Showing papers in "Journal of Petrology in 2005"

Constraints from Thorium/Lanthanum on Sediment Recycling at Subduction Zones and the Evolution of the Continents

Abstract: Arc magmas and the continental crust share many chemical features, but a major question remains as to whether these features are created by subduction or are recycled from subducting sediment. This question is explored here using Th/La, which is low in oceanic basalts ( 0·25) and varies in arc basalts and marine sediments (0·09–0·34). Volcanic arcs form linear mixing arrays between mantle and sediment in plots of Th/La vs Sm/La. The mantle end-member for different arcs varies between highly depleted and enriched compositions. The sedimentary end-member is typically the same as local trench sediment. Thus, arc magmas inherit their Th/La from subducting sediment and high Th/La is not newly created during subduction (or by intraplate, adakite or Archaean magmatism). Instead, there is a large fractionation in Th/La within the continental crust, caused by the preferential partitioning of La over Th in mafic and accessory minerals. These observations suggest a mechanism of ‘fractionation & foundering’, whereby continents differentiate into a granitic upper crust and restite-cumulate lower crust, which periodically founders into the mantle. The bulk continental crust can reach its current elevated Th/La if arc crust differentiates and loses 25–60% of its mafic residues to foundering.

Post-Collisional Transition from Subduction- to Intraplate-type Magmatism in the Westernmost Mediterranean: Evidence for Continental-Edge Delamination of Subcontinental Lithosphere

Abstract: Post-collisional magmatism in the southern Iberian and northwestern African continental margins contains important clues for the understanding of a possible causal connection between movements in the Earth's upper mantle, the uplift of continental lithosphere and the origin of circum-Mediterranean igneous activity. Systematic geochemical and geochronological studies (major and trace element, Sr–Nd–Pb-isotope analysis and laser 40Ar/39Ar-age dating) on igneous rocks provide constraints for understanding the post-collisional history of the southern Iberian and northwestern African continental margins. Two groups of magmatic rocks can be distinguished: (1) an Upper Miocene to Lower Pliocene (8·2–4·8 Ma), Si–K-rich group including high-K (calc-alkaline) and shoshonitic series rocks; (2) an Upper Miocene to Pleistocene (6·3–0·65 Ma), Si-poor, Na-rich group including basanites and alkali basalts to hawaiites and tephrites. Mafic samples from the Si–K-rich group generally show geochemical affinities with volcanic rocks from active subduction zones (e.g. Izu–Bonin and Aeolian island arcs), whereas mafic samples from the Si-poor, Na-rich group are geochemically similar to lavas found in intraplate volcanic settings derived from sub-lithospheric mantle sources (e.g. Canary Islands). The transition from Si-rich (subduction-related) to Si-poor (intraplate-type) magmatism between 6·3 Ma (first alkali basalt) and 4·8 Ma (latest shoshonite) can be observed both on a regional scale and in individual volcanic systems. Si–K-rich and Si-poor igneous rocks from the continental margins of southern Iberia and northwestern Africa are, respectively, proposed to have been derived from metasomatized subcontinental lithosphere and sub-lithospheric mantle that was contaminated with plume material. A three-dimensional geodynamic model for the westernmost Mediterranean is presented in which subduction of oceanic lithosphere is inferred to have caused continental-edge delamination of subcontinental lithosphere associated with upwelling of plume-contaminated sub-lithospheric mantle and lithospheric uplift. This process may operate worldwide in areas where subduction-related and intraplate-type magmatism are spatially and temporally associated.

Magma Generation at a Large, Hyperactive Silicic Volcano (Taupo, New Zealand) Revealed by U–Th and U–Pb Systematics in Zircons

Abstract: Young (<65 ka) explosive silicic volcanism at Taupo volcano, New Zealand, has involved the development and evacuation of several crustal magmatic systems. Up to and including the 26·5 ka 530 km3 Oruanui eruption, magmatic systems were contemporaneous but geographically separated. Subsequently they have been separated in time and have vented from geographically overlapping areas. Single-crystal (secondary ionization mass spectrometry) and multiple-crystal (thermal ionization mass spectrometry) zircon model-age data are presented from nine representative eruption deposits from 45 to 3·5 ka. Zircon yields vary by three orders of magnitude, correlating with the degrees of zircon saturation in the magmas, and influencing the spectra of model ages. Two adjacent magma systems active up to 26·5 ka show wholly contrasting model-age spectra. The smaller system shows a simple unimodal distribution. The larger system, using data from three eruptions, shows bimodal model-age spectra. An older 100 ka peak is interpreted to represent zircons (antecrysts) derived from older silicic mush or plutonic rocks, and a younger peak to represent zircons (phenocrysts) that grew in the magma body immediately prior to eruption. Post-26·5 ka magma batches show contrasting age spectra, consistent with a mixture of antecrysts, phenocrysts and, in two examples, xenocrysts from Quaternary plutonic and Mesozoic–Palaeozoic metasedimentary rocks. The model-age spectra, coupled with zircon-dissolution modelling, highlight contrasts between short-term silicic magma generation at Taupo, by bulk remobilization of crystal mush and assimilation of metasediment and/or silicic plutonic basement rocks, and the longer-term processes of fractionation from crustally contaminated mafic melts. Contrasts between adjacent or successive magma systems are attributed to differences in positions of the source and root zones within contrasting domains in the quartzo-feldspathic (<15 km deep) crust below the volcano.

Similar V/Sc Systematics in MORB and Arc Basalts: Implications for the Oxygen Fugacities of their Mantle Source Regions

Abstract: V/Sc systematics in peridotites, mid-ocean ridge basalts and arc basalts are investigated to constrain the variation of fO2 in the asthenospheric mantle. V/Sc ratios are used here to ‘ see through’ those processes that can modify barometric fO2 determinations in mantle rocks and/or magmas: early fractional crystallization, degassing, crustal assimilation and mantle metasomatism. Melting models are combined here with a literature database on peridotites, arc lavas and mid-ocean ridge basalts, along with new, more precise data on peridotites and selected arc lavas. V/Sc ratios in primitive arc lavas from the Cascades magmatic arc are correlated with fluidmobile elements (e.g. Ba and K), indicating that fluids may subtly influence fO2 during melting. However, for the most part, the average V/Sc-inferred fO2s of arc basalts, MORB and peridotites are remarkably similar ( 1 25 to þ0 5 log units from the FMQ buffer) and disagree with the observation that the barometric fO2s of arc lavas are several orders of magnitude higher. These observations suggest that the upper part of the Earth’s mantle may be strongly buffered in terms of fO2. The higher barometric fO2s of arc lavas and some arc-related xenoliths may be due respectively to magmatic differentiation processes and to exposure to large, time-integrated fluid fluxes incurred during the long-term stability of the lithosphericmantle.

