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JournalISSN: 0743-7463

Langmuir 

About: Langmuir is an academic journal. The journal publishes majorly in the area(s): Adsorption & Monolayer. It has an ISSN identifier of 0743-7463. Over the lifetime, 48263 publication(s) have been published receiving 2179623 citation(s).


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Journal ArticleDOI
07 Feb 1996-Langmuir
Abstract: The use of optical measurements to monitor electrochemical changes on the surface of nanosized metal particles is discussed within the Drude model. The absorption spectrum of a metal sol in water is shown to be strongly affected by cathodic or anodic polarization, chemisorption, metal adatom deposition, and alloying. Anion adsorption leads to strong damping of the free electron absorption. Cathodic polarization leads to anion desorption. Underpotential deposition (upd) of electropositive metal layers results in dramatic blue-shifts of the surface plasmon band of the substrate. The deposition of just 0.1 monolayer can be readily detected by eye. In some cases alloying occurs spontaneously during upd. Alloy formation can be ascertained from the optical absorption spectrum in the case of gold deposition onto silver sols. The underpotential deposition of silver adatoms onto palladium leads to the formation of a homogeneous silver shell, but the mean free path is less than predicted, due to lattice strain in t...

3,285 citations

Journal ArticleDOI
29 Aug 2008-Langmuir
TL;DR: In all of these solvents, full exfoliation of the graphite oxide material into individual, single-layer graphene oxide sheets was achieved by sonication, and graphene oxide dispersions exhibited long-term stability and were made of sheets between a few hundred nanometers and a few micrometers large.
Abstract: The dispersion behavior of graphene oxide in different organic solvents has been investigated. As-prepared graphite oxide could be dispersed in N,N-dimethylformamide, N-methyl-2-pyrrolidone, tetrahydrofuran, and ethylene glycol. In all of these solvents, full exfoliation of the graphite oxide material into individual, single-layer graphene oxide sheets was achieved by sonication. The graphene oxide dispersions exhibited long-term stability and were made of sheets between a few hundred nanometers and a few micrometers large, similar to the case of graphene oxide dispersions in water. These results should facilitate the manipulation and processing of graphene-based materials for different applications.

2,275 citations

Journal ArticleDOI
23 May 1998-Langmuir
Abstract: Nanotubes composed of various materials such as carbon, boron nitride, and oxides have been studied recently. In this report, the discovery of a new route for the synthesis of a nanotube made of titanium oxide is presented. Needle-shaped TiO2 crystals (anatase phase) with a diameter of ≈8 nm and a length of ≈100 nm were obtained when sol−gel-derived fine TiO2-based powders were treated chemically (e.g., for 20 h at 110 °C) with a 5−10 M NaOH aqueous solution. It was found by observation using a transmission electron microscope that the needle-shaped products have a tube structure. The TiO2 nanotubes have a large specific surface area of ≈400 m2·g-1. TiO2 nanotubes obtained in the present work are anticipated to have great potential for use in the preparation of catalysts, adsorbants, and deodorants with high activities, because their specific surface area is greatly increased. If metallic-, inorganic-, or organic-based materials can be inserted into the TiO2 nanotubes, novel characteristics such as electr...

2,247 citations

Journal ArticleDOI
16 Jul 2009-Langmuir
TL;DR: The results clearly indicate that the metal-free g-C(3)N(4) has good performance in photodegradation of organic pollutant.
Abstract: The g-C3N4 photocatalyst was synthesized by directly heating the low-cost melamine. The methyl orange dye (MO) was selected as a photodegrading goal to evaluate the photocatalytic activity of as-prepared g-C3N4. The comparison experiments indicate that the photocatalytic activity of g-C3N4 can be largely improved by the Ag loading. The strong acid radical ion (SO42− or NO3−) can promote the degrading rate of MO for g-C3N4 photocatalysis system. The MO degradation over the g-C3N4 is mainly attributed to the photoreduction process induced by the photogenerated electrons. Our results clearly indicate that the metal-free g-C3N4 has good performance in photodegradation of organic pollutant.

1,990 citations

Journal ArticleDOI
04 Sep 1996-Langmuir
Abstract: Gold colloids have been homogeneously coated with silica using the silane coupling agent (3-aminopropyl)trimethoxysilane as a primer to render the gold surface vitreophilic. After the formation of a thin silica layer in aqueous solution, the particles can be transferred into ethanol for further growth using the Stober method. The thickness of the silica layer can be completely controlled, and (after surface modification) the particles can be transferred into practically any solvent. Varying the silica shell thickness and the refractive index of the solvent allows control over the optical properties of the dispersions. The optical spectra of the coated particles are in good agreement with calculations using Mie's theory for core−shell particles.

1,746 citations

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Performance
Metrics
No. of papers from the Journal in previous years
YearPapers
20211,446
20201,624
20191,819
20181,708
20171,634
20161,542