Showing papers in "Reports on Progress in Physics in 2005"

Smoothed particle hydrodynamics

Abstract: In this review the theory and application of Smoothed particle hydrodynamics (SPH) since its inception in 1977 are discussed. Emphasis is placed on the strengths and weaknesses, the analogy with particle dynamics and the numerous areas where SPH has been successfully applied.

Recent developments in magnetocaloric materials

Abstract: The recent literature concerning the magnetocaloric effect (MCE) has been reviewed. The MCE properties have been compiled and correlations have been made comparing the behaviours of the different families of magnetic materials which exhibit large or unusual MCE values. These families include: the lanthanide (R) Laves phases (RM2, where M = Al, Co and Ni), Gd5(Si1−xGex)4 ,M n(As1−xSbx), MnFe(P1−xAsx), La(Fe13−xSix) and their hydrides and the manganites (R1−xMxMnO3, where R = lanthanide and M = Ca, Sr and Ba). The potential for use of these materials in magnetic refrigeration is discussed, including a comparison with Gd as a near room temperature active magnetic regenerator material. (Some figures in this article are in colour only in the electronic version)

Non-sticking drops

Abstract: While the behaviour of large amounts of liquid is dictated by gravity, surface forces become dominant at small scales. They have for example the remarkable ability to make droplets stick to their substrates (even if they are inclined), which is a practical issue in many cases (windshields, window panes, greenhouses, or microfluidic devices). Here we describe how this problem can be overcome with super-hydrophobic materials. These materials are often developed thanks to micro-textures, which decorate a solid surface, and we describe the way such textures modify the wettability of that solid. We conclude by showing the unusual dynamics of drops in a super-hydrophobic situation.

Boundary slip in Newtonian liquids: a review of experimental studies

Abstract: For several centuries fluid dynamics studies have relied upon the assumption that when a liquid flows over a solid surface, the liquid molecules adjacent to the solid are stationary relative to the solid. This no-slip boundary condition (BC) has been applied successfully to model many macroscopic experiments, but has no microscopic justification. In recent years there has been an increased interest in determining the appropriate BCs for the flow of Newtonian liquids in confined geometries, partly due to exciting developments in the fields of microfluidic and microelectromechanical devices and partly because new and more sophisticated measurement techniques are now available. An increasing number of research groups now dedicate great attention to the study of the flow of liquids at solid interfaces, and as a result a large number of experimental, computational and theoretical studies have appeared in the literature. We provide here a review of experimental studies regarding the phenomenon of slip of Newtonian liquids at solid interfaces. We dedicate particular attention to the effects that factors such as surface roughness, wettability and the presence of gaseous layers might have on the measured interfacial slip. We also discuss how future studies might improve our understanding of hydrodynamic BCs and enable us to actively control liquid slip.

Physics of negative refractive index materials

Abstract: In the past few years, new developments in structured electromagnetic materials have given rise to negative refractive index materials which have both negative dielectric permittivity and negative magnetic permeability in some frequency ranges. The idea of a negative refractive index opens up new conceptual frontiers in photonics. One much-debated example is the concept of a perfect lens that enables imaging with sub-wavelength image resolution. Here we review the fundamental concepts and ideas of negative refractive index materials. First we present the ideas of structured materials or meta-materials that enable the design of new materials with a negative dielectric permittivity, negative magnetic permeability and negative refractive index. We discuss how a variety of resonance phenomena can be utilized to obtain these materials in various frequency ranges over the electromagnetic spectrum. The choice of the wave-vector in negative refractive index materials and the issues of dispersion, causality and energy transport are analysed. Various issues of wave propagation including nonlinear effects and surface modes in negative refractive materials (NRMs) are discussed. In the latter part of the review, we discuss the concept of a perfect lens consisting of a slab of a NRM. This perfect lens can image the far-field radiative components as well as the nearfield evanescent components, and is not subject to the traditional diffraction limit. Different aspects of this lens such as the surface modes acting as the mechanism for the imaging of the evanescent waves, the limitations imposed by dissipation and dispersion in the negative refractive media, the generalization of this lens to optically complementary media and the possibility of magnification of the near-field images are discussed. Recent experimental developments verifying these ideas are briefly covered. (Some figures in this article are in colour only in the electronic version)