Geochemistry, Petrogenesis and Metallogenesis of the Panzhihua Gabbroic Layered Intrusion and Associated Fe-Ti-V Oxide Deposits, Sichuan Province, SW China

Abstract: The Panzhihua gabbroic layered intrusion is associated with the 260Ma Emeishan Large Igneous Province in SW China. This sill-like body hosts a giant Fe–Ti–V oxide deposit with 1333 million ton ore reserves, which makes China a major producer of these metals. The intrusion has a Marginal zone of fine-grained hornblende-bearing gabbro and olivine gabbro, followed upward by Lower, Middle, and Upper zones. The Lower and Middle zones consist of layered melanogabbro and gabbro composed of cumulate clinopyroxene, plagioclase, and olivine. These zones also contain magnetite layers. The Upper zone consists chiefly of leucogabbro composed of plagioclase and clinopyroxene with minor olivine. Most rocks in the body show variable-scale rhythmic modal layering in which dark minerals, primarily clinopyroxene, dominate in the lower parts of each layer, and lighter minerals, primarily plagioclase, dominate in the upper parts. The oxide ores occur as layers and lenses within the gabbros and are concentrated in the lower parts of the intrusion. Ore textures and associated mineral assemblages indicate that the ore bodies formed by very late-stage crystallization of V-rich titanomagnetite from an immiscible oxide liquid in a fluidrich environment. The rocks of the Panzhihua intrusion become more evolved in chemistry upward and follow a tholeiitic differentiation trend with enrichment in Fe, Ti, and V. They are enriched in light rare earth elements relative to heavy rare earth elements, and exhibit positive Nb, Ta, and Ti anomalies and negative Zr and Hf anomalies. The silicate rocks and oxide ores of the Panzhihua intrusion formed from highly evolved Fe–Ti–V-rich ferrobasaltic or ferropicritic magmas. The textures of the ores and the abundance of minor hydrous phases indicate that addition of fluids from upper crustal wall-rocks induced the separation of the immiscible oxide melts from which the Fe–Ti–V oxide ore bodies in the lower part of the intrusion crystallized.

Lower Crustal Magma Genesis and Preservation: a Stochastic Framework for the Evaluation of Basalt–Crust Interaction

Abstract: We present a quantitative assessment of the thermal and dynamic response of an amphibolitic lower crust to the intrusion of basaltic dike swarms in an arc setting. We consider the effect of variable intrusion geometry, depth of intrusion, and basalt flux on the production, persistence, and interaction of basaltic and crustal melt in a stochastic computational framework. Distinct melting and mixing environments are predicted as a result of the crustal thickness and age of the arc system. Shallow crustal (� 30km) environments and arc settings with low fluxes of mantle-derived basalt are likely repositories of isolated pods of mantle and crustal melts in the lower crust, both converging on dacitic to rhyodacitic composition. These may be preferentially rejuvenated in subsequent intrusive episodes. Mature arc systems with thicker crust (� 50km) produce higher crustal and residual basaltic melt fractions, reaching � 0� 4 for geologically reasonable basalt fluxes. The basaltic to basaltic andesite composition of both crustal and mantle melts will facilitate mixing as the network of dikes collapses, and Reynolds numbers reach 10 � 4 –1� 0 in the interiors of dikes that have been breached by ascending crustal melts. This may provide one mechanism for melting, assimilation, storage and homogenization (MASH)-like processes. Residual mineral assemblages of crust thickened by repeated intrusion are predicted to be garnet pyroxenitic, which are denser than mantle peridotite and also generate convective instabilities where some of the crustal material is lost to the mantle. This reconciles the thinner than predicted crust in regions that have undergone a large flux of mantle basalt for a prolonged period of time, and helps explain the enrichment of incompatible elements such as K2O, typical of mature arc settings, without the associated mass balance problem.

Continuous Gradations among Primary Carbonatitic, Kimberlitic, Melilititic, Basaltic, Picritic, and Komatiitic Melts in Equilibrium with Garnet Lherzolite at 3–8 GPa

Abstract: Multianvil melting experiments in the system CaO–MgO–Al2O3– SiO2–CO2 (CMAS–CO2) at 3–8GPa, 1340–1800 � C, involving the garnet lherzolite phase assemblage in equilibrium with CO2-bearing melts, yield continuous gradations in melt composition between carbonatite, kimberlite, melilitite, komatiite, picrite, and basalt melts. The phase relations encompass a divariant surface in P–T space. Comparison of the carbonatitic melts produced at the low-temperature side of this surface with naturally occurring carbonatites indicates that natural magnesiocarbonatites could be generated over a wide range of pressures >2� 5GPa. Melts analogous to kimberlites form at higher temperatures along the divariant surface, which suggests that kimberlite genesis requires more elevated geotherms. However, the amount of water found in some kimberlites has the potential to lower temperatures for the generation of kimberlitic melts by up to 150 � C, provided no hydrous phases are present. Compositions resembling group IB and IA kimberlites are produced at pressures around 5–6GPa and 10GPa, respectively, whereas the compositions of some other kimberlites suggest generation at higher pressures still. At pressures <4GPa, an elevated geotherm produces melilitite-like meltinthe CMAS–CO2system ratherthan kimberlite. Even when a relatively CO2-rich mantle composition containing 0� 15 wt % CO2 is assumed, kimberlites and melilitites are produced by <1% melting and carbonatites are generated by even smaller degrees of melting of <0� 5%.

Potassic Magmatism in Western Sichuan and Yunnan Provinces, SE Tibet, China: Petrological and Geochemical Constraints on Petrogenesis

Abstract: Potassic volcanism in the western Sichuan and Yunnan Provinces, SE Tibet, forms part of an extensive magmatic province in the eastern Indo-Asian collision zone during the Paleogene (40–24Ma). The dominant rock types are phlogopite-, clinopyroxeneand olivinephyric calc-alkaline (shoshonitic) lamprophyres. They are relatively depleted in Na2O, Fe2O3, and Al2O3 compared with the late Permian–early Triassic Emeishan continental flood basalts in the western part of the Yangtze craton, and have very high and variable abundances of incompatible trace elements. Primitive mantle-normalized incompatible element patterns have marked negative Nb, Ta and Ti anomalies similar to those of K-rich subduction-related magmas, although the geodynamic setting is clearly post-collisional. Spatially, some incompatible trace element abundances, together with inferred depths of melt segregation based on the Mg-15 normalized compositions of the samples, display progressive zonation trends from SW to NE with increasing distance from the western boundary of the Yangtze craton. Systematic variations in major and trace element abundances and Sr–Nd–Pb isotope compositions appear to have petrogenetic significance. The systematic increases in incompatible trace element abundances from the western margin to the interior of the Yangtze craton can be explained by progressively decreasing extents of partial melting, whereas steady changes in some incompatible trace element ratios can be attributed to changes in the amount of subduction-derived fluid added to the lithospheric mantle of the Yangtze craton. The mantle source region of the lamprophyres is considered to be a relatively refractory phlogopite-bearing spinel peridotite, heterogeneously enriched by fluids derived from earlier phases of late Proterozoic and Palaeozoic subduction beneath the western part of the Yangtze craton. Calculations based on a non-modal batch melting model show that the degree of partial melting ranges from 0 6% to 15% and the proportion of subduction-derived fluid added from 0 1% to 0 7% (higher-Ba fluid) or from 5% to 25% (lowerBa fluid) from the interior to the western margin of the Yangtze craton. Some pre-existing lithospheric faults might have been reactivated in the area neighbouring the Ailao Shan–Red River (ASRR) strike-slip belt, accompanying collision-induced extrusion of the Indo-China block and left-lateral strike-slip along the ASRR shear zone. This, in turn, could have triggered decompression melting of the previously enriched mantle lithosphere, resulting in calc-alkaline lamprophyric magmatism in the western part of the Yangtze craton.

