Showing papers in &quot;Organometallics in 1986&quot;

Synthesis of Monomeric Permethylyttrocene Derivatives. The Crystal Structures of Cp*2YN(SiMe3)2 and Cp*2YCH(SiMe3)2

TL;DR: In this paper, des calculs ab initio sur les complexes MR 2 (M=Pd ou Pt R=H ou CH 3 ) pour modeliser des copulatures reductives concertees a partir de complexes MR2 L 2 (ou L est une phosphine)

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210 citations

Journal Article•DOI•

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Klaas H. den Haan, Jan L. de Boer, Jan H. Teuben, Anthony L. Spek, B. Kojic-Prodic, Gary R. Hays, Rob Huis - Show less +3 more

01 Aug 1986-Organometallics

TL;DR: In this paper, the reaction of Cp*2YCl·THF (2) with NaN(SiMe3)2 and LiCH(SiME3) 2 yield the monomeric complexes Cp*,2YN(SiMo3)1 (3) and Cp *2YCH (SiMe 3)2 (4), respectively.

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181 citations

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Synthesis and X-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu

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William J. Evans, Laura A. Hughes, Timothy P. Hanusa

Insertion reactions of the 16-electron complexes MHCl(CO)[P(CHMe2)3]2 (M = Ru, Os) with alkynes. The x-ray crystal structure of [(E)-PhCH:CHOs(Cl)(CO)[P(CHMe2)3]2

171 citations

Journal Article•DOI•

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Helmut Werner, Miguel A. Esteruelas, H. Otto

Reactions of alkyl and hydride derivatives of permethylscandocene and zirconocene with nitriles and amines. Catalytic hydrogenation of tert-butyl cyanide with permethylscandocene hydride

TL;DR: In this article, the preparation of composes vinyliques is described in terms of the structure moleculaire et cristalline and the structure of the cristaline.

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165 citations

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John E. Bercaw, David L. Davies, Peter T. Wolczanski

01 Mar 1986-Organometallics

143 citations

Journal Article•DOI•

Synthesis, molecular structure, solution dynamics, and reactivity of (.eta.-C5H5)2M(.mu.-PR2)2Rh(.eta.-indenyl) (M = Zr, Hf; R = Et, Ph)

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R. T. Baker, T.H. Tulip

01 May 1986-Organometallics

125 citations

Journal Article•DOI•

Kinetics and mechanism of CO2 insertion into a metal-hydride bond. A large solvent effect and an inverse kinetic isotope effect

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B. Patrick Sullivan¹, Thomas J. Meyer•Institutions (1)

University of North Carolina at Chapel Hill¹

Polysilane−metal interactions. Photochemical deoligomerizations and base treatment migrations from iron to cyclopentadienyl ligands

TL;DR: In this paper, the insertion of CO 2 dans la liaison Re-H de fac-Re(chelate)(CO) 3 H (chelate=bipy-2,2' ou -4,4').

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125 citations

Journal Article•DOI•

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Keith H. Pannell¹, Jorge Cervantes, Carlos Hernandez², Jeff. Cassias², Steven. Vincenti² - Show less +1 more•Institutions (2)

University of Texas at El Paso¹, Universidad Autónoma Metropolitana²

01 Jan 1986-Organometallics

120 citations

Journal Article•DOI•

Isolation of intermediates in the water gas shift reactions catalyzed by [Ru(bpy)2(CO)Cl]+ and [Ru(bpy)2(CO)2]2+

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Hitoshi Ishida, Koji Tanaka, Masaru Morimoto, Toshio Tanaka

Interaction of palladium(0) complexes with allylic acetates, allyl ethers, allyl phenyl chalcogenides, allylic alcohols, and allylamines. Oxidative addition, condensation, disproportionation, and .pi.-complex formation

111 citations

Journal Article•DOI•

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Takakazu Yamamoto, Mitsuru Akimoto, Osamu Saito, Akio Yamamoto

01 Aug 1986-Organometallics

105 citations

Journal Article•DOI•

The chemistry of cyclopentadienyl-ruthenium and -osmium complexes. 1. The preparation and substitution reactions of (.eta.4-cycloocta-1,5-diene)(.eta.5-cyclopentadienyl)haloruthenium(II) complexes. Versatile new synthetic precursors to open-face cyclopentadienylruthenium(II) chemistry

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Michel O. Albers, David J. Robinson, Alan Shaver, Eric Singleton

Organolanthanide and organoyttrium enolate chemistry. Synthesis of [(C5H4R)2Ln(.mu.-OCH:CH2)]2 complexes and the molecular structure of [(CH3C5H4)2Y(.mu.-OCH:CH2)]2

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William J. Evans, Raul. Dominguez, Timothy P. Hanusa

Reactions of chelate ylides with nickel(0) complexes

Journal Article•DOI•

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Wilhelm Keim, Arno Behr, Bert Gruber, Bernd Hoffmann, Frank H. Kowaldt, Ulf. Kuerschner, Brigitte. Limbaecker, Frank P. Sistig - Show less +4 more

Synthesis, structure and reactivity of some (.sigma.-allenyl)- and (.sigma.-prop-2-ynyl)palladium(II) complexes

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Cornelis J. Elsevier, Henk Kleijn, Jaap Boersma, P. Vermeer

Organotin biocides. 4. Crystal and molecular structure of tricyclohexylstannyl 3-indolylacetate, incorporating the first monodentate carboxylate group bonded to a triorganotin(IV)

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Kieran C. Molloy, Thomas G. Purcell, Ekkehardt Hahn, Herbert Schumann, Jerold J. Zuckerman - Show less +1 more

01 Jan 1986-Organometallics

Journal Article•DOI•

Intermediates in the palladium-catalyzed reactions of 1,3-dienes. The reaction of (.eta.1,.eta.3-octadiendiyl)palladium complexes with acidic substrates

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Peter W. Jolly, Richard Mynott, B. Raspel, K. P. Schick

01 Mar 1986-Organometallics

TL;DR: Etude des intermediaires lors de la dimerisation et la telomerisation du butadiene catalysees par le palladium as mentioned in this paper, et al.

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Preparation and NMR studies of pentacoordinated silicon anions

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Robert Damrauer, Stephen E. Danahey

Organolanthanide and organoyttrium hydride chemistry. Part 8. Structure and reactivity studies of bis(cyclopentadienyl)ytterbium and yttrium alkyl complexes including the x-ray crystal structure of (C5H5)2Yb(CH3)(THF)

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William J. Evans, Raul. Dominguez, Timothy P. Hanusa

01 Feb 1986-Organometallics

Journal Article•DOI•

Dimeric (.eta.2-benzophenone)zirconocene: its remarkable structure and chemistry

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Gerhard Erker, Ulrich Dorf, Peter Czisch, Jeffrey L. Peterson

Organoboranes. 48. Improved procedures for the preparation of boronic and borinic esters

Journal Article•DOI•

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Herbert C. Brown, Morris Srebnik, Thomas E. Cole