HgCdTe infrared detector material: history, status and outlook

Abstract: This article reviews the history, the present status and possible future developments of HgCdTe ternary alloy for infrared (IR) detector applications. HgCdTe IR detectors have been intensively developed since the first synthesis of this material in 1958. This article summarizes the fundamental properties of this versatile narrow gap semiconductor, and relates the material properties to its successful applications as an IR photoconductive and photovoltaic detector material. An emphasis is put on key developments in the crystal growth and their influence on device evolution. Competitive technologies to HgCdTe ternary alloy are also presented. Recent advances of backside illuminated HgCdTe heterojunction photodiodes have enabled a third generation of multispectral instruments for remote sensing applications and have led to the practicality of multiband IR focal plane array technology. Finally, evaluation of HgCdTe for room temperature long wavelength IR applications is presented. (Some figures in this article are in colour only in the electronic version)

Single-photon sources

Abstract: The concept of the photon, central to Einstein's explanation of the photoelectric effect, is exactly 100 years old. Yet, while photons have been detected individually for more than 50 years, devices producing individual photons on demand have only appeared in the last few years. New concepts for single-photon sources, or 'photon guns', have originated from recent progress in the optical detection, characterization and manipulation of single quantum objects. Single emitters usually deliver photons one at a time. This so-called antibunching of emitted photons can arise from various mechanisms, but ensures that the probability of obtaining two or more photons at the same time remains negligible. We briefly recall basic concepts in quantum optics and discuss potential applications of single-photon states to optical processing of quantum information: cryptography, computing and communication. A photon gun's properties are significantly improved by coupling it to a resonant cavity mode, either in the Purcell or strong-coupling regimes. We briefly recall early production of single photons with atomic beams, and the operation principles of macroscopic parametric sources, which are used in an overwhelming majority of quantum-optical experiments. We then review the photophysical and spectroscopic properties and compare the advantages and weaknesses of various single nanometre-scale objects used as single-photon sources: atoms or ions in the gas phase and, in condensed matter, organic molecules, defect centres, semiconductor nanocrystals and heterostructures. As new generations of sources are developed, coupling to cavities and nano-fabrication techniques lead to improved characteristics, delivery rates and spectral ranges. Judging from the brisk pace of recent progress, we expect single photons to soon proceed from demonstrations to applications and to bring with them the first practical uses of quantum information.

Supercooled dynamics of glass-forming liquids and polymers under hydrostatic pressure

Abstract: An intriguing problem in condensed matter physics is understanding the glass transition, in particular the dynamics in the equilibrium liquid close to vitrification Recent advances have been made by using hydrostatic pressure as an experimental variable These results are reviewed, with an emphasis in the insight provided into the mechanisms underlying the relaxation properties of glass-forming liquids and polymers

Microrheology of complex fluids

Abstract: The field of microrheology is concerned with how materials store and dissipate mechanical energy as a function of length scale. Recent developments in the theory and instrumentation of the microrheology of complex fluids are reviewed. Equal emphasis is given to the physical phenomena probed, advances in instrumentation, and specific experimental systems in which this field has already had an impact. The inversion of the compliance data, measurement of sample heterogeneity, high frequency viscoelasticity, effects of shear flow, single molecule experiments, surface viscoelasticity and time evolution studies are considered. The techniques highlighted include particle tracking microrheology, diffusing wave spectroscopy, laser tracking, magnetic tweezers and atomic force microscopy. Specific examples of complex fluid systems are chosen from the fields of polymers, colloids and biological assemblies.

