Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1962"

TL;DR: In this article, a general method is described which can be used to synthesize nearly all the lanthanide halides in high purity and good yield, including tri-halides except the iodides of samarium and europium.

TL;DR: Nickel(II), rhodium(III), palladium (II), iridium(III) and other central atoms are combined with diethyldithiophosphate (dtp − ) diethyrdithiocarbamate (dtc − ) 2,2′-di(aminoethyl)sulphide (daes), thiosemicarbazide (tscaz), and other sulphur-containing ligands as mentioned in this paper.

TL;DR: In this paper, the AB2-type selenides and tellurides of niobium, tantalum, molybdenum and tungsten have been prepared in single crystalline form by means of transport reactions.

TL;DR: In this paper, the infra-red spectra of the tris-2, 2′-bipyridine and tris 1,10-phenanthroline complexes of iron(II), cobalt (II), nickel (II, copper(II, and zinc(II) have been obtained from 250 to 2000 cm −1.

TL;DR: Tetrahydrofuran complexes of TiCl3, VCl3 and VOCl2 were isolated and their compositions determined in this paper, and the anhydrous metal chlorides complexed easily.

TL;DR: In this article, the interaction between diethylenetriaininepentaacetic acid and rare-earth metal ions (Ln/sup 3+/) was investigated.

TL;DR: In this paper, the authors used HDOΦP in toluene as a carrier diluent to extract M(III) lanthanides and actinides from aqueous perchlorate, chloride and nitrate media.

TL;DR: In this article, the Slater-Condon theory of atomic spectra is evaluated from experimental atomic energy levels for B, C, N and O, and for their unipositive ions.

TL;DR: In this paper, a simple cation exchange mechanism was proposed to examine the effect of ion charge, size, and coordination properties on solvent extraction in organophosphates, and the results of this simple exchange mechanism were shown to improve the performance of dialkylphosphoric acids when used in combination with neutral organophorous compounds.

TL;DR: In this article, a procedure for the estimation of the critical constants of salts, provided reliable liquid density data are available, is explained, applied specifically to NaCl and KCl, the liquid densities of which have been determined from the melting point to the normal boiling point.

TL;DR: In this article, the etch patterns of colloidal metal particles placed on graphite single crystals catalyse the oxidation of graphite, but the catalysis occurs only at the metal-carbon interface.

TL;DR: In this paper, the effect of diluent diluents on metal extraction has been studied under various conditions, such as cyclohexane, hexane, carbon tetrachloride, benzene and chloroform.

TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.

TL;DR: In this article, the preparation of pure stoicheiometric chromites MCr2O4 (Mg2+, Zn2+, Cu2+, Mn2+, Fe2+, Co2+, Ni2+) from suitable precursors is discussed.

TL;DR: In this paper, stable complexes of 1,1,1-trifluoro-3-2′-thenoyl acetone (HTTA) and neutral organophosphorus compounds have been isolated from the organic phase.

TL;DR: In this paper, the ternary system NH3UO3O has been studied in aqueous solutions and the stability of these phases is discussed.

TL;DR: In this paper, it was shown that water helps to destroy the anhydrous synergic species, causing antisynergism to occur, which is connected with the water contents of the organic phase.

TL;DR: In this article, a high and low temperature X-ray powder camera for small radioactive samples is presented, which can be used to measure the properties of americium trifluoride with barium vapour.

TL;DR: In this article, the thermal decomposition of rare-earth sulfates was studied by thermogravimetric analysis (TGA) and differential thermal analysis (DTA) up to a temperature limit of 1400 deg C.

TL;DR: In this paper, the selectivity of anion exchange resins in contact with very dilute external solutions (negligible resin invasion by non-exchange electrolyte) is considered due in large part to changes in the solvation of the ions, resulting from differences in the properties of the resin-phase solution and the external dilute aqueous solution.

TL;DR: In this paper, the effect of synergistic agents on the extraction of M(III) lanthanides was investigated as a function of carrier diluent, synergistic agent, concentration of H 2 MEHP, and concentration of Z of M (III) linthanides.

TL;DR: In this paper, the preparation and partial characterization of a number of new complexes of the oxovanadium(IV) ion were reported, in which the vanadium-oxygen multiple bond in each compound has been established by infrared spectra.

TL;DR: In this article, stable solid complexes have been confirmed by ultra-violet and visible absorption spectrophotometric measurements of dilute solutions of uranyl, thorium and neodymium complexes.

TL;DR: In this paper, it was shown that tetra-alkyldiphosphine disulphides of the type RR′P(S)-(S)PRR′ yield two isomeric diphosphines, which has been proved without question by nuclear magnetic resonance (n.m.r.) and chemical reactions.

TL;DR: In this article, a procedure involving high temperature ignition in a stream of oxygen was devised for the isolation of iodine from a variety of materials and a large sodium iodide, well-type crystal was used as a selective detector for the 130I activation product.

TL;DR: In this article, the mass assignments, half-lives and radiation characteristics of the isobaric pairs 126Sn126Sb, 127Sn127Sb (Sb), 128Sb and 129Sb have been investigated and the isotope 130Sb has been investigated.

TL;DR: In this paper, the formation constants of the hydrogen chelates (LnHZ) and of the normal Chelates(LnZ − ) have been evaluated at 20°C, 30°C and 40°C with an ionic strength of 0·10(KNO 3 ).

TL;DR: In this paper, the partition coefficients of europium and thorium extracted from 4 M NaN 3 into 5% TBP in a number of diluents were determined.

TL;DR: An X-ray single-crystal structural study of thallium (I) methoxide, TlOCH3, was conducted in this article, which yielded the thalium arrangement along with a proposed over-all configuration of the molecule.

TL;DR: In this paper, the partition of zirconium(IV) between sulphuric acid solutions and DEHPA in an organic solvent has been investigated, and the mechanism of the extraction is discussed on the basis of these results.