Showing papers in "Nature Photonics in 2021"

Photonics for artificial intelligence and neuromorphic computing

Abstract: Research in photonic computing has flourished due to the proliferation of optoelectronic components on photonic integration platforms. Photonic integrated circuits have enabled ultrafast artificial neural networks, providing a framework for a new class of information processing machines. Algorithms running on such hardware have the potential to address the growing demand for machine learning and artificial intelligence in areas such as medical diagnosis, telecommunications, and high-performance and scientific computing. In parallel, the development of neuromorphic electronics has highlighted challenges in that domain, particularly related to processor latency. Neuromorphic photonics offers sub-nanosecond latencies, providing a complementary opportunity to extend the domain of artificial intelligence. Here, we review recent advances in integrated photonic neuromorphic systems, discuss current and future challenges, and outline the advances in science and technology needed to meet those challenges. Photonics offers an attractive platform for implementing neuromorphic computing due to its low latency, multiplexing capabilities and integrated on-chip technology.

Comprehensive defect suppression in perovskite nanocrystals for high-efficiency light-emitting diodes

Abstract: Electroluminescence efficiencies of metal halide perovskite nanocrystals (PNCs) are limited by a lack of material strategies that can both suppress the formation of defects and enhance the charge carrier confinement. Here we report a one-dopant alloying strategy that generates smaller, monodisperse colloidal particles (confining electrons and holes, and boosting radiative recombination) with fewer surface defects (reducing non-radiative recombination). Doping of guanidinium into formamidinium lead bromide PNCs yields limited bulk solubility while creating an entropy-stabilized phase in the PNCs and leading to smaller PNCs with more carrier confinement. The extra guanidinium segregates to the surface and stabilizes the undercoordinated sites. Furthermore, a surface-stabilizing 1,3,5-tris(bromomethyl)-2,4,6-triethylbenzene was applied as a bromide vacancy healing agent. The result is highly efficient PNC-based light-emitting diodes that have current efficiency of 108 cd A−1 (external quantum efficiency of 23.4%), which rises to 205 cd A−1 (external quantum efficiency of 45.5%) with a hemispherical lens. Guanidinium doping is shown to enhance the operation of perovskite nanocrystal light-emitting diodes.

Deep learning for the design of photonic structures

Abstract: Innovative approaches and tools play an important role in shaping design, characterization and optimization for the field of photonics. As a subset of machine learning that learns multilevel abstraction of data using hierarchically structured layers, deep learning offers an efficient means to design photonic structures, spawning data-driven approaches complementary to conventional physics- and rule-based methods. Here, we review recent progress in deep-learning-based photonic design by providing the historical background, algorithm fundamentals and key applications, with the emphasis on various model architectures for specific photonic tasks. We also comment on the challenges and perspectives of this emerging research direction. The application of deep learning to the design of photonic structures and devices is reviewed, including algorithm fundamentals.

Stable pure-blue hyperfluorescence organic light-emitting diodes with high-efficiency and narrow emission

Abstract: Organic light-emitting diodes (OLEDs) are a promising light-source technology for future generations of display1,2. Despite great progress3–12, it is still challenging to produce blue OLEDs with sufficient colour purity, lifetime and efficiency for applications. Here, we report pure-blue (Commission Internationale de l’ Eclairage (CIE) coordinates of 0.13, 0.16) OLEDs with high efficiency (external quantum efficiency of 32 per cent at 1,000 cd m−2), narrow emission (full-width at half-maximum of 19 nm) and good stability (95% of the initial luminacnce (LT95) of 18 hours at an initial luminance of 1,000 cd m−2). The design is based on a two-unit stacked tandem hyperfluorescence OLED with improved singlet-excited-state energy transfer from a sky-blue assistant dopant exhibiting thermally activated delayed fluorescence (TADF) called hetero-donor-type TADF(HDT-1) to a pure-blue emitter. With stricter control of device fabrication and procedures it is expected that device lifetimes will further improve to rival commercial fluorescent blue OLEDs. Pure-blue organic LEDs with narrow emission and improved stability show promise for display applications.