Evidence for a Widespread Tethyan Upper Mantle with Indian-Ocean-Type Isotopic Characteristics

Abstract: The mantle sources of Tethyan basalts and gabbros from Iran, Tibet, the eastern Himalayas, the seafloor off Australia, and possibly Albania were isotopically similar to those of present-day Indian Ocean ridges and hotspots. Alteration-resistant incompatible element compositions of many samples resemble those of ocean-ridge basalts, although ocean-island-like compositions are also present. Indian-Ocean-type mantle was widespread beneath the Neotethys in the Jurassic and Early Cretaceous, and present beneath at least parts of the Paleotethys as long ago as the Early Carboniferous. The mantle beneath the Indian Ocean today thus may be largely 'inherited' Tethyan mantle. Although some of the Tethyan rocks may have formed in intra-oceanic back-arcs or fore-arcs, contamination of the asthenosphere by material subducted shortly before mogmatism cannot be a general explanation for their Indian-Ocean-ridge-like low- 206Pb/ 204Pb signatures. Supply of low- 206Pb/ 204Pb material to the asthenosphere via plumes is not supported by either present-day Indian Ocean hotspots or the ocean-island-like Tethyan rocks. Old continental lower crust or lithospheric mantle, including accreted, little-dehydrated marine sedimentary material, provides a potential low- 206Pb/ 204Pb reservoir only if sufficient amounts of such material can be introduced into the asthenosphere over time. Anciently subducted marine sediment is a possible low- 206Pb/ 204Pb source only if the large increase of U/ Pb that occurs during subduction-related dewatering is somehow avoided. Fluxing of low-U/Pb fluids directly into the asthenosphere during ancient dewatering and introduction of ancient pyroxenitic lowercrustal restite or basaltic lower-arc crust into the asthenosphere provide two other means of creating Tethyan-Indian Ocean mantle, but these mechanisms, too, have potentially significant problems. © The Author 2005. Published by Oxford University Press. All rights reserved.

Near-Ultrahigh Pressure Processing of Continental Crust: Miocene Crustal Xenoliths from the Pamir

Abstract: Xenoliths of subducted crustal origin hosted by Miocene ultrapotassic igneous rocks in the southern Pamir provide important new information regarding the geological processes accompanying tectonism during the Indo-Eurasian collision Four types have been studied: sanidine eclogites (omphacite, garnet, sanidine, quartz, biotite, kyanite), felsic granulites (garnet, quartz, sanidine and kyanite), basaltic eclogites (omphacite and garnet), and a glimmerite (biotite, clinopyroxene and sanidine) Apatite, rutile and carbonate are the most abundant minor phases Hydrous phases (biotite and phengite in felsic granulites and basaltic eclogites, amphiboles in mafic and sanidine eclogites) and plagioclase form minor inclusions in garnet or kyanite Solid-phase thermobarometry reveals recrystallization at mainly ultrahigh temperatures of 1000–1100 C and nearultrahigh pressures of 2 5–2 8GPa Textures, parageneses and mineral compositions suggest derivation of the xenoliths from subducted basaltic, tonalitic and pelitic crust that experienced highpressure dehydration melting, K-rich metasomatism, and solid-state re-equilibration The timing of these processes is constrained by zircon ages from the xenoliths and Ar/Ar ages of the host volcanic rocks to 57–11Ma These xenoliths reveal that deeply subducted crust may undergo extensive dehydration-driven partial melting, density-driven differentiation and disaggregation, and sequestration within the mantle These processes may also contribute to the alkaline volcanism observed in continent-collision zones

Geochemical Evidence for Mantle Origin and Crustal Processes in Volcanic Rocks from Popocatépetl and Surrounding Monogenetic Volcanoes, Central Mexico

Abstract: Elemental, isotopic, and mineral compositions as well as rock textures were examined in samples from Popocatepetl volcano and immediately surrounding monogenetic scoria cones of the Sierra Chichinautzin Volcanic Field, central Mexico. Magma generation is strongly linked to the active subduction regime to the south. Rocks range in composition from basalt to dacite, but Popocatepetl samples are generally more evolved and have mineral compositions and textures consistent with more complicated, multi-stage evolutionary processes. High-Mg calc-alkaline and more alkaline primitive magmas are present in the monogenetic cones. Systematic variations in major and trace element compositions within the monogenetic suite can mostly be explained by polybaric fractional crystallization processes in small and short-lived magmatic systems. In contrast, Popocatepetl stratovolcano has produced homogeneous magma compositions from a shallow, long-lived magma chamber that is periodically replenished by primitive basaltic magmas. The current eruption (1994–present) has produced silicic dome lavas and pumice clasts that display mingling of an evolved dacitic component with an olivine-bearing mafic component. The longevity of the magma chamber hosted in Cretaceous limestones has fostered interaction with these rocks as evidenced by the chemical and isotopic compositions of the different eruptive products, contact-metamorphosed xenoliths, and fumarolic gases. Popocatepetl volcanic products display a considerable range of Sr/Sr (0 70397–0 70463) and eNd (þ6 2 to þ3 0) whereas Pb isotope ratios are relatively homogeneous (Pb/Pb 18 61–18 70; Pb/Pb 15 56–15 60).

