Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1972"

TL;DR: In this article, the I.r. and PMR spectra of 28 N-aryl salicylaldimines were derived by 15N-labelling of N-p-tolylsalicylldimine and they were used to establish that the bases exist in the phenol-imine form at room temperature in deuterochloroform.

TL;DR: The vibrational spectra of the molecular M6+O6 (M = Mo, Te, W) group in ordered perovskites of the type Ba2M2+M6 +O6 are reported in this article.

TL;DR: In this article, the Elovich Equation was used to describe the kinetics of isotopic exchange of phosphate between 32P-labeled dilute orthophosphate solutions and Fe(III) phosphate complexes on the surfaces of goethite (α-FeOOH) crystals in dilute suspension.

TL;DR: In this article, the crystal structure of zirconium molybdate was determined from integrated precession photographs using MoKα radiation, and a three-dimensional network of cross-linked chains built-up of quite regular [ZrO 3 eq (OH 2 eq O 2 ax ]-pentagonal bipyramids and distorted cis -MoO 4 (OH)(H 2 O-octahedra).

TL;DR: Exitation functions have been measured for a number of nuclear reactions of nickel isotopes with 5–56 MeV protons with peak cross-sections determined for 60 Co formation from natural nickel.

TL;DR: The crystal structure of trisacetylacetonato (1,10-phenanthroline) europium(III), Eu(C 6 H 7 O 2 ) 3 (C 12 H 8 N 2 ), has been determined by single crystal X-ray diffraction techniques.

TL;DR: In this article, a chain mechanism involving homolytic bond cleavage of hexachloroplatinate(IV) to yield atomic chlorine and a labile platinum(III) species is proposed to account for the observed behavior.

TL;DR: In this paper, the structure of the dibenzylethylenediamine (DLS) and benzylethymenediamines (BH) complexes is deduced from reflectance spectra at room temperature and at liquid nitrogen temperature, visible spectra in solution, and conductivity measurements in DMF.

TL;DR: The combination of two bidentate ligands, the thenolytrifluoroacetone and the Lewis base phenanthroline or dipyridyl, produces a very strong synergic effect in solvent extraction of lanthanides and bivalent transition metals as mentioned in this paper.

TL;DR: In this article, the adsorber and its characterization were presented and discussed, and the sorption of the alkali metals appeared to proceed by an ion-exchange mechanism in NH4NO3 solutions.

TL;DR: In this paper, the electronic, ESR and i.r. spectra of a series of Cu(en) 1 X 2, z H 2 O and Cu(bipy), where X involves various anions, are reported and the local molecular structures of the copper(II) ions present in the different complexes are tentatively predicted.

TL;DR: In this article, column performance was studied as a function of particle size of the support, liquid loading of HDEHP, temperature, column cross-sectional area and bed length by measuring the plate height, H, as well as the mobile phase velocity, ν, for the elutions of Cf(III) and Cm(III).

TL;DR: In this paper, the DEHPA complexes of divalent cobalt, nickel and copper have tetrahedral, octahedral and square-planar structures with compositions CoX2.2H2O, NiX2HO, (NiX2O)3 and (CuX2)3 respectively.

TL;DR: In this paper, the ion exchange behavior of α-zirconium phosphate crystals titrated with potassium ion and the behavior of the potassium-exchanged forms with HCl has been examined.

TL;DR: The reaction of several variously substituted pyridines with bis(acetylacetonato)oxovanadium(IV), VO(ACA)2, has been studied as mentioned in this paper.

TL;DR: In this paper, the I 0 values for 21 nuclides were determined based on cadmium ratio measurements and known values for the thermal neutron activation cross-sections for 152 Gd was found to be 1100±100b.

TL;DR: In this paper, the spectral, magnetic and conductance properties of 2,6-lutidine N-oxide (LNO) with various metal nitrates and thiocyanates were investigated.

TL;DR: In this paper, the Cu(I) halide complexes of bis(diphenylphosphino)methane (DPM) and 1,2-bis(diphosphino)-ethane(DPE) with X L ratio 2:1, 3:2, 4:3, 1:1 and 2:3 were isolated and characterized by analytical data, conductivity and mole.

TL;DR: Two crystal phases of strontium-nickel oxides, SrNiO3 and compounds with composition near SrNi2O5, containing tetra-and tri-valent nickel ions respectively, have been synthesized in oxidation atmosphere as mentioned in this paper.

TL;DR: In this paper, the authors studied the properties of indium(III) complexes with thiomalic, malic, and aspartic acid and found that the trend in the stability constant values of these complexes was thIoS > malic > asPartic.

TL;DR: In this paper, the complexes formed by zinc(II), cadmium(II) and mercury (II) thiocyanates with pyridine have been examined spectroscopically (down to 222 cm−1) in the solid state.

TL;DR: The phase transition temperature between the body-centered cubic Cf2O3 and monoclinic CfO3 is ∼ 1400°C as mentioned in this paper, and these phases have a rhombohedral structure.

TL;DR: The first uncharged hepta-coordinate organometallic molecule with monodentate ligands for which a structure has been determined by X-ray crystallography is MoCl2(CO)2£(CH3)2C6H53 as mentioned in this paper.

TL;DR: In this article, a variety of complexes of the general formulae L Au X and L AU X 3 (L = neutral ligand; X = Cl, Br, I) have been prepared and their i.r. spectra studied in the region 145-600 cm −1.

TL;DR: A microcrystalline cerium(IV) phosphate with formula CeH2P2O8.1.33H2O has been synthesized and characterized by its X-ray diffraction pattern as discussed by the authors.

TL;DR: In this article, the stability constants and enthalpies of formation for the formation of the lanthanide monomalonato complexes were determined by potentiometric and calorimetric titrations in solutions of 0·10 M (NaClO4) and 2·00 M ionic strength.

TL;DR: In this article, the stability constants for the cyanide complexes of Cu(I, Ag(I), and Au(I) in aqueous solution were determined, and the E0 for Au(CN)2− was found to be −0·50V, which was combined with a previous estimate of the Au+(aq)/Au(s) standard reduction potential (+1·668V) to give log β2 = 36·6.

TL;DR: In this paper, the stability constants for simple and mixed dl(X)- and meso(Y)-tartaric acid complexes of Fe(III), La(III) and Nd(III).

TL;DR: In this article, the magnetic properties over the temperature range from 80° to 300°K are reported for a number of copper(II) complexes with N-hydroxyalkylsalicylideneimines having empirical formulae.