High-efficiency, long-lifetime deep-blue organic light-emitting diodes

Abstract: Simultaneously achieving both a high efficiency and long lifetime in deep-blue organic light-emitting diodes is challenging. Here we report thermally activated delayed fluorescence (TADF) organic light-emitting diodes that aim to meet this goal by combining a new design of blue TADF materials with a triplet-exciton recycling protocol. Two TADF materials, one distributing and one emitting, were doped into a host to form triplet-exciton-distributed TADF devices. The singlet excitons were transferred from the host to the emitter via the distributing TADF material by cascade energy transfer, whereas the triplet excitons were transferred to the emitter as singlet excitons by a triplet-exciton recycling process between the low-triplet-energy host and the distributing TADF material. The resulting triplet-exciton-distributed TADF devices achieved a high external quantum efficiency of 33.5 ± 0.1, a colour coordinate corrected current efficiency over 400 cd A–1, a lifetime of >5,000 h and a y colour coordinate below 0.10. Exciton energy cascade transfer and recycling bring improvements in the efficiency and lifetime of deep-blue organic light-emitting diodes.

Large-scale neuromorphic optoelectronic computing with a reconfigurable diffractive processing unit

Abstract: There is an ever-growing demand for artificial intelligence. Optical processors, which compute with photons instead of electrons, can fundamentally accelerate the development of artificial intelligence by offering substantially improved computing performance. There has been long-term interest in optically constructing the most widely used artificial-intelligence architecture, that is, artificial neural networks, to achieve brain-inspired information processing at the speed of light. However, owing to restrictions in design flexibility and the accumulation of system errors, existing processor architectures are not reconfigurable and have limited model complexity and experimental performance. Here, we propose the reconfigurable diffractive processing unit, an optoelectronic fused computing architecture based on the diffraction of light, which can support different neural networks and achieve a high model complexity with millions of neurons. Along with the developed adaptive training approach to circumvent system errors, we achieved excellent experimental accuracies for high-speed image and video recognition over benchmark datasets and a computing performance superior to that of cutting-edge electronic computing platforms. Linear diffractive structures are by themselves passive systems but researchers here exploit the non-linearity of a photodetector to realize a reconfigurable diffractive ‘processing’ unit. High-speed image and video recognition is demonstrated.

Hertz-linewidth semiconductor lasers using CMOS-ready ultra-high-Q microresonators

Abstract: Driven by narrow-linewidth bench-top lasers, coherent optical systems spanning optical communications, metrology and sensing provide unrivalled performance To transfer these capabilities from the laboratory to the real world, a key missing ingredient is a mass-produced integrated laser with superior coherence Here, we bridge conventional semiconductor lasers and coherent optical systems using CMOS-foundry-fabricated microresonators with a high Q factor of over 260 million and finesse over 42,000 A five-orders-of-magnitude noise reduction in the pump laser is demonstrated, enabling a frequency noise of 02 Hz2 Hz−1 to be achieved in an electrically pumped integrated laser, with a corresponding short-term linewidth of 12 Hz Moreover, the same configuration is shown to relieve the dispersion requirements for microcomb generation that have handicapped certain nonlinear platforms The simultaneous realization of this high Q factor, highly coherent lasers and frequency combs using foundry-based technologies paves the way for volume manufacturing of a wide range of coherent optical systems Using CMOS-ready ultra-high-Q microresonators, a highly coherent electrically pumped integrated laser with frequency noise of 02 Hz2 Hz−1, corresponding to a short-term linewidth of 12 Hz, is demonstrated The device configuration is also found to relieve the dispersion requirements for microcomb generation that have limited certain nonlinear platforms

High-power portable terahertz laser systems

Abstract: Terahertz (THz) frequencies remain among the least utilized in the electromagnetic spectrum, largely due to the lack of powerful and compact sources. The invention of THz quantum cascade lasers (QCLs) was a major breakthrough to bridge the so-called ‘THz gap’ between semiconductor electronic and photonic sources. However, their demanding cooling requirement has confined the technology to a laboratory environment. A portable and high-power THz laser system will have a qualitative impact on applications in medical imaging, communications, quality control, security and biochemistry. Here, by adopting a design strategy that achieves a clean three-level system, we have developed THz QCLs (at ~4 THz) with a maximum operating temperature of 250 K. The high operating temperature enables portable THz systems to perform real-time imaging with a room-temperature THz camera, as well as fast spectral measurements with a room-temperature detector. GaAs-based terahertz quantum cascade lasers emitting around 4 THz are demonstrated up to 250 K without a magnetic field. To elevate the operation temperature, carrier leakage channels are reduced by carefully designing the quantum well structures.