Integrating Ultramafic Lamprophyres into the IUGS Classification of Igneous Rocks: Rationale and Implications

Abstract: RECEIVED JULY 16, 2004; ACCEPTED MARCH 16, 2005ADVANCE ACCESS PUBLICATION APRIL 29, 2005We introduce a modification to the current IUGS classificationsystem for igneous rocks to include ultramafic lamprophyres, whicharecurrentlyentirelyomitted.Thisisdonebyincludinganewstepinthe sequential system, after the assignment of pyroclastic rocks andcarbonatites, that considers ultramafic inequigranular textured rockswith olivine and phlogopite macrocrysts and/or phenocrysts. At thisstepultramaficlamprophyresareconsideredtogetherwithkimberlites,orangeites (former Group 2 kimberlites) and olivine lamproites.This proposal allows the correct identification and classificationof ultramafic lamprophyres within the IUGS scheme. Only threeend-members are required for describing the petrographic and com-positional continuum of ultramafic lamprophyres: alno¨ite (essentialgroundmass melilite), aillikite (essential primary carbonate) anddamtjernite (essentialgroundmass nepheline and/or alkali feldspar).It is argued that all ultramafic lamprophyre rock types canbe relatedto a common magma type which differs in important petrogeneticaspects from kimberlites, orangeites, olivine lamproites and theremainder of lamprophyres such as alkaline and calc-alkaline vari-eties. Ultramafic lamprophyres can be readily distinguished fromolivine lamproites by the occurrence of primary carbonates, and fromkimberlites by the presence of groundmass clinopyroxene. In othercases distinction between aillikites, kimberlites and orangeites mustrely on mineral compositions in order to recognize their petrogeneticaffinities.

Crystal size distributions (CSD) in three dimensions : insights from the 3D reconstruction of a highly porphyritic rhyolite.

Abstract: Growth histories and residence times of crystals in magmatic systems can be revealed by studying crystal sizes, size distributions and shapes. In this contribution, serial sectioning has been employed on a sample of porphyritic rhyolite from a Permo-Carboniferous laccolith from the Halle Volcanic Complex, Germany, to reconstruct the distribution of felsic phenocrysts in three dimensions in order to determine their true shapes, sizes and three-dimensional size distributions. A model of all three phenocryst phases (quartz, plagioclase, K-feldspar) with 217 crystals, and a larger model containing 1599 K-feldspar crystals was reconstructed in three dimensions. The first model revealed a non-touching framework of crystals in three dimensions, suggesting that individual crystals grew freely in the melt prior to quenching of the texture. However, crystal shapes are complex and show large variation on a Zingg diagram (intermediate over long axis plotted against short over intermediate axis). They often do not resemble the crystallographic shapes expected for phenocrysts growing unhindered from a melt, indicating complex growth histories. In contrast, the three-dimensional size distribution is a simple straight line with a negative slope. Stereologically corrected size distributions from individual sections compare well with stereologically corrected size distributions obtained previously from the same sample. However, crystal size distribution (CSD) data from individual sections scatter considerably. It is shown that CSDs can be robustly reproduced with a sampling size of greater than � 200 crystals. The kind of shape assumed in stereological correction of CSDs, however, has a large influence on the calculation and estimation of crystal residence times.

Tertiary Ultrapotassic Volcanism in Serbia: Constraints on Petrogenesis and Mantle Source Characteristics

Abstract: The Serbian province of Tertiary ultrapotassic volcanism is related to a post-collisional tectonic regime that followed the closure of the Tethyan Vardar Ocean by Late Cretaceous subduction beneath the southern European continental margin. Rocks of this province form two ultrapotassic groups; one with affinities to lamproites, which is concentrated mostly in the central parts of the Vardar ophiolitic suture zone, and the other with affinities to kamafugites, which crops out in volcanoes restricted to the western part of Serbia. The lamproitic group is characterized by a wide range of Sr/Sri (0 70735–0 71299) and Nd/Ndi (0 51251–0 51216), whereas the kamafugitic group is isotopically more homogeneous with a limited range of Sr/Sri (0 70599–0 70674) and Nd/Ndi (0 51263–0 51256). The Pb isotope compositions of both groups are very similar (Pb/Pb 18 58–18 83, Pb/Pb 15 62–15 70 and Pb/Pb 38 74–38 99), falling within the pelagic sediment field and resembling Mesozoic flysch sediments from the Vardar suture zone. The Sr and Nd isotopic signatures of the primitive lamproitic rocks correlate with rare earth element fractionation and enrichment of most high field strength elements (HFSE), and can be explained by melting of a heterogeneous mantle source consisting of metasomatic veins with phlogopite, clinopyroxene and F-apatite that are out of isotopic equilibrium with the peridotite wall-rock. Decompression melting, with varying contributions from depleted peridotite and ultramafic veins to the final melt, accounts for consistent HFSE enrichment and isotopic variations in the lamproitic group. Conversely, the most primitive kamafugitic rocks show relatively uniform Sr and Nd isotopic compositions and trace element patterns, and small but regular variations of HFSE, indicating variable degrees of partial melting of a relatively homogeneously metasomatized mantle source. Geochemical modelling supports a role for phlogopite, apatite and Ti-oxide in the source of the kamafugitic rocks. The presence of two contrasting ultrapotassic suites in a restricted geographical area is attributable to the complex geodynamic situation involving recent collision of a number of microcontinents with contrasting histories and metasomatic imprints in their mantle lithosphere. The geochemistry of the Serbian ultrapotassic rocks suggests that the enrichment events that modified the source of both lamproitic and kamafugitic groups were related to Mesozoic subduction events. The postcollisional environment of the northern Balkan region with many extensional episodes is consistent at regional and local levels with the occurrence of ultrapotassic rocks, providing a straightforward relationship between geodynamics and volcanism.

Early–Middle Jurassic dolerite dykes from western Dronning Maud Land (Antarctica): identifying mantle sources in the Karoo Large Igneous Province

Abstract: A suite of dolerite dykes from the Ahlmannryggen region of western Dronning Maud Land (Antarctica) forms part of the much more extensive Karoo igneous province of southern Africa. The dyke compositions include both low- and high-Ti magma types, including picrites and ferropicrites. New Ar-40/Ar-39 age determinations for the Ahlmannryggen intrusions indicate two ages of emplacement at similar to 178 and similar to 190 Ma. Four geochemical groups of dykes have been identified in the Ahlmannrygggen region based on analyses of similar to 60 dykes. ne groups are defined on the basis of whole-rock TiO2 and Zr contents, and reinforced by rare earth element (REE), Sr-87/Sr-86 and Nd-143/Nd-144 isotope data. Group I were intruded at similar to 190Ma and have low TiO2 and Zr contents and a significant Archaean crustal component, but also evidence of hydrothermal alteration. Group 2 dykes were intruded at similar to 178Ma; they have low to moderate TiO2 and Zr contents and are interpreted to be the result of mixing of melts derived from an isotopically depleted source with small melt fractions of an enriched lithospheric mantle source. Group 3 dyke were intruded at similar to 190Ma and form the most distinct magma group; these are largely picritic with superficially mid-ocean ridge basalt (MORB)-like chemistry (flat REE patterns, Sr-87/Sr-86, similar to 0.7035, is an element of Nd-i similar to 9). However, they have very high TiO2 (similar to 4 wt %) and Zr (similar to 500ppm) contents, which is not consistent with melting of MORB-source mantle. The Group 3 magmas are inferred to be derived by partial melting of a strongly depleted mantle source in the garnet stability field. This group includes several high Mg Fe dykes (ferropicrites), which are interpreted as high- temperature melts. Some Group 3 dykes also show evidence of contamination by continental crust. Group 4 dykes are low-K picrites intruded at similar to 178Ma; they have very high TiO2-Zr contents and are the most enriched magma group of the Karoo-Antarctic province, with ocean-island basalt (OIB)-like chemistry. Dykes of Group I and Group 3 are sub-parallel (ENE-WSW) and both groups were emplaced at similar to 190Ma in response to the same regional stress field, which had changed by similar to 178Ma, when Group 2 and Group 4 dykes were intruded along a dominantly NNE-SSW strike.