The physics of snow crystals

Abstract: We examine the physical mechanisms governing the formation of snow crystals, treating this problem as a case study of the dynamics of crystal growth from the vapour phase. Particular attention is given to the basic theoretical underpinnings of the subject, especially the interplay of particle diffusion, heat diffusion and surface attachment kinetics during crystal growth, as well as growth instabilities that have important effects on snow crystal development. The first part of this review focuses on understanding the dramatic variations seen in snow crystal morphology as a function of temperature, a mystery that has remained largely unsolved since its discovery 75 years ago. To this end we examine the growth of simple hexagonal ice prisms in considerable detail, comparing crystal growth theory with laboratory measurements of growth rates under a broad range of conditions. This turns out to be a surprisingly rich problem, which ultimately originates from the unusual molecular structure of the ice surface and its sensitive dependence on temperature. With new clues from precision measurements of attachment kinetics, we are now just beginning to understand these structural changes at the ice surface and how they affect the crystal growth process. We also touch upon the mostly unexplored topic of how dilute chemical impurities can greatly alter the growth of snow crystals. The second part of this review examines pattern formation in snow crystals, with special emphasis on the growth of snow crystal dendrites. Again we treat this as a case study of the more general problem of dendritic growth during diffusion-limited solidification. Since snow crystals grow from the vapour, we can apply dendrite theory in the simplified slowgrowth limit where attachment kinetics dominates over capillarity in selecting the tip velocity. Although faceting is quite pronounced in these structures, many aspects of the formation of snow crystal dendrites are fairly well described using a theoretical treatment that does not explicitly incorporate faceting. We also describe electrically modified ice dendrite growth, which produces some novel needle-like structures.

The Casimir force: background, experiments, and applications

Abstract: The Casimir force, which is the attraction of two uncharged material bodies due to modification of the zero-point energy associated with the electromagnetic modes in the space between them, has been measured with per cent-level accuracy in a number of recent experiments. A review of the theory of the Casimir force and its corrections for real materials and finite temperature are presented in this report. Applications of the theory to a number of practical problems are discussed.

Jovian atmospheric dynamics: An update after Galileo and Cassini

Abstract: The Galileo and Cassini spacecrafts have greatly enhanced the observational record of Jupiter's tropospheric dynamics, particularly through returning high spatial resolution, multi-spectral and global imaging data with episodic coverage over periods of months to years. These data, along with those from Earth-based telescopes, have revealed the stability of Jupiter's zonal jets, captured the evolution of vortices and equatorial waves, and mapped the distributions of lightning and moist convection. Because no observations of Jupiter's interior exist, a forward modelling approach has been used to relate observations at cloud level to models of shallow or deep jet structure, shallow or deep jet forcing and energy transfer between turbulence, vortices and jets. A range of observed phenomena can be reproduced in shallow models, though the Galileo probe winds and jet stability arguments hint at the presence of deep jets. Many deep models, however, fail to reproduce Jupiter-like non-zonal features (e.g. vortices). Jupiter's dynamics likely include both deep and shallow processes, requiring an integrated approach to future modelling—an important goal for the post-Galileo and Cassini era.

Reflection anisotropy spectroscopy

Abstract: Reflection anisotropy spectroscopy (RAS) is a non-destructive optical probe of surfaces that is capable of operation within a wide range of environments. In this review we trace the development of RAS from its origins in the 1980s as a probe of semiconductor surfaces and semiconductor growth through to the present where it is emerging as a powerful addition to the wide range of existing ultra-high vacuum (UHV) surface science techniques. The principles, instrumentation and theoretical considerations of RAS are discussed. The recent progress in the application of RAS to investigate phenomena at metal surfaces is reviewed, and applications in fields including electrochemistry, molecular assembly, liquid crystal device fabrication and remote stress sensing are discussed. We show that the experimental study of relatively simple surfaces combined with continuing progress in the theoretical description of surface optics promises to unlock the full potential of RAS. This provides a firm foundation for the application of the technique to the challenging fields of ambient, high pressure and liquid environments. It is in these environments that RAS has a clear advantage over UHV-based probes for investigating surface phenomena, and its surface sensitivity, ability to monitor macroscopic areas and rapidity of response make it an ideal complement to scanning probe techniques which can also operate in such environments.

