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Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1965"


Journal ArticleDOI
G. Blasse1
TL;DR: In this article, a number of mixed metal oxides with perovskite-like structures are reported, and the Jahn-Teller distortions of these compounds are discussed.

305 citations


Journal ArticleDOI
W.E. Prout1, E.R. Russell1, H.J. Groh1
TL;DR: In this article, a granular form of potassium hexacyanocobalt (II) ferrate (II), which is a highly selective absorbent for cesium ion, is described.

163 citations


Journal ArticleDOI
TL;DR: In this paper, the presence of the Me → N = C donor π-bond was proved in the dimethyl glyoxime complexes of bivalent metals by infrared spectrophotometry.

147 citations


Journal ArticleDOI
TL;DR: The plutonium-oxygen phase diagram between PuO1·5 and PuO2 and between room temperature and 900° has been studied using a high-temperature X-ray powder-diffraction camera.

90 citations



Journal ArticleDOI
TL;DR: In this paper, the preparation of three types of complexes (1:1, 1:3 and 2:3) by the direct reaction of Cu(I)X (XCl, Br, I) and triphenylphosphine is described.

79 citations



Journal ArticleDOI
TL;DR: In this article, the dissociation constants of DTPA complexes with Am, Cm, Bk, Cf, Es and Fm have been determined by an ion exchange technique, and the values obtained are: Americium 10 −22·92, Curium 10−22·99, Berkelium 10-22·79, Californium 10 -22·57, Einsteinium 10 ¼·62 and Fermium 10¼·70.

79 citations


Journal ArticleDOI
TL;DR: In this article, well-crystalline complexes of the novel types MCl3(dipy)H2O, MCH3COO)3D, MCL3D2EtOH, and M(CNS)3DDD3D3 are described and compared with 1:10-phenanthroline compounds with respect to possible structures and relative stability.

78 citations




Journal ArticleDOI
TL;DR: In this paper, the authors investigated the stability of Zr4+, Fe3+ and UO22+ ion complexes with benzohydroxamic acid using the distribution method and pH-potentiometric method.

Journal ArticleDOI
TL;DR: In this article, the infra-red spectra (900-240 cm−1) of twelve alkali metal uranates are presented. And the results are correlated with X-ray diffraction data, and uranyl bond lengths of the compounds have been calculated.

Journal ArticleDOI
TL;DR: In this article, the Mossbauer absorption spectra of α-, β-, γ-, and δ-FeOOH have been examined at room temperature and at 77°K.

Journal ArticleDOI
TL;DR: In this article, the hydrogen ion dependencies and extractant dependencies of an M(VI) element, UO 2 2+, into a benzene solution of di n-octyl phosphinic acid, (n -C 8 H 17 ) 2 PO(OH), H[DOP, from an aqueous acidic chloride medium have been determined radiometrically.

Journal ArticleDOI
TL;DR: In this paper, a series of complexes in which substituted pyridines are co-ordinated to transition metal halides were investigated and the spectra were correlated with the known structures of the complexes.

Journal ArticleDOI
TL;DR: Aniline complexes of manganese, cobalt, nickel, zinc, and cadmium chlorides, bromides, and iodides have been described in this paper, and the spectra are used to determine the probable co-ordination arrangement about the metal atoms in each complex.

Journal ArticleDOI
TL;DR: In this article, a comparison of partition data for the solvent extraction of mineral acids, uranium (VI), and some lanthanide elements by dis-(di-n-hexylphosphinyl)-alkanes is presented, as a function of aqueous concentration of nitric, hydrochloric, and perchloric acids.

Journal ArticleDOI
TL;DR: Spectrophotometric studies in the visible region have been made on benzene solutions of Cu(chelate)2 with increasing amounts of 4-methyl-pyridine (4-me-py) as discussed by the authors.

Journal ArticleDOI
M. Tanaka1, T. Niinomi1
TL;DR: In this paper, the extraction of copper (II) with capric acid dissolved in benzene is theoretically treated, and the extracted species has the dimeric structure of composition (CuR2HR)2 down to 10−5 M of copper.

Journal ArticleDOI
TL;DR: In this paper, the far infrared spectra of the above complexes, together with those of (2-mepy)2 CuX2 (X = Cl−, NO3−) are reported and the CuO, CuN and CuCl stretching modes are tentatively assigned.

Journal ArticleDOI
TL;DR: In this article, the authors used solution and reflectance spectral data at room temperature of low symmetry complexes with the ligands tartrate, lactate, malate, mandelate, citrate, and citrate to identify three distinct absorption bands in the 11-20 kK region.

Journal ArticleDOI
TL;DR: The total half-lives of 252Cf, 250Cf and 253Cf are 2.646 ± 0.004 years, 13·2 ± 0·5 years and 17·6 ± 0 ·2 days as mentioned in this paper.

Journal ArticleDOI
TL;DR: In this article, the equations for evaluation of solubility products of uranyl phosphates were derived and the following values were determined: [UO 2 2+ ][HPO 4 2− ] = 10 −12·17± 0·07, [U O 2 2 + ] 3 [PO 4 3− ] 2 = 10−49·7±0·3.

Journal ArticleDOI
TL;DR: By reaction of gaseous chlorine azide with SnCl4, TiCl4 and VOCl3 at 0°C, the crystalline, hygroscopic, explosive Azidechlorides SnCl3N3, TiNCl3, N2 and Cl2 respectively can be obtained in good yields.

Journal ArticleDOI
TL;DR: In this paper, thermally stable well-crystalline complexes of the types M(CH 3 COO) 3 (phen) and M(NO 3 ) 3(phen) 2, where phen = 1:10-phenanthroline, have been isolated.

Journal ArticleDOI
TL;DR: In this paper, the deviations of systems from ideal behaviour are discussed in terms of molecular association of the solutes and the information is related to solvent extraction studies involving these solutes.

Journal ArticleDOI
TL;DR: In this paper, the visible spectra of some of the compounds, the infra-red spectra, and the X-ray powder patterns have been determined and the compositions of these compounds appear to reflect the increasing spatial constraint produced by decreasing cationic crystal radius as the atomic number of the lanthanide becomes larger.

Journal ArticleDOI
TL;DR: In this article, the thermal decomposition of K3[Co(C2O4)3]·3H2O in the solid-state, was studied by thermogravimetry, high temperature reflectance spectroscopy, differential thermal analysis, mass spectrometry, gas evolution analysis, and by magnetic techniques.

Journal ArticleDOI
TL;DR: In this article, the authors used the phosphorus nuclear magnetic resonance method to determine the equilibrium constant of the reaction Zn(TTA)2 (org.) + TOPO (org.), which was found to be approximately 10 1/mole in anhydrous carbon tetrachloride medium.