Petrogenesis of a Late Jurassic Peraluminous Volcanic Complex and its High-Mg, Potassic, Quenched Enclaves at Xiangshan, Southeast China

Abstract: A late Mesozoic belt of volcanic–intrusive complexes occurs in SE China. Volcanic activity at Xiangshan in the NW of the belt took place mainly in the Late Jurassic (158–135Ma). The volcanic rocks from the Xiangshan volcanic complex include rhyolitic crystal tuffs, welded tuffs, rhyolite lavas, porphyritic lavas, and associated subvolcanic rocks. Mineral assemblages in these magmatic rocks include K-feldspar, plagioclase, quartz, Fe-rich biotite and minor amphibole, orthopyroxene and almandine. Mineral geothermometry indicates a high crystallization temperature (>850 C) for the Xiangshan magmas. The volcanic rocks are generally peraluminous; SiO2 contents are between 65 4% and 76 8% and the samples have high alkalis, rare earth elements (REE), high field strength elements and Ga contents and high Ga/Al ratios, but are depleted in Ba, Sr and transition metals. Trace element geochemistry and Sr–Nd–O isotope systematics imply that the Xiangshan magmas were probably derived from partial melting of Middle Proterozoic metamorphic lower-crustal rocks that had been dehydrated during an earlier thermal event. These features suggest an A-type affinity. Quenched mafic enclaves, hosted by the subvolcanic rocks, consist mainly of alkali feldspar, plagioclase, clinopyroxene, phlogopite and amphibole. Geothermometry calculations indicate that the primary magmas that chilled to form the quenched enclaves had anomalously high temperatures (>1200 C). The quenched enclaves have boninitic affinities; for example, intermediate SiO2 contents, high MgO and low TiO2 contents, high Mg-numbers and high concentrations of Sc, Ni, Co and V. However, they also have shoshonitic characteristics, e.g. enrichment in alkalis, high K2O contents with high K2O/Na2O ratios, high light REE and large ion lithophile element contents, low initial eNd values ( 4 2) and high initial Sr/Sr ratios (0 7081). We suggest a phlogopite-bearing spinel harzburgitic lithospheric mantle source for these high-Mg potassic magmas. Underplating of such anomalously high-temperature magmas could have induced granulite-facies lower-crustal rocks to partially melt and generate the Xiangshan A-type volcanic suite. A back-arc extensional setting, related to subduction of the Palaeo-Pacific plate, is favoured to explain the petrogenesis of the Xiangshan volcanic complex and quenched enclaves.

Time markers for the evolution and exhumation history of a Late Palaeozoic paired metamorphic belt in North-Central Chile (34°-35°30′S)

Abstract: A multi-method geochronological approach is applied to unravel the dynamics of a paired metamorphic belt in the Coastal Cordillera of central Chile. This is represented by high-pressure - low-temperature rocks of an accretionary prism (Western Series), and a low-pressure- high-temperature overprint in the retro-wedge with less deformed metagreywackes (Eastern Series) intruded by magmas of the coeval arc. A pervasive transposition foliation formed in metagreywackes and interlayered oceanic crust of the Western Series during basal accretion near metamorphic peak conditions (∼350-400°C, 7-11 kbar) at 292-319 Ma (

Experimental Constraints on the Role of Garnet Pyroxenite in the Genesis of High-Fe Mantle Plume Derived Melts

Abstract: The anhydrous phase relations of an uncontaminated (primitive), ferropicrite lava from the base of the Early Cretaceous Parana´- Etendeka continental flood basalt province have been determined between 1 atm and 7GPa. The sample has high contents of MgO (� 14� 9 wt %), FeO* (14� 9 wt %) and Ni (660ppm). Olivine phenocrysts have maximum Fo contents of 85 and are in equilibrium with the bulk rock, assuming a K Olliquid DFeMg of 0� 32. A comparison of our results with previous experimental studies of high-Mg rocks shows that the high FeO content of the ferropicrite causes an expan- sion of the liquidus crystallization field of garnet and clinopyroxene relative to olivine; orthopyroxene was not observed in any of our experiments. The high FeO content also decreases solidus temper- atures. Phase relations indicate that the ferropicrite melt last equili- brated either at � 2� 2GPa with an olivine-clinopyroxene residue, or at � 5GPa with a garnet-clinopyroxene residue. The low bulk-rock Al2O3 content (9 wt %) and high (Gd/Yb)n ratio (3� 1) are consistent with the presence of residual garnet in the ferropicrite melt source and favour high-pressure melting of a garnet pyroxenite source. The garnet pyroxenite may represent subducted oceanic litho- sphereentrainedbytheupwellingTristanstartingmantleplumehead. During adiabatic decompression, intersection of the garnet pyroxenite solidus at � 5GPa would occur at a mantle potential temperature of � 1550 � C and yield a ferropicrite primary magma. Subsequent melting of the surrounding peridotite at � 4� 5GPa may be restricted by the thickness of the overlying sub-continental lithosphere, such that dilution of the garnet pyroxenite melt component would be signific- antly less than in intra-oceanic plate settings (where the lithosphere is thinner). This model may explain the limited occurrence of ferropicrites at the base of continental flood basalt sequences and their apparent absence in ocean-island basalt successions.