Radiotherapy with beams of carbon ions

Abstract: In cancer treatment, the introduction of MeV bremsstrahlung photons has been instrumental in delivering higher doses to deep-seated tumours, while reducing the doses absorbed by the surrounding healthy tissues. Beams of protons and carbon ions have a much more favourable dose-depth distribution than photons (called ‘x-rays’ by medical doctors) and are the new frontiers of cancer radiation therapy. Section 2 presents the status of the first form of hadrontherapy which uses beams of 200–250 MeV protons. The central part of this review is devoted to the discussion of the physical, radiobiological and clinical bases of the use of 400 MeV u −1 carbon ions in the treatment of radio-resistant tumours. These resist irradiation with photon as well as proton beams. The following section describes the carbon ion facilities that are either running or under construction. Finally, the projects recently approved or proposed are reviewed here. (Some figures in this article are in colour only in the electronic version)

The mass of the photon

Abstract: Because classical Maxwellian electromagnetism has been one of the cornerstones of physics during the past century, experimental tests of its foundations are always of considerable interest. Within that context, one of the most important efforts of this type has historically been the search for a rest mass of the photon. The effects of a nonzero photon rest mass can be incorporated into electromagnetism straightforwardly through the Proca equations, which are the simplest relativistic generalization of Maxwell's equations. Using them, it is possible to consider some far-reaching implications of a massive photon, such as variation of the speed of light, deviations in the behaviour of static electromagnetic fields, longitudinal electromagnetic radiation and even questions of gravitational deflection. All of these have been studied carefully using a number of different approaches over the past several decades. This review attempts to assess the status of our current knowledge and understanding of the photon rest mass, with particular emphasis on a discussion of the various experimental methods that have been used to set upper limits on it. All such tests can be most easily categorized in terms of terrestrial and extra-terrestrial approaches, and the review classifies them as such. Up to now, there has been no conclusive evidence of a finite mass for the photon, with the results instead yielding ever more stringent upper bounds on the size of it, thus confirming the related aspects of Maxwellian electromagnetism with concomitant precision. Of course, failure to find a finite photon mass in any one experiment or class of experiments is not proof that it is identically zero and, even as the experimental limits move more closely towards the fundamental bounds of measurement uncertainty, new conceptual approaches to the task continue to appear. The intrinsic importance of the question and the lure of what might be revealed by attaining the next decimal place are as strong a draw on this question as they are in any other aspect of precise tests of physical laws.

Ultrasound techniques for characterizing colloidal dispersions

Abstract: Interest in the interaction of acoustic waves with particulate mixtures has a long history—dating back to the work of Rayleigh in the 19th century. This interest has intensified over the last fifteen years as advances in electronics and instrumentation science have brought the possibility of using ultrasound to characterize colloidal mixtures both in the laboratory and in-process, and in both of these contexts a small number of instruments are currently in use. The characterization of colloidal mixtures by ultrasound requires a formal theoretical basis which relates the properties of the mixture, particularly the dispersed phase particle size distribution (PSD), to the complex wavenumber governing propagation. The number of theoretical treatments is vast, having evolved over more than a century. This paper is intended to provide a review of these developments in a form which will enable new researchers in the field to climb a very steep learning curve in a relatively short time. We discuss definitions and production techniques for colloidal mixtures and the basic physical phenomena underlying wave propagation through them. We identify two approaches to the propagation problem—scattering and coupled-phase; these are treated both separately and comparatively, particularly in relation to limitations that arise when the concentration of particles is high and the basic theories break down. We introduce the basic method for the measurement of PSD and show how dynamic effects such as flocculation and crystallization can be observed and modelled. The core of all ultrasonic characterization procedures is the physical measurement of the ultrasonic wave attenuation coefficient and phase velocity as functions of frequency; here we discuss these techniques on the basis that what is observable or measurable about a colloid depends on both its physical properties and the frequency bandwidth available for measurement. This paper concludes with our view on future developments of measurement technique and theoretical treatments.

