Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1955"
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TL;DR: In this paper, the preparation of cyclopentadienyl-carbon monoxide compounds of manganese, iron and cobalt is described, and the configurations and structures of the compounds are discussed briefly.
333 citations
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TL;DR: In this article, the X-ray powder was used to study the UO2-U3O8 range at temperatures between 20° and 969°C after annealing at 1000°C.
194 citations
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166 citations
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TL;DR: A series of nitrato aquo nitrosylruthenium complexes, of general formula [RuNO(NO3)y(OH)3−y(H2O)2], has been identified.
153 citations
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TL;DR: In this paper, it was shown that the data are in agreement with an average cosmic-ray production rate of about 0·14 tritium atoms per cm 2 per second of the earth's surface, on the assumption that essentially all of this tritiium passes into water without decaying into helium and the tritiated water is precipitated out and goes into the sea.
108 citations
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TL;DR: In this paper, the infrared absorption spectra in the CO stretching region of mono-and binuclear transition metal cyclopentadienyl-carbon monoxide compounds are presented.
94 citations
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TL;DR: In this article, the authors discuss the properties of tetravalent silicon compounds in which bonding is not of the pure sp 3 -type, and silicon compounds with chemical reactivities unusual in terms of analogous carbon compounds.
63 citations
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TL;DR: In this paper, a number of the chemical reactions of disilyl sulfide, selenide, and selenides have been studied, as well as of the previously known disilyls ether, and they have been chosen to encourage the compounds to display donor activity.
53 citations
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TL;DR: In this article, a method for the automatic recording of derivative curves of the proton absorption lines, and such curves were obtained for each substance over a variety of temperatures, was developed for the calculation of second moments and the prediction of line shapes.
51 citations
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TL;DR: The difficulties encountered in the preparation of sodium and calcium aluminium hydrides and the methods of overcoming them are described in this article, as well as some of the properties of these compounds.
50 citations
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TL;DR: In this article, the reaction of silyl iodide with phosphorus, phosphine, arsenic and the arsenides of potassium and mercury has been studied, and evidence is presented for the existence of the compounds P(SiH3)2I, P(SILI3)3, PILI4I, SILI5I, SiH3I2I2, AsILI6I2 and AsILII4I2 have been isolated and characterized.
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TL;DR: The crystal structure of a uranium oxide phase of composition UO2·82 has been determined by X-ray powder diffraction techniques using a Guinier-type focusing camera.
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TL;DR: In this paper, the masses of the isotopes of the heaviest elements have been calculated from known decay data in the region, extended by means of decay energies calculated from closed decay-energy cycles and estimated from the systematics of alpha and beta decay energies.
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TL;DR: In this article, a consideration of alpha systematics indicated that it might be possible to prepare a number of new isotopes of emanation, francium, and radium with half-lives sufficiently long to permit radio-chemical isolation and identification.
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TL;DR: In this article, the thermal decomposition of thorium oxalate dihydrate has been studied in the temperature region 270-900°C in both air and nitrogen atmospheres.
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TL;DR: In this paper, the vibrational frequencies of the hydrides XH2, XH3, and XH4 have been calculated on the assumption that the electron distribution in each molecule is spherical and rigid.
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TL;DR: Using the glow-discharge technique of sample preparation, some wire- mounted sources of emanation isotopes were prepared and exposed in the magnetic alpha-particle spectrograph and the alpha spectrum of Fr 212 was made.
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TL;DR: In this paper, the β-decay half-life of Cs137 has been obtained from a specific activity measurement, and the disintegration rate was measured in a 4π-type proportional counter.
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TL;DR: Two nuclides not previously reported in the literature, Pu245 and Am245, have been produced by neutron irradiation methods and the study of their radiations is described and a preliminary decay scheme for Am245 is presented.
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TL;DR: In this paper, the behavior of the effective nuclear charge Z ∗ and the effective principal quantum number n ∗ is investigated, with special emphasis on the beginning of the 3d, 4f-, and 5f periods.
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TL;DR: In this article, the compositions of the uranates precipitated by mixing solutions of sodium hydroxide and uranyl chloride have been investigated by the method of residues, and the results indicate that two uransates are formed, Na 2 U 16 O 49 (yellow) and Na 2 u 2 O 7 (orange).
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TL;DR: In this article, spontaneous fission of Cf252 was investigated by radiochemical determination of the yields of fifteen fission products ranging in mass number from 99 to 143, and the yield-mass curve indicated a value of 5 ± 1 for the average number of neutrons emitted per fission.
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TL;DR: In this article, three hydrates of thorium tetrafluoride have been identified from a chemical, tensimetric, and X-ray crystallographic study, and the highest hydrate is pseudotetragonal and can be thermally degraded to ThF 4.0·25H 2 O.
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TL;DR: In this article, X-ray diffraction and electron microscope photographs of the corrosion film formed by the action of elementary fluorine on copper at temperatures between 100°C and 500°C have been taken, showing that the film has a cupric fluoride structure rapidly changing to the basic fluoride on exposure to air.
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TL;DR: In this paper, a solution of ruthenium tetroxide in nitric acid is reduced by hydrogen peroxide to give a deep red solution, which decomposes fairly rapidly.
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TL;DR: The beta-emitting isotopes Pu 246 and Am 246 were found in the debris of a thermonuclear test and the chemical evidence for the existence of these isotopes is described in this paper.