Temporal Evolution of Magmatism in the Northern Volcanic Zone of the Andes: The Geology and Petrology of Cayambe Volcanic Complex (Ecuador)

Abstract: In the Northern Volcanic Zone of the Andes, the Cayambe Volcanic Complex consists of: (1) a basal, mostly effusive volcano, the Viejo Cayambe, whose lavas (andesites and subordinate dacites and rhyolites) are typically calc-alkaline; and (2) a younger, essentially dacitic, composite edifice, the Nevado Cayambe, characterized by lavas with adakitic signatures and explosive eruptive styles. The construction of Viejo Cayambe began >1·1 Myr ago and ended at 1·0 Ma. The young and still active Nevado Cayambe grew after a period of quiescence of about 0·6 Myr, from 0·4 Ma to Holocene. Its complex history is divided into at least three large construction phases (Angureal cone, Main Summit cone and Secondary Summit cone) and comprises large pyroclastic events, debris avalanches, as well as periods of dome activity. Geochemical data indicate that fractional crystallization and crustal assimilation processes have a limited role in the genesis of each suite. On the contrary, field observations, and mineralogical and geochemical data show the increasing importance of magma mixing during the evolution of the volcanic complex. The adakitic signature of Nevado Cayambe magmas is related to partial melting of a basaltic source, which could be the lower crust or the subducted slab. However, reliable geophysical and geochemical evidence indicates that the source of adakitic component is the subducted slab. Thus, the Viejo Cayambe magmas are inferred to come from a mantle wedge source metasomatized by slab-derived melts (adakites), whereas the Nevado Cayambe magmas indicate a greater involvement of adakitic melts in their petrogenesis. This temporal evolution can be related to the presence of the subducted Carnegie Ridge, modifying the geothermal gradient along the Wadati–Benioff zone and favouring slab partial melting

Kimberlite-like Metasomatism and 'Garnet Signature' in Spinel-peridotite Xenoliths from Sal, Cape Verde Archipelago: Relics of a Subcontinental Mantle Domain within the Atlantic Oceanic Lithosphere?

Abstract: kimberlite-like metasomatism in the Cape Verde lithospheric mantle, together with the presence of lherzolitic domains, partially reequilibrated from the garnet to the spinel stability field, may suggest the presence of subcontinental mantle lithosphere relicts left behind by drifting of the African Plate during the opening of the Central Atlantic Ocean.

Pressure–Temperature Evolution of a Late Palaeozoic Paired Metamorphic Belt in North–Central Chile (34°–35°30′S)

Abstract: In the Chilean Coastal Cordillera, two units, the Western and Eastern Series, constitute coeval parts of a Late Palaeozoic paired metamorphic belt dominated by siliciclastic metasediments. The Western Series also contains rocks from the upper oceanic crust and represents an accretionary prism. Omnipresent high-pressure conditions are reflected by Na–Ca-amphibole and phengite in greenschists. Peak PT conditions of 7 0–9 3 kbar, 380–420 C point to a metamorphic gradient of 11–16 C/km. Three unique occurrences of blueschist yield deviating conditions of 9 5–10 7 kbar, 350– 385 C and are interpreted as relics from the lowermost part of the basal accretion zone preserving the original gradient of 9–11 C/km along the subducting slab. Pervasive ductile deformation related to basal accretion occurred near peak PT conditions. Deformation and PT evolution of the metapsammopelitic rocks is similar to that of the metabasites. However, a rare garnet mica-schist yields peak PT conditions of 9 6–14 7 kbar, 390–440 C reflecting a retrograde stage after cooling from a high-temperature garnet-forming stage. It is considered to be an exhumed relic from the earliest siliciclastic rocks subducted below a still hot mantle wedge. A retrograde overprint of all rock types occurred at 300–380 C. Continuous reactions caused crystal growth and recrystallization with abundant free water mostly under strain-free conditions. They record a pressure release of 3–4 kbar without erasing peak metamorphic mineral compositions. The Eastern Series lacks metabasite intercalations and represents a less deformed retro-wedge area. In the study area it was entirely overprinted at a uniform depth at 3 0 5 kbar with temperatures progressively rising from 400 C to 720 C towards the coeval Late Palaeozoic magmatic arc batholith. The interrelated pattern of PT data permits a conceptual reconstruction of the fossil convergent margin suggesting a flat subduction angle of 25 with continuous basal accretion at a depth of 25–40 km and a short main intrusion pulse in the magmatic arc. The latter was accompanied by the formation of a thermal dome in the retro-wedge area, which remained stable relative to the vertically growing accretionary prism characterized by cyclic mass flow.

On the Use of Changes in Dihedral Angle to Decode Late-stage Textural Evolution in Cumulates

Abstract: The melt-filled pore structure in the final stages of solidification of cumulates must lie somewhere between the two end-members of impingement (in which pore topology is controlled entirely by the juxtaposition of growth faces of adjacent grains) and textural equilibrium (in which pore topology is controlled by the minimization of internal energies). The exact position between these two end-members is controlled by the relative rates of crystal growth and textural equilibration. For samples in which growth has stopped, or is very slow, textural equilibrium will prevail. A close examination of dihedral angles in natural examples demonstrates that these two end-member textures can be distinguished. The impingement end-member results in a population of apparent solid–melt dihedral angles with a median of ∼60° and a standard deviation of ∼25–30°, whereas the texturally equilibrated end-member population has a median of ∼28° and a standard deviation of ∼14°. For the specific case of cumulates in the Rum Layered Intrusion, residual porosity in troctolitic cumulates was close to the impingement end-member, whereas that in peridotites was close to melt-bearing textural equilibrium. Suites of glass-bearing samples from small, or frequently disturbed, magma systems show modification of initial impingement textures. These modifications may be a consequence of textural equilibration or of diffusion-limited growth during quenching. Distinction can be made between these two processes by a consideration of grain shape. The geometry of interstitial phases in suites of fully solidified cumulates from the Rum Layered Intrusion shows variable approach to sub-solidus textural equilibrium from an initial state inherited by pseudmorphing of the last melt. Textural equilibration at pore corners occurs as a continuous process, with a gradual movement of the entire dihedral angle population towards the equilibrium final state. If the initial, pseudomorphed state is one of disequilibrium (i.e. a melt-present impingement texture) this change is accompanied by a reduction in the spread of the population. If it is one of equilibrium, the change is accompanied by an initial increase in the spread of the population, followed by a decrease. These observations demonstrate that previously published models of dihedral angle change involving the instantaneous establishment of the equilibrium angle in the immediate vicinity of the pore corner are incorrect.