Near fields in nanostructures

Abstract: Recent progress in near-field optics instrumentation has led to a new class of subwavelength optical experiments in which near-field optical microscopes are used to image precisely the electromagnetic field distributions inside nanostructures microfabricated at the surface of dielectric wafers (microwaveguides, optical splitters, whispering-gallery modes, three-dimensional photonic crystals, metal nanoparticle gratings, plasmon waveguides, etc). In the light of these new advances, we review the physics of near-field optics in the presence of nanostructured materials (the so-called nano-optics). After the introductory part, revealing the main theoretical schemes and computation techniques well-suited for nano-optics, we will focus on several typical examples of calculations extracted from the recent literature. We will begin this series by revisiting the challenging problem of the optical addressing of both passive or active nanostructures in a subwavelength area. In this context, various procedures for the optimization of the energy transfer efficiency inside addressed nanostructures will be detailed. Finally, the concept of photonic local density of states in near-field optics will be revisited.

Sum-frequency generation spectroscopy of interfaces

Abstract: This paper reviews aspects of nonlinear optical spectroscopy of interfaces. The emphasis is put on second-order nonlinear optical techniques, such as sum-frequency generation (SFG), which possess intrinsic surface or interface selectivity and can therefore be used to probe buried interfaces accessible by light. The basic concepts of the second-order nonlinear response of surfaces and interfaces are given. While SFG in the ultraviolet–visible range allows one to achieve surface-specific electronic spectroscopy, infrared–visible SFG spectroscopy allows one to have access to absolute vibrational spectra of adsorbates at an interface. The main experimental schemes commonly employed are described. Selected experimental examples are given for studies of liquid surfaces and interfaces, polymer surfaces and interfaces, solid surfaces under ultra-high vacuum conditions or in inert atmospheres, solid–gas interfaces, solid–liquid interfaces and solid–solid interfaces. Both frequency-resolved studies and time-domain measurements are addressed.

Computer simulation of liquid crystals

Abstract: A review is presented of molecular and mesoscopic computer simulations of liquid crystalline systems. Molecular simulation approaches applied to such systems are described, and the key findings for bulk phase behaviour are reported. Following this, recently developed lattice Boltzmann approaches to the mesoscale modelling of nemato-dynamics are reviewed. This paper concludes with a discussion of possible areas for future development in this field.

Fluctuation microscopy: a probe of medium range order

Abstract: Fluctuation microscopy is a hybrid diffraction-imaging technique that detects medium range order in amorphous materials by examining spatial fluctuations in coherent scattering. These fluctuations appear as speckle in images and diffraction patterns. The volume of material contributing to the speckle is determined by the point-spread function (the resolution) of the imaging optics and the sample thickness. The spatial periodicities being probed are related to the diffraction vector. Statistical analysis of the speckle allows the random and non-random (ordered) contributions to be discriminated. The image resolution that gives the maximum speckle contrast, as determined by the normalized variance of the image intensity, is determined by the characteristic length scale of the ordering. Because medium range ordering length scales can extend out to about the tenth coordination shell, fluctuation microscopy tends to be a low image resolution technique.This review presents the kinematical scattering theory underpinning fluctuation microscopy and a description of fluctuation electron microscopy as it has been employed in the transmission electron microscope for studying amorphous materials. Recent results using soft x-rays for studying nanoscale materials are also presented. We summarize outstanding issues and point to possible future directions for fluctuation microscopy as a technique.

