Showing papers in "Polyhedron in 2013"

TL;DR: In this paper, the homoleptic cobalt(II) complexes [Co(EPh)4]2− (E, O, S, Se) were isolated as (Ph4P)2[Co(OPh4]·(CH3CN) (1), K(Ph 4P)[Co (OPh) 4] (2), Ph4P 2[Co (SPh 4]4] (3), and Ph 4P 2 [Co (SePh) 2] (4) from reactions of CoCl2 or CoI

TL;DR: In this article, a thalidomide-based dithiocarbamate ligand; 3-(1,3dioxoisoindolin-2-yl)-2,6-dioxopiperidine-1-carbodithioate was synthesized by the sodium hydroxide assisted reaction of thalidmide with carbon disulfide at 0-5°C.

TL;DR: In this paper, the impact of zero-dimensional compounds in the field of magnetic refrigeration was examined by an examination of 3D, 3d-4f and 4f molecular compounds and more recent polymeric materials.

TL;DR: The complex 3, which strongly binds to both DNA and protein and performs both DNA cleavage and protein cleavage, exhibits a higher cytotoxicity than the other complexes due to enhanced hydrophobicity of both pmdt and the diimine co-ligand.

TL;DR: In this paper, a combined theoretical and experimental study on the electronic structure and photoluminescence properties of β zinc molybdate (β-ZnMoO4) microcrystals synthesized by the hydrothermal method has been employed.

TL;DR: In this article, superparamagnetic iron oxide nanoparticles (SPIONs) have been successfully synthesized through a simple and facile hydrothermal reduction route using a single iron precursor (FeCl3·6H2O), and a combination of the inherent chemical reduction capability of maltose decomposition products (glucose as reducing sugar) and its acid (gluconic acid as a capping agent).

TL;DR: In this article, the preparation and isolation of 5,5′-bis(2-hydroxytrazole) by oxidation of 5 5′-bistetrazole using commercially available oxone is described.

TL;DR: In this paper, a family of electronically tuned fac-Re(CO)3Cl pyridyl-1,2,3-triazole complexes have been synthesized by refluxing methanol solutions of [Re( CO)5Cl] and the substituted 2-(1-R-1H-1 2,3,triazol-4-yl)pyridine ligands (pytri-R) were characterised by elemental analysis, HR-ESMS, IR, 1H and 13C NMR.

TL;DR: In this article, a model based on distortions of tetrahedral [MoO 4 ] clusters due to medium-range intrinsic defects and intermediary energy levels (deep and shallow holes) within the band gap was proposed to explain the stages involved for the formation of octahedron-like PbMoO4 crystals.

TL;DR: In this article, the salicylidene 2-picoloyl hydrazone ligand (H2sal-phz) was prepared by reaction of picoloyls hydrazine with Salicylaldehyde, and the new compounds were characterized by 1H NMR and IR spectroscopies.

TL;DR: The results envisaged herein indicate that Cu(TMCPMP-TS)(Phen) holds ample merit to develop it as a therapeutic agent against cancer.

TL;DR: A series of nano-sized Al-substituted manganese zinc ferrites, Mn0.8Zn0.2Fe2O3 xAlxO4 (x = 0.0� 1.0), with a cubic spinel crystal structure were prepared through the citrate sol-gel auto-combustion method.

TL;DR: In this paper, a single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit was synthesized using two different Schiff bases N,N/-bis(3-methoxysalicylidenimino)-1,3-diaminopropane (L1H2) and N, N/-bis (3-ethoxyaliclyideniminos)-1.3-diagrams (L2H2), respectively.

TL;DR: In this paper, the synthesis and characterization of the rhenium anions [Re(bpy-R)(CO)3]−1 (bpyR = 4,4′-disubstitued-2,2′-bipyridine; R = CF3, H, Me, tBu, OMe) were reported.