Suppression of temperature quenching in perovskite nanocrystals for efficient and thermally stable light-emitting diodes

Abstract: The thermal quenching of light emission is a critical bottleneck that hampers the real-world application of lead halide perovskite nanocrystals in both electroluminescent and down-conversion light-emitting diodes. Here, we report CsPbBr3 perovskite nanocrystals with a temperature-independent emission efficiency of near unity and constant decay kinetics up to a temperature of 373 K. This unprecedented regime is obtained by a fluoride post-synthesis treatment that produces fluorine-rich surfaces with a wider energy gap than the inner nanocrystal core, yielding suppressed carrier trapping, improved thermal stability and efficient charge injection. Light-emitting diodes incorporating these fluoride-treated perovskite nanocrystals show a low turn-on voltage and spectrally pure green electroluminescence with an external quantum efficiency as high as 19.3% at 350 cd m−2. Importantly, nearly 80% of the room-temperature external quantum efficiency is preserved at 343 K, in contrast to the dramatic drop commonly observed for standard CsPbBr3 perovskite nanocrystal light-emitting diodes. These results provide a promising pathway for high-performance, practical light-emitting diodes based on perovskite nanostructures. Fluoride-treated CsPbBr3 nanocrystals emit light with near unity efficiency at temperatures of up to 373 K.

Machine learning and applications in ultrafast photonics

Abstract: Recent years have seen the rapid growth and development of the field of smart photonics, where machine-learning algorithms are being matched to optical systems to add new functionalities and to enhance performance. An area where machine learning shows particular potential to accelerate technology is the field of ultrafast photonics — the generation and characterization of light pulses, the study of light–matter interactions on short timescales, and high-speed optical measurements. Our aim here is to highlight a number of specific areas where the promise of machine learning in ultrafast photonics has already been realized, including the design and operation of pulsed lasers, and the characterization and control of ultrafast propagation dynamics. We also consider challenges and future areas of research. The potential of machine-learning application to the field of ultrafast photonics is reviewed, with key examples including pulsed lasers, and control and characterization of ultrafast propagation dynamics.

Stable and low-photovoltage-loss perovskite solar cells by multifunctional passivation

Abstract: Metal halide perovskite solar cells have demonstrated a high power conversion efficiency (PCE), and further enhancement of the PCE requires a reduction of the bandgap-voltage offset (WOC) and the non-radiative recombination photovoltage loss (ΔVOC,nr). Here, we report an effective approach for reducing the photovoltage loss through the simultaneous passivation of internal bulk defects and dimensionally graded two-dimensional perovskite interface defects. Through this dimensionally graded perovskite formation approach, an open-circuit voltage (VOC) of 1.24 V was obtained with a champion PCE of 21.54% in a 1.63 eV perovskite system (maximum VOC = 1.25 V, WOC = 0.38 V and ΔVOC,nr = 0.10 V); we further decreased the WOC to 0.326 V in a 1.53 eV perovskite system with a VOC of 1.21 V and a PCE of 23.78% (certified 23.09%). This approach is equally effective in achieving a low WOC (ΔVOC,nr) in 1.56 eV and 1.73 eV perovskite solar cell systems, and further leads to the substantially improved operational stability of perovskite solar cells. The use of a dimensionally graded 2D perovskite interface and passivation results in perovskite solar cells with very low photovoltage loss.