Modulation of photonic structures by surface acoustic waves

Abstract: This paper reviews the interaction between coherently stimulated acoustic phonons in the form of surface acoustic waves with light beams in semiconductor based photonic structures We address the generation of surface acoustic wave modes in these structures as well as the technological aspects related to control of the propagation and spatial distribution of the acoustic fields The microscopic mechanisms responsible for the interaction between light and surface acoustic modes in different structures are then reviewed Particular emphasis is given to the acousto-optical interaction in semiconductor microcavities and its application in photon control These structures exhibit high optical modulation levels under acoustic excitation and are compatible with integrated light sources and detectors

Non-linear dynamics of semiconductor superlattices

Abstract: In the last decade, non-linear dynamical transport in semiconductor superlattices (SLs) has witnessed significant progress in theoretical descriptions as well as in experimentally observed non-linear phenomena. However, until now, a clear distinction between non-linear transport in strongly and weakly coupled SLs was missing, although it is necessary to provide a detailed description of the observed phenomena. In this review, strongly coupled SLs are described by spatially continuous equations and display self-sustained current oscillations due to the periodic motion of a charge dipole as in the Gunn effect for bulk semiconductors. In contrast, weakly coupled SLs have to be described by spatially discrete equations. Therefore, weakly coupled SLs exhibit a more complex dynamical behaviour than strongly coupled ones, which includes the formation of stationary electric field domains, pinning or propagation of domain walls consisting of a charge monopole, switching between stationary domains, self-sustained current oscillations due to the recycling motion of a charge monopole and chaos. This review summarizes the existing theories and the experimentally observed non-linear phenomena for both types of semiconductor SLs.

Nucleic acid nanostructures: Bottom-up control of geometry on the nanoscale

Abstract: DNA may seem an unlikely molecule from which to build nanostructures, but this is not correct. The specificity of interaction that enables DNA to function so successfully as genetic material also enables its use as a smart molecule for construction on the nanoscale. The key to using DNA for this purpose is the design of stable branched molecules, which expand its ability to interact specifically with other nucleic acid molecules. The same interactions used by genetic engineers can be used to make cohesive interactions with other DNA molecules that lead to a variety of new species. Branched DNA molecules are easy to design, and they can assume a variety of structural motifs. These can be used for purposes both of specific construction, such as polyhedra, and for the assembly of topological targets. A variety of two-dimensional periodic arrays with specific patterns have been made. DNA nanomechanical devices have been built with a series of different triggers, small molecules, nucleic acid molecules and proteins. Recently, progress has been made in self-replication of DNA nanoconstructs, and in the scaffolding of other species into DNA arrangements.

Quark-model study of few-baryon systems

Abstract: We review the application of non-relativistic constituent quark models to study one, two and three non-strange baryon systems. We present results for the baryon spectra, potentials and observables of the nucleon?nucleon (NN), N?, ?? and NN*(1440) systems, and binding energies of three non-strange baryon systems. We emphasize the observable effects related to quark antisymmetry and its interplay with quark dynamics.

Disorder-driven non-Fermi liquid behaviour of correlated electrons

Abstract: Systematic deviations from standard Fermi-liquid behaviour have been widely observed and documented in several classes of strongly correlated metals. For many of these systems, mounting evidence is emerging that the anomalous behaviour is most likely triggered by the interplay of quenched disorder and strong electronic correlations. In this review, we present a broad overview of such disorder-driven non-Fermi liquid behaviour, and discuss various examples where the anomalies have been studied in detail. We describe both their phenomenological aspects as observed in experiment, and the current theoretical scenarios that attempt to unravel their microscopic origin.

Surface structure determination using x-ray standing waves

Abstract: The technique of x-ray standing waves as a means of structure determination is reviewed with special emphasis on its application to the investigation of adsorbed atoms and molecules at well-characterized single crystal surfaces in ultra-high vacuum. Topics covered include: the physical principles of the method and the underlying theory; methods of detection of the x-ray absorption and their relative merits; the specific advantages of photoelectron detection together with a description of the modified method of data analysis and its underlying physical basis (required to account for non-dipolar angular effects in the photoemission process); some practical issues of data analysis and interpretation including recent developments in the use of structural 'imaging' by direct inversion of the measured structural parameters. A broad survey of applications is included covering atomic and molecular adsorbates on semiconductors and metals as well as the use of the technique to obtain site-specific electronic structure information. Some comments on likely future developments and applications are given.

