Journal of Adhesion Science and Technology 

About: Journal of Adhesion Science and Technology is an academic journal published by Brill. The journal publishes majorly in the area(s): Adhesive & Adhesion. It has an ISSN identifier of 0169-4243. Over the lifetime, 4507 publications have been published receiving 81742 citations.

Contact angle, wetting, and adhesion: a critical review

Abstract: The theory of the contact angle of pure liquids on solids, and of the determination of the surface free energy of solids, γs, is reviewed. The basis for the three components γLW s, γ⊕s, and γ⊖s is developed, and an algebraic expression for these properties in terms of measured contact angles is presented. The inadequacy of the 'two-liquid' methodology (which yields a parameter, 'γp') is demonstrated. Attention is given to contact angle hysteresis and to the film pressure, πe. Some recommendations are made with regard to contact angle measurements. A new treatment of hydrophilicity, and of the scale of hydrophobic/hydrophilic behavior, is proposed. It is shown that there are two kinds of hydrophilic behavior, one due to Lewis basicity (electron-donating or proton-accepting structures) and the other due to Lewis acidity (electron-accepting or proton-donating structures). The properties γ⊖ and γ⊕ are the quantitative measures of these types of behavior and they are structurally independent of each other. A t...

Plasma surface modification of polymers for improved adhesion: a critical review

Abstract: Since the earliest systematic research during the 1960s, the field of materials surface modification by 'cold', low-pressure plasma treatment has undergone an enormous expansion. Much of this expansion has taken place in recent years, particularly in the surface modification of polymeric materials, for which there now exist numerous industrial applications (enhancement of paint adhesion, improved bonding in polymer matrix composites, etc.). In this paper, we provide a critical review of the development and trends in this field; reference is also made to other surface modification techniques, particularly to corona treatment, and comparisons are made wherever appropriate. We begin with a brief overview of adhesion theory, and of the physics and chemistry of 'cold' plasmas. Next, interaction mechanisms between a plasma and a polymer surface are examined; these include physical bombardment by energetic particles and by ultraviolet photons, and chemical reactions at or near the surface. The resulting four mai...

Role of acid-base interfacial bonding in adhesion

Abstract: The strength of macroscopic adhesive bonds of polymers is known to be directly proportional to the microscopic exothermic interfacial energy changes of bond formation, as measured by Dupre's 'work of adhesion'. Since the work of adhesion can be very appreciably increased by interfacial acid-base bonding with concomitant increases in adhesive bond strength, it is important to understand the acid-base character of polymers and of the surface sites of substrates or of the reinforcing fillers of polymer composites. The best known acid-base bonds are the hydrogen bonds; these are typical of acid-base bonds, with interaction energies dependent on the acidity of the hydrogen donor and on the basicity of the hydrogen acceptor. The strengths of the acidic or basic sites of polymers and of inorganic substrates can be easily determined by spectroscopic or calorimetric methods, and from this information one can start to predict the strengths of adhesive bonds. An important application of the new knowledge of interfac...

Synthetic gecko foot-hair micro/nano-structures as dry adhesives

Abstract: This paper proposes techniques to fabricate synthetic gecko foot-hairs as dry adhesives for future wall-climbing and surgical robots, and models for understanding the synthetic hair design issues. Two nanomolding fabrication techniques are proposed: the first method uses nanoprobe indented flat wax surface and the second one uses a nano-pore membrane as a template. These templates are molded with silicone rubber, polyimide, etc. type of polymers under vacuum. Next, design parameters such as length, diameter, stiffness, density, and orientation of hairs are determined for non-matting and rough surface adaptability. Preliminary micro/nano-hair prototypes showed adhesion close to the predicted values for natural specimens (around 100 nN each).

Adhesion and Surface Issues in Cellulose and Nanocellulose

Abstract: This paper provides a review of the scientific literature concerned with adhesion and surface properties of cellulose and nanocellulose. Cellulose is the most abundant chemical compound on earth and its natural affinity for self-adhesion has long been recognized. The ease of adhesion that occurs in cellulose has contributed to its use in paper and other fiber-based composite materials. Cellulose adhesion, which has received considerable attention over the past half century, occurs over a practical length scale ranging from the nanoscale to millimeters. Adhesion theories that have been examined in the bonding of cellulose fibers include: mechanical interlocking, adsorption or wetting theory, diffusion theory, and the theory of weak boundary layers. Cellulose fibers on the nanoscale are prepared in four different ways: (1) bacterial cellulose nanofibers, (2) cellulose nanofibers by electrospinning, (3) microfibrillated cellulose plant cell fibers and (4) nanorods or cellulose whiskers. Structure and propert...