Organic phosphors with bright triplet excitons for efficient X-ray-excited luminescence

Abstract: Materials that exhibit X-ray-excited luminescence have great potential in radiation detection, security inspection, biomedical applications and X-ray astronomy1–5. However, high-performance materials are almost exclusively limited to ceramic scintillators, which are typically prepared under high temperatures6. Herein we report metal-free organic phosphors based on a molecular design that supports efficient triplet exciton harvesting to enhance radioluminescence. These organic scintillators exhibit a detection limit of 33 nGy s–1, which is 167 times lower than the standard dosage for X-ray medical examination and we demonstrate their potential application in X-ray radiography. These findings provide a fundamental design principle and new route for the creation of promising alternatives to incumbent inorganic scintillators. Furthermore, they offer new opportunities for development of flexible, stretchable X-ray detectors and imagers for non-destructive radiography testing and medical imaging. Organic, metal-free materials that act as efficient X-ray scintillators could bring new opportunities for X-ray imaging.

Metasurface optics for on-demand polarization transformations along the optical path

Abstract: Polarization plays a key role in science; hence its versatile manipulation is crucial. Existing polarization optics, however, can only manipulate polarization in a single transverse plane. Here we demonstrate a new class of polarizers and wave plates—based on metasurfaces—that can impart an arbitrarily chosen polarization response along the propagation direction, regardless of the incident polarization. The underlying mechanism relies on transforming an incident waveform into an ensemble of pencil-like beams with different polarization states that beat along the optical axis thereby changing the resulting polarization at will, locally, as light propagates. Remarkably, using form-birefringent metasurfaces in combination with matrix-based holography enables the desired propagation-dependent polarization response to be enacted without a priori knowledge of the incident polarization—a behaviour that would require three polarization-sensitive holograms if implemented otherwise. Our work expands the use of polarization in the design of multifunctional metasurfaces and may find application in tunable structured light, optically switchable devices and versatile light–matter interactions. Using a metasurface that allows shaping of the polarization state of a light beam independently at each point of space along its propagation direction, longitudinally variable polarization optical components are demonstrated, inspiring new directions in structured light, polarization-switchable devices and light–matter interaction.

CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays

Abstract: Halide perovskite semiconductors are poised to revitalize the field of ionizing radiation detection as they have done to solar photovoltaics. We show that all-inorganic perovskite CsPbBr3 devices resolve 137Cs 662-keV γ-rays with 1.4% energy resolution, as well as other X- and γ-rays with energies ranging from tens of keV to over 1 MeV in ambipolar sensing and unipolar hole-only sensing modes with crystal volumes of 6.65 mm3 and 297 mm3, respectively. We report the scale-up of CsPbBr3 ingots to up to 1.5 inches in diameter with an excellent hole mobility–lifetime product of 8 × 10−3 cm2 V−1 and a long hole lifetime of up to 296 μs. CsPbBr3 detectors demonstrate a wide temperature region from ~2 °C to ~70 °C for stable operation. Detectors protected with suitable encapsulants show a uniform response for over 18 months. Consequently, we identify perovskite CsPbBr3 semiconductor as an exceptional candidate for new-generation high-energy γ-ray detection. Energy resolution of high-energy photon detectors is desired for applications ranging from biomedical imaging to homeland security. In this work, perovskite-based γ-ray detection with 1.4% energy resolution is demonstrated.

Metasurfaces for quantum photonics

Abstract: Rapid progress in the development of metamaterials and metaphotonics allowed bulky optical assemblies to be replaced with thin nanostructured films, often called metasurfaces, opening a broad range of novel and superior applications of flat optics to the generation, manipulation and detection of classical light. Recently, these developments started making headway in quantum photonics, where novel opportunities arose for the control of non-classical nature of light, including photon statistics, quantum state superposition, quantum entanglement and single-photon detection. In this Perspective, we review recent progress in the emerging field of quantum-photonics applications of metasurfaces, focusing on innovative and promising approaches to create, manipulate and detect non-classical light. Progress in the field of quantum-photonics applications of metasurfaces is reviewed. Cutting-edge research, including the development of optical chips supporting high-dimensional quantum entanglement and advanced quantum tomography, is summarized.