Hafnium Isotope and Trace Element Constraints on the Nature of Mantle Heterogeneity beneath the Central Southwest Indian Ridge (13°E to 47°E)

Abstract: Hafnium isotope and incompatible trace element data are presented for a suite of mid-ocean ridge basalts (MORB) from 13 to 47 E on the Southwest Indian Ridge (SWIR), one of the slowest spreading and most isotopically heterogeneous mid-ocean ridges. Variations in Nd–Hf isotope compositions and Lu/Hf ratios clearly distinguish an Atlantic–Pacific-type MORB source, present west of 26 E, characterized by relatively low eHf values for a given eNd relative to the regression line through all Nd–Hf isotope data for oceanic basalts (termed the ‘Nd–Hf mantle array line’; the deviation from this line is termed DeHf) and low Lu/Hf ratios, from an Indian Ocean-type MORB signature, present east of 32 E, characterized by relatively high DeHf values and Lu/Hf ratios. Additionally, two localized, isotopically anomalous areas, at 13–15 E and 39–41 E, are characterized by distinctly low negative and high positive DeHf values, respectively. The low DeHf MORB from 13 to 15 E appear to reflect contamination by HIMU-type mantle from the nearby Bouvet mantle plume, whereas the trace element and isotopic compositions of MORB from 39 to 41 E are most consistent with contamination by metasomatized Archean continental lithospheric mantle. Relatively small source-melt fractionation of Lu/Hf relative to Sm/Nd, compared with MORB from faster-spreading ridges, argues against a significant role for garnet pyroxenite in the generation of most central SWIR MORB. Correlations between DeHf and Sr and Pb isotopic and trace element ratios clearly delineate a highDeHf ‘ Indian Ocean mantle component’ that can explain the isotope composition of most Indian Ocean MORB as mixtures between this component and a heterogeneous Atlantic–Pacific-type MORB source. The Hf, Nd and Sr isotope compositions of Indian Ocean MORB appear to be most consistent with the hypothesis that this component represents fragments of subduction-modified lithospheric mantle beneath Proterozoic orogenic belts that foundered into the nascent Indian Ocean upper mantle during the Mesozoic breakup of Gondwana.

Volcan Popocatepetl, Mexico. Petrology, magma mixing, and immediate sources of volatiles for the 1994 - Present eruption

Abstract: Volcan Popocatepetl has been the site of voluminous degassing accompanied by minor eruptive activity from late 1994 until the time of writing (August 2002). This contribution presents petrological investigations of magma erupted in 1997 and 1998, including major-element and volatile (S, Cl, F, and H2O) data from glass inclusions and matrix glasses. Magma erupted from Popocatepetl is a mixture of dacite (65 wt % SiO2, two-pyroxenes þ plagioclase þ Fe–Ti oxides þ apatite, 3 wt % H2O, P 1⁄4 1 5 kbar, f O2 1⁄4 DNNO þ 0 5 log units) and basaltic andesite (53 wt % SiO2, olivine þ two-pyroxenes, 3 wt % H2O, P 1⁄4 1–4 kbar). Magma mixed at 4–6 km depth in proportions between 45:55 and 85:15 wt % silicic:mafic magma. The pre-eruptive volatile content of the basaltic andesite is 1980 ppm S, 1060 ppm Cl, 950 ppm F, and 3 3 wt % H2O. The pre-eruptive volatile content of the dacite is 130 50 ppm S, 880 70 ppm Cl, 570 100 ppm F, and 2 9 0 2 wt % H2O. Degassing from 0 031 km of erupted magma accounts for only 0 7 wt % of the observed SO2 emission. Circulation of magma in the volcanic conduit in the presence of a modest bubble phase is a possible mechanism to explain the high rates of degassing and limited magma production at Popocatepetl.

Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks

Abstract: Andalusite occurs as an accessory mineral in many types of peraluminous felsic igneous rocks, including rhyolites, aplites, granites, pegmatites, and anatectic migmatites. Some published stability curves for And ¼ Sil and the water-saturated granite solidus permit a small stability field for andalusite in equilibrium with felsic melts. We examine 108 samples of andalusite-bearing felsic rocks from more than 40 localities world-wide. Our purpose is to determine the origin of andalusite, including the T–P–X controls on andalusite formation, using eight textural and chemical criteria: size— compatibility with grain sizes of igneous minerals in the same rock; shape—ranging from euhedral to anhedral, with no simple correlation with origin; state of aggregation—single grains or clusters of grains; association with muscovite—with or without rims of monocrystalline or polycrystalline muscovite; inclusions—rare mineral inclusions and melt inclusions; chemical composition—andalusite with little significant chemical variation, except in iron content (008–171 wt % FeO); compositional zoning—concentric, sector, patchy, oscillatory zoning cryptically reflect growth conditions; compositions of coexisting phases—biotites with high siderophyllite–eastonite contents (Aliv 268 007 atoms per formula unit), muscovites with 057–401 wt % FeO and 002– 285 wt % TiO2, and apatites with 353 018 wt % F. Coexisting muscovite–biotite pairs have a wide range of F contents, and FBt ¼ 1612FMs þ 0015. Most coexisting minerals have compositions consistent with equilibration at magmatic conditions. The three principal genetic types of andalusite in felsic igneous rocks are: Type 1 Metamorphic—(a) prograde metamorphic (in thermally metamorphosed peraluminous granites), (b) retrograde metamorphic (inversion from sillimanite of unspecified origin), (c) xenocrystic (derivation from local country rocks), and (d) restitic (derivation from source regions); Type 2 Magmatic—(a) peritectic (water-undersaturated, T") associated with leucosomes in migmatites, (b) peritectic (water-undersaturated, T#), as reaction rims on garnet or cordierite, (c) cotectic (water-undersaturated, T#) direct crystallization from a silicate melt, and (d) pegmatitic (watersaturated, T#), associated with aplite–pegmatite contacts or pegmatitic portion alone; Type 3 Metasomatic—(water-saturated, magma-absent), spatially related to structural discontinuities in host, replacement of feldspar and/or biotite, intergrowths with quartz. The great majority of our andalusite samples show one or more textural or chemical criteria suggesting a magmatic origin. Of the many possible controls on the formation of andalusite (excess Al2O3, water concentration and fluid evolution, high Be–B–Li–P, high F, high Fe–Mn–Ti, and kinetic considerations), the two most important factors appear to be excess Al2O3 and the effect of releasing water (either to strip alkalis from the melt or to reduce alumina solubility in the melt). Of particular importance is the evidence for magmatic andalusite in granites showing no significant depression of the solidus, suggesting that the And ¼ Sil equilibrium must cross the granite solidus rather than lie below it. Magmatic andalusite, however formed, is susceptible to supra- or sub-solidus reaction to produce muscovite. In many cases, textural evidence of this reaction remains, but in other cases muscovite may completely replace andalusite leaving little or no evidence of its former existence.

