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Showing papers in "Reviews of Geophysics in 1994"


Journal ArticleDOI
TL;DR: In this article, a new parameterization of oceanic boundary layer mixing is developed to accommodate some of this physics, including a scheme for determining the boundary layer depth h, where the turbulent contribution to the vertical shear of a bulk Richardson number is parameterized.
Abstract: If model parameterizations of unresolved physics, such as the variety of upper ocean mixing processes, are to hold over the large range of time and space scales of importance to climate, they must be strongly physically based. Observations, theories, and models of oceanic vertical mixing are surveyed. Two distinct regimes are identified: ocean mixing in the boundary layer near the surface under a variety of surface forcing conditions (stabilizing, destabilizing, and wind driven), and mixing in the ocean interior due to internal waves, shear instability, and double diffusion (arising from the different molecular diffusion rates of heat and salt). Mixing schemes commonly applied to the upper ocean are shown not to contain some potentially important boundary layer physics. Therefore a new parameterization of oceanic boundary layer mixing is developed to accommodate some of this physics. It includes a scheme for determining the boundary layer depth h, where the turbulent contribution to the vertical shear of a bulk Richardson number is parameterized. Expressions for diffusivity and nonlocal transport throughout the boundary layer are given. The diffusivity is formulated to agree with similarity theory of turbulence in the surface layer and is subject to the conditions that both it and its vertical gradient match the interior values at h. This nonlocal “K profile parameterization” (KPP) is then verified and compared to alternatives, including its atmospheric counterparts. Its most important feature is shown to be the capability of the boundary layer to penetrate well into a stable thermocline in both convective and wind-driven situations. The diffusivities of the aforementioned three interior mixing processes are modeled as constants, functions of a gradient Richardson number (a measure of the relative importance of stratification to destabilizing shear), and functions of the double-diffusion density ratio, Rρ. Oceanic simulations of convective penetration, wind deepening, and diurnal cycling are used to determine appropriate values for various model parameters as weak functions of vertical resolution. Annual cycle simulations at ocean weather station Papa for 1961 and 1969–1974 are used to test the complete suite of parameterizations. Model and observed temperatures at all depths are shown to agree very well into September, after which systematic advective cooling in the ocean produces expected differences. It is argued that this cooling and a steady salt advection into the model are needed to balance the net annual surface heating and freshwater input. With these advections, good multiyear simulations of temperature and salinity can be achieved. These results and KPP simulations of the diurnal cycle at the Long-Term Upper Ocean Study (LOTUS) site are compared with the results of other models. It is demonstrated that the KPP model exchanges properties between the mixed layer and thermocline in a manner consistent with observations, and at least as well or better than alternatives.

3,756 citations


Journal ArticleDOI
TL;DR: In this article, the authors compile all known in situ LIPs younger than 250 Ma and analyze dimensions, crustal structures, ages, and emplacement rates of representatives of the three major LIP categories: Ontong Java and Kerguelen-Broken Ridge oceanic plateaus, North Atlantic volcanic passive margins, and Deccan and Columbia River continental flood basalts Crustal thickness ranges from 20 to 40 km, and the lower crust is characterized by high (70-76 km s?1) compressional wave velocities.
Abstract: Large igneous provinces (LIPs) are a continuum of voluminous iron and magnesium rich rock emplacements which include continental flood basalts and associated intrusive rocks, volcanic passive margins, oceanic plateaus, submarine ridges, seamount groups, and ocean basin flood basalts Such provinces do not originate at “normal” seafloor spreading centers We compile all known in situ LIPs younger than 250 Ma and analyze dimensions, crustal structures, ages, and emplacement rates of representatives of the three major LIP categories: Ontong Java and Kerguelen-Broken Ridge oceanic plateaus, North Atlantic volcanic passive margins, and Deccan and Columbia River continental flood basalts Crustal thicknesses range from 20 to 40 km, and the lower crust is characterized by high (70-76 km s?1) compressional wave velocities Volumes and emplacement rates derived for the two giant oceanic plateaus, Ontong Java and Kerguelen, reveal short-lived pulses of increased global production; Ontong Java’s rate of emplacement may have exceeded the contemporaneous global production rate of the entire mid-ocean ridge system The major part of the North Atlantic volcanic province lies offshore and demonstrates that volcanic passive margins belong in the global LIP inventory Deep crustal intrusive companions to continental flood volcanism represent volumetrically significant contributions to the crust We envision a complex mantle circulation which must account for a variety of LIP sizes, the largest originating in the lower mantle and smaller ones developing in the upper mantle This circulation coexists with convection associated with plate tectonics, a complicated thermal structure, and at least four distinct geochemical/isotopic reservoirs LIPs episodically alter ocean basin, continental margin, and continental geometries and affect the chemistry and physics of the oceans and atmosphere with enormous potential environmental impact Despite the importance of LIPs in studies of mantle dynamics and global environment, scarce age and deep crustal data necessitate intensified efforts in seismic imaging and scientific drilling in a range of such features