600-km repeater-like quantum communications with dual-band stabilization

Abstract: Twin-field (TF) quantum key distribution (QKD) fundamentally alters the rate-distance relationship of QKD, offering the scaling of a single-node quantum repeater. Although recent experiments have demonstrated the new opportunities for secure long-distance communications allowed by TF-QKD, formidable challenges remain to unlock its true potential. Previous demonstrations have required intense stabilization signals at the same wavelength as the quantum signals, thereby unavoidably generating Rayleigh scattering noise that limits the distance and bit rate. Here, we introduce a dual-band stabilization scheme that overcomes past limitations and can be adapted to other phase-sensitive single-photon applications. Using two different optical wavelengths multiplexed together for channel stabilization and protocol encoding, we develop a setup that provides repeater-like key rates over communication distances of 555 km and 605 km in the finite-size and asymptotic regimes respectively and increases the secure key rate at long distance by two orders of magnitude to values of practical relevance. Twin-field quantum key distribution over 600 km is demonstrated. The key ingredient for success is the dual-band phase stabilization that dramatically reduce the phase fluctuations on optical fibre by more than four orders of magnitude.

Prospects for metal halide perovskite-based tandem solar cells

Abstract: Over the past decade, metal halide perovskite photovoltaics have been a major focus of research, with single-junction perovskite solar cells evolving from an initial power conversion efficiency of 3.8% to reach 25.5%. The broad bandgap tunability of perovskites makes them versatile candidates as the subcell in a tandem photovoltaics architecture. Stacking photovoltaic absorbers with cascaded bandgaps in a multi-junction device can potentially overcome the Shockley–Queisser efficiency limit of 33.7% for single-junction solar cells. There is now intense activity in developing tandem solar cells that pair perovskite with either itself or with a variety of mature photovoltaic technologies such as silicon and Cu(In,Ga)(S,Se)2 (CIGS). In this review, we survey recent advances in the field and discuss its outlook. A discussion of the evolution, present status and future outlook for tandem solar cells employing perovskite materials.

Sensitive, small, broadband and scalable optomechanical ultrasound sensor in silicon photonics

Abstract: Ultrasonography1 and photoacoustic2,3 (optoacoustic) tomography have recently seen great advances in hardware and algorithms. However, current high-end systems still use a matrix of piezoelectric sensor elements, and new applications require sensors with high sensitivity, broadband detection, small size and scalability to a fine-pitch matrix. This work demonstrates an ultrasound sensor in silicon photonic technology with extreme sensitivity owing to an innovative optomechanical waveguide. This waveguide has a tiny 15 nm air gap between two movable parts, which we fabricated using new CMOS-compatible processing. The 20 μm small sensor has a noise equivalent pressure below 1.3 mPa Hz−1/2 in the measured range of 3–30 MHz, dominated by acoustomechanical noise. This is two orders of magnitude better than for piezoelectric elements of an identical size4. The demonstrated sensor matrix with on-chip photonic multiplexing5–7 offers the prospect of miniaturized catheters that have sensor matrices interrogated using just a few optical fibres, unlike piezoelectric sensors that typically use an electrical connection for each element. An optical ultrasound sensor based on a CMOS-compatible split-rib waveguide is demonstrated, offering high sensitivity, broadband detection (measured 3–30 MHz), small size (20 μm) and scalability to a fine-pitch matrix.

Twin-field quantum key distribution over a 511 km optical fibre linking two distant metropolitan areas

Abstract: The basic principle of quantum mechanics1 guarantees the unconditional security of quantum key distribution (QKD)2–6 at the cost of forbidding the amplification of a quantum state. As a result, and despite remarkable progress in worldwide metropolitan QKD networks7,8 over the past decades, a long-haul fibre QKD network without a trusted relay has not yet been achieved. Here, through the sending-or-not-sending protocol9, we achieve twin-field QKD10 and distribute secure keys without any trusted repeater over a 511 km long-haul fibre trunk that links two distant metropolitan areas. The fibre trunk contains 12 fibres in the cable, three of which are used for the quantum channel, optical synchronization and frequency locking, respectively. The remaining nine are used for classical fibre communication. Our secure key rate is around three orders of magnitude greater than that expected if the previous QKD field-test system was applied over the same length. Efficient quantum-state transmission and stable single-photon interference over such a long-haul deployed fibre pave the way to large-scale fibre quantum networks. A field test of twin-field quantum key distribution was implemented through a 511 km optical fibre. To this end, precise wavelength control of remote independent laser sources and fast time- and phase-compensation systems are developed.