High pressure equations of state and planetary interiors

Abstract: Developments in the theory of strong compression of solids in the last decade, especially some results based on thermodynamic principles, have not yet been digested by the geophysics and high pressure physics communities. They are reviewed here with emphasis on analytical representations that readily accommodate the thermodynamic constraints. Molecular dynamics calculations, made possible by large, fast computers, offer an alternative approach that can handle complex crystal structures and may reveal effects missed by analytical methods but can give unsatisfactory values of properties that depend on high derivatives of the potential functions and, like many of the analytical equations, have difficulty with thermodynamic constraints. Both analytical and numerical methods are simpler in the classical, high temperature regime, well above the Debye temperature, and for most purposes this is a reasonable approximation in applications to planetary interiors. Seismological observations yield data for equation of state studies that are far more reliable than laboratory data at pressures exceeding about 30 GPa and can be used to calibrate laboratory pressure scales. Equations developed for the Earth's mantle and core are applied to the other terrestrial planets and the Moon, yielding estimates of the radii of their metallic cores and deep interior densities and compositions.

Physical limits of silicon transistors and circuits

Abstract: A discussion on transistors and electronic computing including some history introduces semiconductor devices and the motivation for miniaturization of transistors. The changing physics of field-effect transistors and ways to mitigate the deterioration in performance caused by the changes follows. The limits of transistors are tied to the requirements of the chips that carry them and the difficulties of fabricating very small structures. Some concluding remarks about transistors and limits are presented.

Weak links in high critical temperature superconductors

Abstract: The traditional distinction between tunnel and highly transmissive barriers does not currently hold for high critical temperature superconducting Josephson junctions, both because of complicated materials issues and the intrinsic properties of high temperature superconductors (HTS). An intermediate regime, typical of both artificial superconductor–barrier–superconductor structures and of grain boundaries, spans several orders of magnitude in the critical current density and specific resistivity. The physics taking place at HTS surfaces and interfaces is rich, primarily because of phenomena associated with d-wave order parameter (OP) symmetry. These phenomena include Andreev bound states, the presence of the second harmonic in the critical current versus phase relation, a doubly degenerate state, time reversal symmetry breaking and the possible presence of an imaginary component of the OP. All these effects are regulated by a series of transport mechanisms, whose rules of interplay and relative activation are unknown. Some transport mechanisms probably have common roots, which are not completely clear and possibly related to the intrinsic nature of high-TC superconductivity. The d-wave OP symmetry gives unique properties to HTS weak links, which do not have any analogy with systems based on other superconductors. Even if the HTS structures are not optimal, compared with low critical temperature superconductor Josephson junctions, the state of the art allows the realization of weak links with unexpectedly high quality quantum properties, which open interesting perspectives for the future. The observation of macroscopic quantum tunnelling and the qubit proposals represent significant achievements in this direction. In this review we attempt to encompass all the above aspects, attached to a solid experimental basis of junction concepts and basic properties, along with a flexible phenomenological background, which collects ideas on the Josephson effect in the presence of d-wave pairing for different types of barriers.

Electron tunnelling in self-assembled monolayers

Abstract: A review on the mechanisms and characterization methods of electronic transport through self-assembled monolayers (SAMs) is presented. Using SAMs of alkanethiols in a nanometre scale device structure, tunnelling is unambiguously demonstrated as the main intrinsic conduction mechanism for defect-free large bandgap SAMs, exhibiting well-known temperature and length dependences. Inelastic electron tunnelling spectroscopy exhibits clear vibrational modes of the molecules in the device, presenting direct evidence of the presence of molecules in the device.