Mesoproterozoic Reworking of Palaeoproterozoic Ultrahigh-temperature Granulites in the Central Indian Tectonic Zone and its Implications

Abstract: In the southern periphery of the Sausar Mobile Belt (SMB), the southern component of the Central Indian Tectonic Zone (CITZ), a suite of felsic and aluminous granulites, intruded by gabbro, noritic gabbro, norite and orthopyroxenite, records the polymetamorphic evolution of the CITZ. Using sequences of prograde, peak and retrograde reaction textures, mineral chemistry, geothermobarometric results and petrogenetic grid considerations from the felsic and the aluminous granulites and applying metamorphosed mafic dyke markers and geochronological constraints, two temporally unrelated granulite-facies tectonothermal events of Pre-Grenvillian age have been established. The first event caused Ultrahigh-temperature (UHT) metamorphism (M1) (T ∼950°C) at relatively deeper crustal levels (P ∼9 kbar) and a subsequent post-peak near-isobaric cooling P–T history (M2). M1 caused pervasive biotite-dehydration melting, producing garnet–orthopyroxene and garnet–rutile and sapphirine–spinel-bearing incongruent solid assemblages in felsic and aluminous granulites, respectively. During M2, garnet–corundum and later spinel–sillimanite–biotite assemblages were produced by reacting sapphirine–spinel–sillimanite and rehydration of garnet–corundum assemblages, respectively. Applying Electron Microprobe (EMP) dating techniques to monazites included in M1 garnet or occurring in low-strain domains in the felsic granulites, the UHT metamorphism is dated at 2040–2090 Ma. Based on the deep crustal heating–cooling P–T trajectory, the authors infer an overall counterclockwise P–T path for this UHT event. During the second granulite event, the Palaeoproterozoic granulites experienced crustal attenuation to ∼6•4 kbar at T ∼675°C during M3 and subsequent near-isothermal loading to ∼8 kbar during M4. In the felsic granulites, the former is marked by decomposition of M1 garnet to orthopyroxene–plagioclase symplectites. During M4, there was renewed growth of garnet–quartz symplectites in the felsic granulites, replacing the M3 mineral assemblage and also the appearance of coronal garnet–quartz–clinopyroxene assemblages in metamorphosed mafic dykes. Using monazites from metamorphic overgrowths and metamorphic recrystallization domains from the felsic granulite, the M4 metamorphism is dated at 1525–1450 Ma. Using geochronological and metamorphic constraints, the authors interpret the M3–M4 stages to be part of the same Mesoproterozoic tectonothermal event. The result provides the first documentation of UHT metamorphism and Palaeo- and Mesoproterozoic metamorphic processes in the CITZ. On a broader scale, the findings are also consistent with the current prediction that isobarically cooled granulites require a separate orogeny for their exhumation.

Plastic Deformation and Recrystallization of Garnet: A Mechanism to Facilitate Diffusion Creep

Abstract: Elongate and deformed garnets from Glenelg, NW Scotland, occur within a thin shear zone transecting an eclogite body that has undergone partial retrogression to amphibolite facies at circa 700°C. Optical microscopy, back-scattered electron imaging, electron probe microanalysis and electron back-scatter diffraction reveal garnet sub-structures that are developed as a function of strain. Subgrains with low-angle misorientation boundaries occur at low strain and garnet orientations are dispersed, around rational crystallographic axes, across these boundaries. Towards high-strain areas, boundary misorientations increase and there is a loss of crystallographic control on misorientations, which tend towards random. In high-strain areas, a polygonal garnet microstructure is developed. The garnet orientations are randomly dispersed around the original single-crystal orientation. Some garnet grains are elongate and Ca-rich garnet occurs on the faces of elongate grains oriented normal to the foliation. Commonly, the garnet grains are admixed with matrix minerals, and, where in contact with other phases, garnet is well faceted. We suggest that individual garnet porphyroclasts record an evolution from low-strain conditions, where dislocation creep and recovery accommodated deformation, through increasing strain, where dynamic recrystallization occurred by subgrain rotation, to highest strains, where recrystallized grains were able to deform by diffusion creep assisted grain boundary sliding with associated rotations.

Microchemical and Sr Isotopic Investigation of Zoned K-feldspar Megacrysts: Insights into the Petrogenesis of a Granitic System and Disequilibrium Crystal Growth

Abstract: K-feldspar megacrysts (Kfm) are used to investigate the magmatic evolution of the 7Ma Monte Capanne (MC) monzogranite (Elba, Italy). Dissolution and regrowth of Kfm during magma mixing or mingling events produce indented resorption surfaces associated with high Ba contents. Diffusion calculations demonstrate that Kfm chemical zoning is primary. Core-to-rim variations in Ba, Rb, Sr, Li and P support magma mixing (i.e. high Ba and P and low Rb/ Sr at rims), but more complex variations require other mechanisms. In particular, we show that disequilibrium growth (related to variations in diffusion rates in the melt) may have occurred as a result of thermal disturbance following influx of mafic magma in the magma chamber. Initial 87 Sr/ 86 Sr ratios (ISr) (obtained by microdrilling) decrease from core to rim. Inner core analyses define a mixing trend extending towards a high ISr–Rb/Sr melt component, whereas the outer cores and rims display a more restricted range of ISr, but a larger range of Rb/Sr. Lower ISr at the rim of one megacryst suggests mixing with high-K calc-alkaline mantle-derived volcanics of similar age on Capraia. Trace element and isotopic profiles suggest (1) early megacryst growth in magmas contaminated by crust and refreshed by high ISr silicic melts (as seen in the inner cores) and (2) later recharge with mafic magmas (as seen in the outer cores) followed by (3) crystal fractionation, with possible interaction with hydrothermal fluids (as seen in the rim). The model is compatible with the field occurrence of mafic enclaves and xenoliths.

Intra-Grain Sr Isotope Evidence for Crystal Recycling and Multiple Magma Reservoirs in the Recent Activity of Stromboli Volcano, Southern Italy

Abstract: Over the last several hundred years, Stromboli has been characterized by steady-state Strombolian activity. The volcanic products are dominated by degassed and highly porphyritic (HP-magma) black scoria bombs, lapilli and lava flows of basaltic shoshonitic composition. Periodically (about one to three events per year), more energetic explosive eruptions also eject light coloured volatile-rich pumices with low phenocryst content (LP-magma) that have more mafic compositions than the HP-magma. An in situ major and trace element and Sr isotope microanalysis study is presented on four samples chosen to characterize the different modes of activity at Stromboli: a lava flow (1985-1986 effusive event), a scoria bomb from the 'normal' present-day activity of Stromboli (April 1984), and a scoria and coeval pumice sample from a recent more explosive eruption (September 1996). Plagioclase (An

Exhumation Paths of High-Pressure-Low- Temperature Metamorphic Rocks from the Lycian Nappes and the Menderes Massif (SW Turkey): a Multi-Equilibrium Approach

Abstract: The Menderes Massif and the overlying Lycian Nappes occupy an extensive area of SW Turkey where high-pressure–low-temperature metamorphic rocks occur. Precise retrograde P–T paths reflecting the tectonic mechanisms responsible for the exhumation of these highpressure–low-temperature rocks can be constrained with multiequilibrium P–Testimatesrelyingonlocalequilibria.Whereasasimple isothermal decompression is documented for the exhumation of highpressure parageneses from the southern Menderes Massif, various P–T paths are observed in the overlying Karaova Formation of the Lycian Nappes. In the uppermost levels of this unit, far from the contact with the Menderes Massif, all P–T estimates depict cooling decompression paths. These high-pressure cooling paths are asso