Ultra-fast germanium photodiode with 3-dB bandwidth of 265 GHz

Abstract: On a scalable silicon technology platform, we demonstrate photodetectors matching or even surpassing state-of-the-art III–V devices. As key components in high-speed optoelectronics, photodetectors with bandwidths greater than 100 GHz have been a topic of intense research for several decades. Solely InP-based detectors could satisfy the highest performance specifications. Devices based on other materials, such as germanium-on-silicon devices, used to lag behind in speed, but enabled complex photonic integrated circuits and co-integration with silicon electronics. Here we demonstrate waveguide-coupled germanium photodiodes with optoelectrical 3-dB bandwidths of 265 GHz and 240 GHz at a photocurrent of 1 mA. This outstanding performance is achieved by a novel device concept in which a germanium fin is sandwiched between complementary in situ-doped silicon layers. Our photodetectors show internal responsivities of 0.3 A W−1 (265 GHz) and 0.45 A W−1 (240 GHz) at a wavelength of 1,550 nm. The internal bandwidth–efficiency product of the latter device is 86 GHz. Low dark currents of 100–200 nA are obtained from these ultra-fast photodetectors. By sandwiching a germanium fin between complementary in situ-doped silicon layers, a waveguide-coupled germanium photodiode with a 3-dB bandwidth of 265 GHz, accompanied by high responsivity and low dark current, is realized.

Electrically driven acousto-optics and broadband non-reciprocity in silicon photonics

Abstract: Emerging technologies based on tailorable photon–phonon interactions promise new capabilities ranging from high-fidelity information processing to non-reciprocal optics and quantum state control. However, many existing realizations of such light–sound couplings involve unconventional materials and fabrication schemes challenging to co-implement with scalable integrated photonic circuitry. Here, we demonstrate direct acousto-optic modulation within silicon waveguides using electrically driven surface acoustic waves (SAWs). By co-integrating electromechanical SAW transducers with a standard silicon-on-insulator photonic platform, we harness silicon’s strong elasto-optic effect to create travelling-wave phase and single-sideband amplitude modulators from 1 to 5 GHz, with index modulation strengths comparable to electro-optic technologies. Extending this non-local interaction to centimetre scales, we demonstrate non-reciprocal modulation with operation bandwidths of >100 GHz and insertion losses of 100 GHz and insertion losses of <0.6 dB are obtained.

Directly modulated membrane lasers with 108 GHz bandwidth on a high-thermal-conductivity silicon carbide substrate

Abstract: Increasing the modulation speed of semiconductor lasers has attracted much attention from the viewpoint of both physics and the applications of lasers. Here we propose a membrane distributed reflector laser on a low-refractive-index and high-thermal-conductivity silicon carbide substrate that overcomes the modulation bandwidth limit. The laser features a high modulation efficiency because of its large optical confinement in the active region and small differential gain reduction at a high injection current density. We achieve a 42 GHz relaxation oscillation frequency by using a laser with a 50-μm-long active region. The cavity, designed to have a short photon lifetime, suppresses the damping effect while keeping the threshold carrier density low, resulting in a 60 GHz intrinsic 3 dB bandwidth (f3dB). By employing the photon–photon resonance at 95 GHz due to optical feedback from an integrated output waveguide, we achieve an f3dB of 108 GHz and demonstrate 256 Gbit s−1 four-level pulse-amplitude modulations with a 475 fJ bit−1 energy cost of the direct-current electrical input. Directly modulated membrane distributed reflector lasers are fabricated on a silicon carbide platform. The 3 dB bandwidth, four-level pulse-amplitude modulation speed and operating energy for transmitting one bit are 108 GHz, 256 Gbit s−1 and 475 fJ, respectively.

