Journal•ISSN: 0577-6171
Journal of The Chemical Society D: Chemical Communications
Royal Society of Chemistry
About: Journal of The Chemical Society D: Chemical Communications is an academic journal. The journal publishes majorly in the area(s): Crystal structure & Ring (chemistry). Over the lifetime, 4192 publications have been published receiving 39130 citations.
Topics: Crystal structure, Ring (chemistry), Yield (chemistry), Catalysis, Ion
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TL;DR: The skeletal structures of carboranes, the higher boranes and borane anions, and many transition-metal carbonyl cluster species are related to the number of skeletal bonding electron-pairs they contain this article.
Abstract: The skeletal structures of carboranes, the higher boranes and borane anions, and many transition-metal carbonyl cluster species are related to the number of skeletal bonding electron-pairs they contain; species with n skeletal atoms adopt closo-structures if held together by (n+ 1) pairs, nido-structures if held together by (n+ 2) pairs, and arachno-structures if held together by (n+ 3) pairs of skeletal bonding electrons.
701 citations
TL;DR: Treatment of bis-1,3-dithiole with 1 equiv. of chlorine affords a very stable radical cation which is amenable to full chemical and spectroscopic characterization as mentioned in this paper.
Abstract: Treatment of bis-1,3-dithiole with 1 equiv. of chlorine affords a very stable radical cation which is amenable to full chemical and spectroscopic characterization.
306 citations
TL;DR: A new optically active diphosphine-rhodium(I) catalytic system has been used in several asymmetric reductions giving optical yields of up to 72% as mentioned in this paper.
Abstract: A new optically active diphosphine–rhodium(I) catalytic system has been used in several asymmetric reductions giving optical yields of up to 72%.
283 citations
TL;DR: In this article, the authors summarized the qualitative predictions of the radical pair mechanism of CIDNP and summarized them in two simple rules, i.e., they were summarized as follows:
Abstract: Qualitative predictions of the radical pair mechanism of CIDNP are summarized in two simple rules.
244 citations
TL;DR: N-Protected amino-acid active esters react readily with polystyrenesulphonamide yielding, after deprotection, the poly(aminoacylsULphonamides): these polymers are suitable for solid phase peptide synthesis, the completed peptide being cleaved from the resin by methylation and hydrolysis or aminolysis.
Abstract: N-Protected amino-acid active esters react readily with polystyrenesulphonamide yielding, after deprotection, the poly(aminoacylsulphonamides): these polymers are suitable for solid phase peptide synthesis, the completed peptide being cleaved from the resin by methylation and hydrolysis or aminolysis.
218 citations