Showing papers in "Journal of Organometallic Chemistry in 2020"

TL;DR: In this article, a solgel process was used to synthesize MWCNTs/Li-doped TiO2 nanoparticles via a sol-gel process from MWC NTs, titanium isopropoxide (Ti (OPr)4, and LiCl4.

TL;DR: In this paper, Fe3O4 nanoparticles from the solution of ferrous/ferric mixed salt solution for alkaline medium were prepared using the chemical co-precipitation process.

TL;DR: In this paper, the synthesis and evaluation of new (B←N) and (B-O) units containing aminebis(phenolate) boron complexes designed by combination of amine-bis-phenolate ligands and various boronic acids in toluene reflux using a Dean-Stark apparatus was discussed.

TL;DR: A short review of some of our recent work mainly targeting cancer-related oncoproteins through the development of primarily novel air and water-stable iron-based organometallic agents is presented in this article.

TL;DR: The organometallic Schiff base ligand (L) was synthesized by reacting 2-acetylferrocene with 1,8-naphthalenediamine in 1:1 molar ratio as mentioned in this paper.

TL;DR: In this paper, the palladium(II) Schiff base complexes of the general formula [Pd(L1−6)2] [L1 = Naphthyl-salicyl-aldimine (1), L2 = NAPHthyl)-methoxysalicylaldimines (2), L3 = Nphthyl]-methoxide-methoxy-1-naphthydimine(3), L4 = Niphthyl-(Biphenyl)-saloxide-2-hydroxy-

TL;DR: In this paper, five homobimetallic compounds derived from indacene and p-phenylene ligands with different Fe-Fe distances have been synthesized, and the catalytic effect on the thermal decomposition of Ammonium perchlorate (AP) of each complex is analyzed, establishing comparisons with catocene (Cat) and ferrocene (Fc).

TL;DR: In this paper, the authors reviewed recent advances in the active field of Fc-based derivatives of burning rate catalysts and discussed their significant improvements in anti-migration properties.

TL;DR: In this paper, a review summarizes the synthetic routes and potential effect of fluorine or fluorinated substituents on N-heterocyclic carbenes and their applications in catalysis.

TL;DR: Aromatic amidines 1a-e undergo facile reaction with one isocyanide in PdCl2(CNBut)2 giving carbene complexes 2b-d (Scheme 2) in high isolated yields as mentioned in this paper.

TL;DR: In this article, the use of group 4 metals as Lewis acid catalysts for the synthesis of polycarbonates (PCs) and cyclic carbonates (CCs) by the copolymerization and cycloaddition of epoxides and CO2 respectively.

TL;DR: In this article, a facile synthetic strategy for the synthesis of 1,5-disubstituted tetrazole (1,5)-based chromone derivatives with different through photocatalyzed one-pot multicomponent reactions between aldehyde derivatives 7a-c, sodium azide, chromenocyl bromide in presence of triethylamine using ZnO nanorods (NRs) and Ag-doped NN composites (NCs).

TL;DR: This tutorial article describes the detailed protocols for studies with human plasma and human microsomes, which simulate the conditions in the blood and liver, respectively, so that medicinal chemists from organometallic backgrounds can take the plunge without fear.

TL;DR: A review of the recent advances in nickel-catalyzed cyanation reaction can be found in this paper, which covers literature from 2001 to 2019, focusing on the recent developments in nickel catalyzed cyanidation.

TL;DR: In this article, a water-soluble polymer nanocomposites with gold nanoparticles (AuNPs) were synthesized using functional copolymer of 1-vinyl-1,2,4-triazole with Nvinylpyrrolidone as a stabilizing matrix.

TL;DR: In this paper, the role of axial nitrogen-donor ligands was explored and the photophysical properties of these complexes were investigated in detail, revealing that they are photoluminescent in air-equilibrated pH 7.4 phosphate-buffered saline with quantum yields ranging from 1.7 to 3.1%.

TL;DR: In this paper, the synthesis, structural features and catalytic activity of rhoda-and iridacarborane halide complexes containing monoanionic dicarbollide [L-C2B9H10]− (L = SMe2, NMe3) and tricarborone [tBuHN-C3B8H10]- ligands are discussed.

TL;DR: In this paper, the reactivity of unsymmetrical pyrazole-based PCN pincer Ni(II) halides has been tested in the presence of copper(II)-halides as an oxidizing agent as well as with NaBH4 and LiAlH4 as a hydride source.

TL;DR: In this article, butylene linked bis-benzimidazole-based N-heterocyclic carbene precursors and their PEPPSI-type bimetallic Pd-complexes were reported.

TL;DR: A new class of cheap, easily synthesized and modifiable boronate esters (B1, B3, B4, B6) and their corresponding N-Heterocyclic Carbene (NHC)-stabilized boronal esters have been synthesized for the first time under toluene reflux using a Dean-Stark apparatus to remove the water by-product as mentioned in this paper.

TL;DR: In this article, the effects of steric property, hydrophilicity, and binding energy of NHC to O2 and H2O on the decomposition of Cu(I)−NHC were studied using theoretical calculations.

TL;DR: In this article, tetra and octa substituted zinc and copper phthalocyanines have been studied as hole transporting materials in the inverted-type (p-i-n) PSCs without using any dopant material.

TL;DR: In this paper, the authors describe the advances in the development of the homogenous catalytic systems for asymmetric hydrosilylation of prochiral ketones for the period of 2010-2020, which is characterized by significant progress in the efficiency of the catalytic system using base metals, expansion of the substrate scope, and further improvement of reaction conditions.

TL;DR: The results revealed that complexes 4 and 5 displayed significant changes in their spectral features upon addition of SM-DNA, thus, indicating that these complexes bind to DNA with a significant affinity.

TL;DR: The dimesitylborylcarborane [1-BMes2-2-me-closo-1,2-C2B10H10] (1) was reported to have Acceptor Numbers very close to that of the known 2-H and 2-Ph analogues as discussed by the authors.

TL;DR: Pyridyl benzothiazole hydrazone derivatives containing ruthenium, rhodium and iridium complexes have been synthesized, characterized and evaluated for antimicrobial activity.

TL;DR: In this article, the effects of different reaction parameters, i.e., the use of several other solvents, the temperature, the carbon monoxide pressure, the base and the catalyst concentrations, were evaluated in details on the efficiency of the carbonylations.

TL;DR: In this article, the interaction of Cu(NO3)2 with pentyl {[benzyl(dibutyl)ammonio]methyl}phosphonate (L) was studied by Fourier Transform Infrared (FTIR) spectroscopy with the use of isomolar series solution.

TL;DR: In this article, phthalonitrile (3) and non-peripherally tetra triclosan (5-chloro-2-(2,4-dichlorophenoxy)phenol) substituted phthalocyanine (4) and its metallo-phthalocyanines derivatives (5 and 6) were prepared.

TL;DR: In this paper, ammonium perchlorate (AP)-based propellants, such as ferrocenylated-amino pyridines (AP-Fcs) and ferrocene thiazoles (AT-Fqs), have been synthesized.