A wavelength-scale black phosphorus spectrometer

Abstract: On-chip spectrometers with compact footprints are being extensively investigated owing to their promising future in critical applications such as sensing, surveillance and spectral imaging. Most existing miniaturized spectrometers use large arrays of photodetection elements to capture different spectral components of incident light, from which its spectrum is reconstructed. Here, we demonstrate a mid-infrared spectrometer in the 2–9 µm spectral range, utilizing a single tunable black phosphorus photodetector with an active area footprint of only 9 × 16 µm2, along with a unique spectral learning procedure. Such a single-detector spectrometer has a compact size at the scale of the operational wavelength. Leveraging the wavelength and bias-dependent responsivity matrix learned from the spectra of a tunable blackbody source, we reconstruct unknown spectra from their corresponding photoresponse vectors. Enabled by the strong Stark effect and the tunable light–matter interactions in black phosphorus, our single-detector spectrometer shows remarkable potential in the reconstruction of the spectra of both monochromatic and broadband light. Furthermore, its ultracompact structure that is free from bulky interferometers and gratings, together with its electrically reconfigurable nature, may open up pathways towards on-chip mid-infrared spectroscopy and spectral imaging. A single-photodetector spectrometer based on black phosphorus is demonstrated in the wavelength range from 2 to 9 μm. The footprint is 9 × 16 μm2. The spectrometer is free from bulky interferometers and gratings, and is electrically reconfigurable.

Pockels soliton microcomb

Abstract: Kerr soliton microcombs have recently emerged as a prominent topic in integrated photonics and have enabled new horizons for optical frequency metrology. Kerr soliton microcombs, as the name suggests, are based on high-order cubic optical nonlinearity. It is desirable to exploit quadratic photonic materials, namely Pockels materials, for soliton generation and on-chip implementation of 1f–2f comb self-referencing. Such quadratically driven solitons have been proposed theoretically, but have not yet been observed in a nanophotonic platform, despite recent progress in quadratic comb generation in free-space and crystalline resonators. Here, we report photonic-chip-based Pockels microcomb solitons driven by three-wave mixing in an aluminium nitride microring resonator. In contrast to typical Kerr solitons, the Pockels soliton features unity soliton generation fidelity, two-by-two evolution of multi-soliton states, favourable tuning dynamics and high pump-to-soliton conversion efficiency. Photonic-chip-based microcomb solitons driven by Pockels nonlinearity—the quadratic χ(2) effect—instead of the Kerr soliton are demonstrated in an aluminium nitride microring resonator with a conversion efficiency of 17%.

Synthetic helical dichroism for six-dimensional optical orbital angular momentum multiplexing

Abstract: Optical multiplexing1–11 by creating orthogonal data channels has offered an unparalleled approach for information encoding with substantially improved density and security. Despite the fact that the orbital angular momentum (OAM) of light involves physical orthogonal division, the lack of explicit OAM sensitivity at the nanoscale prevents this feature from realizing nanophotonic information encoding. Here we demonstrate the viability of nanoscale information multiplexing utilizing the OAM of light. This is achieved by discovering OAM-dependent polarization ellipses in non-paraxial focusing conditions and hence synthetic helical dichroism resulting from the distinct absorption of achiral nanoparticles to the different order of OAM beams. Leveraging this mechanism, the application of subwavelength-scale focused OAM beams to self-assemble plasmonic nanoaggregates further enables six-dimensional optical information multiplexing, in conjunction with wavelength, polarization and three spatial dimensions. Our results suggest the possibility of multiplexing OAM division as an unbounded degree of freedom for nanophotonic information encoding, security imprinting and beyond. Multiplexing orbital angular momentum states as independent and orthogonal information carriers for data encryption is realized through disorder-induced synthetic helical dichroism in disordered nanoaggregates.

Advances in solution-processed near-infrared light-emitting diodes

Abstract: Near-infrared light-emitting diodes based on solution-processed semiconductors, such as organics, halide perovskites and colloidal quantum dots, have emerged as a viable technological platform for biomedical applications, night vision, surveillance and optical communications. The recently gained increased understanding of the relationship between materials structure and photophysical properties has enabled the design of efficient emitters leading to devices with external quantum efficiencies exceeding 20%. Despite considerable strides made, challenges remain in achieving high radiance, reducing efficiency roll-off and extending operating lifetime. This Review summarizes recent advances on emissive materials synthetic methods and device key attributes that collectively contribute to improved performance of the fabricated light-emitting devices. A summary of recent advances in the near-infrared light-emitting diodes that are fabricated by solution-processed means, with coverage of devices based on organic semiconductors, halide perovskites and colloidal quantum dots.

