chitin scaffolds are useful in the tissue-engineering field because of its abundance, biodegradability, non-toxicity, chemical inertness and biocompatible properties.

Journal ArticleDOI
TL;DR: The impact of homogalacturonans deficiency on the cell wall porosity of Arabidopsis thaliana QUA1 mutant was investigated using NMR measurements of protons mobility interpreted in terms of pore size variations at nanometer and micrometer scales to inform about the porosity network density and heterogeneity.

Journal ArticleDOI
TL;DR: To fabricate a biomimetic nanostructured bicomponent scaffolds, two types of chitin/silk fibroin (SF) nanofibrous scaffolds (blend scaffolds and hybrid scaffolds) were prepared by electrospinning or simultaneous electrosp spinning of ch itin/SF solutions.

Journal ArticleDOI
TL;DR: The covalently immobilized Saccharomyces cerevisiae alcohol dehydrogenase to magnetic Fe(3)O(4) nanoparticles via glutaraldehyde coupling reaction was studied and enhanced thermal stability and good durability in the repeated use after recovered by magnetic separations.

Journal ArticleDOI
TL;DR: Chitin-based polyurethane elastomers (PUEs) were synthesized by step growth polymerization techniques using poly(epsilon-caprolactone) (PCL) varying diisocyanate and chain extender structures in accordance with proposed PUEs structure and crystallinity showed that crystallinity decreased from aliphatic to aromatic characters of the diisOCyanates used in the final PU.

Journal ArticleDOI
TL;DR: The levan solutions exhibited the pseudoplastic behavior, which was characterized by the power law model, and the exponential equation was favorably applied to describe the effect of concentration on the apparent viscosity of the levan polysaccharides.