TL;DR: In this paper, the interaction of nickel(II) with the nonsteroidal anti-inflammatory drug sodium diclofenac (Nadicl) in the presence of the N,N′-donor heterocyclic ligands 2, 2′-dipyridylketone oxime (Hpko), 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) leads to the formation of mononuclear Ni(II)-complex.

TL;DR: In this article, a new complex of nickel(II) with 1-(2-[(5-methylfuran-2yl)methylene)] hydrazono) phthalazine HL (1) has been synthesized and characterized by elemental analysis, IR, electronic spectra, TGA, 1H and 13C NMR spectroscopy.

TL;DR: In this article, the authors used a tetra(4-N-pyridyl)porphyrinatomanganese(III) acetate, supported on silica coated magnetite nanoparticles, SiO2-Fe3O4, for efficient epoxidation of alkenes and hydroxylation of alkanes.

TL;DR: In this paper, a density functional analysis was performed on a dinuclear GdIII-GdIII complex and the authors derived magneto-structural correlations to relate the sign and strength of J to specific structural parameters.

TL;DR: In this article, the reactions of di-2-pyridyl ketone (dpk), 2-benzoylpyridine (zpy), and 2-hydroxybenzophenone (Hbp) with (Re(CO)5Cl) (A) and trans-(ReOX3(PPh3)2 )( B, X = Cl, Br) were studied.

TL;DR: A series of metal complexes with o-hydroxyacetophenone-2-thiophenoyl hydrazone (Hhath) have been synthesized and characterized with the help of elemental analyses, magnetic susceptibility measurements, electronic, IR, NMR and ESR spectral techniques as discussed by the authors.

TL;DR: In this article, five new compounds have been prepared by the reaction of MnCl2·4H2O with aroylhydrazone in the presence of NaN3.

TL;DR: In this paper, three dicobalt(II) complexes, namely [Co2(L1H)(H2O)2(OAc)2]-OAc2 (1), [Co 2(L2), H2O), OAc 2 (OAc 2 ), OAc 3 (2), and OAc 4 (3), have been synthesized and characterized by common physicochemical techniques, and in the case of complex 1 also by single crystal X-ray diffraction analysis.

TL;DR: In this paper, the phthalocyanine dyes have a free carboxyl group, facilitating the covalent attachment of the dyes on the silica surface via amide bond formation.

TL;DR: In this paper, the magneto-structural properties of seven novel compounds [Cu(pz)2(SCN)2]n (1, 3, 5, 6 and 7) have been synthesized and characterised structurally and spectroscopically by single X-ray analysis.

TL;DR: In this article, the authors discuss the contributions of organic chemistry to the interdisciplinary science of molecule-based magnetics, in reference to transition metal coordination chemistry carried out successfully by Olivier Kahn and other scientists.

TL;DR: In this article, Antiferro and ferromagnetic couplings were observed in [Gd(hfac) 3 (2pyNO)(H 2 O)] and Gd(gd-nitroxide complexes) 2, respectively, where 2pyNO stands for tert -butyl 2-pyridyl nitroxide and HNN for 4,4,5,5-tetramethylimidazolin-1-oxyl 3-oxide.

TL;DR: Three mono-nuclear copper(II) complexes were synthesized using a variety of tridentate amine ligands (mpipy, mpiq and bdmpzpy) as discussed by the authors.

TL;DR: A series of new bichelated complexes of the formula [M(L)2]H2O were synthesized from the reaction of N-[(2-benzylthio)-phenyl] salicylaldimine (HL), 1, a new tridentate (O, N, S donor) potential Schiff base with metal salts in methanol medium as discussed by the authors.

TL;DR: In this article, a new complex of Ni(II) with p-[ N, N -bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone (CEAB-4MTSC) have been synthesized and characterized by elemental analysis, IR, electronic, 1 H NMR spectroscopy.

TL;DR: In this article, the X-ray crystal structures of Ag2(9-aca) and Ag4(DMSO) complexes were determined for the fungus Candida albicans.