Nanoscale terahertz scanning probe microscopy

Abstract: Terahertz radiation has become an important diagnostic tool in the development of new technologies. However, the diffraction limit prevents terahertz radiation (λ ≈ 0.01–3 mm) from being focused to the nanometre length scale of modern devices. In response to this challenge, terahertz scanning probe microscopy techniques based on coupling terahertz radiation to subwavelength probes such as sharp tips have been developed. These probes enhance and confine the light, improving the spatial resolution of terahertz experiments by up to six orders of magnitude. In this Review, we survey terahertz scanning probe microscopy techniques that achieve spatial resolution on the scale of micrometres to angstroms, with particular emphasis on their overarching approaches and underlying probing mechanisms. Finally, we forecast the next steps in the field. Recent progress in terahertz scanning probe microscopy is reviewed with an emphasis on techniques that access length scales below 100 nm relevant to material science. An outlook on the future of nanoscale terahertz scanning probe microscopy is also provided.

Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks

Abstract: Perovskite nanocrystals are exceptional candidates for light-emitting diodes (LEDs). However, they are unstable in the solid film and tend to degrade back to the bulk phase, which undermines their potential for LEDs. Here we demonstrate that perovskite nanocrystals stabilized in metal–organic framework (MOF) thin films make bright and stable LEDs. The perovskite nanocrystals in MOF thin films can maintain the photoluminescence and electroluminescence against continuous ultraviolet irradiation, heat and electrical stress. As revealed by optical and X-ray spectroscopy, the strong emission originates from localized carrier recombination. Bright LEDs made from perovskite-MOF nanocrystals are demonstrated with a maximum external quantum efficiency of over 15% and a high brightness of over 105 cd m−2 after the device reaches stabilization. During LED operation, the nanocrystals can be well preserved, free of ion migration or crystal merging through protection by the MOF matrix, leading to a stable performance over 50 hours. The use of metal–organic frameworks helps protect perovskite nanocrystals, resulting in bright, stable light-emitting diodes.

Ultrastrong plasmon–phonon coupling via epsilon-near-zero nanocavities

Abstract: Vibrational ultrastrong coupling, where the light–matter coupling strength is comparable to the vibrational frequency of molecules, presents new opportunities to probe the interactions between molecules and zero-point fluctuations, harness cavity-modified chemical reactions and develop novel devices in the mid-infrared spectral range. Here we use epsilon-near-zero nanocavities filled with a model polar medium (SiO2) to demonstrate ultrastrong coupling between phonons and gap plasmons. We present classical and quantum-mechanical models to quantitatively describe the observed plasmon–phonon ultrastrong coupling phenomena and demonstrate a modal splitting of up to 50% of the resonant frequency (normalized coupling strength η > 0.25). Our wafer-scale nanocavity platform will enable a broad range of vibrational transitions to be harnessed for ultrastrong coupling applications. An epsilon-near-zero medium is used to demonstrate ultrastrong coupling between phonons and gap plasmons. The approach may pave the path to exploitation of vibrational transitions.

Composite fast scintillators based on high-Z fluorescent metal–organic framework nanocrystals

Abstract: Scintillators, materials that produce light pulses upon interaction with ionizing radiation, are widely employed in radiation detectors. In advanced medical-imaging technologies, fast scintillators enabling a time resolution of tens of picoseconds are required to achieve high-resolution imaging at the millimetre length scale. Here we demonstrate that composite materials based on fluorescent metal–organic framework (MOF) nanocrystals can work as fast scintillators. We present a prototype scintillator fabricated by embedding MOF nanocrystals in a polymer. The MOF comprises zirconium oxo-hydroxy clusters, high-Z linking nodes interacting with the ionizing radiation, arranged in an orderly fashion at a nanometric distance from 9,10-diphenylanthracene ligand emitters. Their incorporation in the framework enables fast sensitization of the ligand fluorescence, thus avoiding issues typically arising from the intimate mixing of complementary elements. This proof-of-concept prototype device shows an ultrafast scintillation rise time of ~50 ps, thus supporting the development of new scintillators based on engineered fluorescent MOF nanocrystals. Composites of fluorescent metal–organic framework nanocrystals in a polymer are exploited to create fast scintillators with a rise time of about 50 ps.