1,367 citations


Journal ArticleDOI
TL;DR: The most important change in Cenozoic atmospheric circulation was a severalfold reduction in wind intensity that occurred at the time of the Paleocene-Eocene boundary as mentioned in this paper.
Abstract: The mineral component of pelagic sediment is brought to the deep sea by transport in the wind. Extraction and analysis of this dust allows estimation of the past aridity of the eolian source region, via flux determinations, and of the intensity of the transporting winds, from grain size data. These two parameters, the grain size and mass flux of dust, vary independently. There are three significant sources of modern dust, eastern and central Asia, northwest Africa, and Arabia, all in the northern hemisphere. As the rainfall associated with the Intertropical Convergence Zone is an effective barrier to southerly transport of dust, the northern hemisphere is an order of magnitude more “dusty” than is the southern, an asymmetry that has characterized most of the Cenozoic. Eolian flux data show that most of the northern hemisphere was more arid during glacial maxima, with 3 to 5 times as much dust transported during glacial stages than during interglacials; only northwestern South America varied in the opposite sense. The periodicity of Quaternary variation in both eolian flux and eolian grain size data is strongly influenced by the Milankovitch cycles of orbital variability. Wind intensities vary on a shorter time scale than the general 100-kyr cycles of glaciation and general aridity. Eolian grain sizes display forcing at precessional (19 and 23 kyr), tilt (41 kyr), and at approximately 30 kyr periodicities. As a result the generalization that winds are uniformly stronger during glacial times is not valid. Whole-Cenozoic records show that the largest change in dust flux, an order of magnitude increase, occurred in the northern hemisphere and reflects continental drying associated with the late Pliocene onset of northern hemisphere glaciation. Southern hemisphere eolian records show no sign of paleoclimatic changes in the late Pliocene. The most important change in Cenozoic atmospheric circulation was a severalfold reduction in wind intensity that occurred at the time of the Paleocene-Eocene boundary. Before then, latest Cretaceous and Paleocene winds were essentially as strong as those of the late Cenozoic. This shift appears to be one of several climatic responses to a change in the nature and amount of global heat transport at about 55 Ma.

856 citations


Journal ArticleDOI
TL;DR: In this article, a theoretical treatment of the ascent, emplacement, and eruption of magma on Mars is presented, showing that the lower gravity, fluid convective motions and crystal settling processes driven by positive and negative buoyancy forces, as well as overall diapiric ascent rates, will be slower on Mars than on Earth, permitting larger diapirs to ascend to shallower depths.
Abstract: We present a theoretical treatment of the ascent, emplacement, and eruption of magma on Mars. Because of the lower gravity, fluid convective motions and crystal settling processes driven by positive and negative buoyancy forces, as well as overall diapiric ascent rates, will be slower on Mars than on Earth, permitting larger diapirs to ascend to shallower depths. Martian environmental conditions operate to modulate the various eruption styles and the morphology and morphometry of resulting landforms, providing new insight into several volcanological problems.

336 citations


Journal ArticleDOI
TL;DR: In this paper, passive particles and their transport across (not necessarily off) continental shelves during high stands of sea level are investigated. But the authors focus on the portion of the water column closest to the seabed, where physical processes are effective where and when they influence the bottom boundary layer.
Abstract: Transport of participate material across continental shelves is well demonstrated by the distributions on the seabed and in the water column of geological, chemical, or biological components, whose sources are found farther landward or farther seaward. This paper addresses passive (incapable of swimming) particles and their transport across (not necessarily off) continental shelves during high stands of sea level. Among the general factors that influence across-shelf transport are shelf geometry, latitudinal constraints, and the timescale of interest. Research studies have investigated the physical mechanisms of transport and have made quantitative estimates of mass flux across continental shelves. Important mechanisms include wind-driven flows, internal waves, wave-orbital flows, infragravity phenomena, buoyant plumes, and surf zone processes. Most particulate transport occurs in the portion of the water column closest to the seabed. Therefore physical processes are effective where and when they influence the bottom boundary layer, causing shear stresses sufficient to erode and transport particulate material. Biological and geological processes at the seabed play important roles within the boundary layer. The coupling of hydrodynamic forces from currents and surface gravity waves has a particularly strong influence on across-shelf transport; during storm events, the combined effect can transport particles tens of kilometers seaward. Several important mechanisms can cause bidirectional (seaward and landward) transport, and estimates of the net flux are difficult to obtain. Also, measurements of across-shelf transport are made difficult by the dominance of along-shelf transport. Geological parameters are often the best indicators of net across-shelf transport integrated over time scales longer than a month. For example, fluvially discharged particles with distinct composition commonly accumulate in the midshelf region. Across-shelf transport of particulate material has important implications for basic and applied oceanographic research (e.g., dispersal of planktonic larvae and particle-reactive pollutants). Continued research is needed to understand the salient mechanisms and to monitor them over a range of timescales.

325 citations


Journal ArticleDOI
TL;DR: The role of water in the evolution of planetary atmospheres is discussed in this article, where models of ocean and atmospheric and oceanic data and models of the coupled system are used to perform systematic analyses of hydrological processes and their role in system interaction.
Abstract: Earth is unique among the planets of the solar system in possessing a full hydrological cycle. The role of water in the evolution of planetary atmospheres is discussed. As the atmospheres of the planets developed and modified the early climates of the planets, only the climate trajectory of Earth intercepted the water phase transitions near the triplet point of water, thus allowing the full gamut of water forms to coexist. As a result, transitions between the water phases pervade the entire system and probably are responsible for the creation of a unique climate state. The interactions between the components of the climate system are enriched by the nonlinearity of the water phase transitions. The nonlinear character of the phase transitions of water suggests that the climate should be particularly sensitive to hydrological processes, especially in the tropics. Signatures of the nonlinearity are found in both the structures of the oceans and the atmosphere. Models of the ocean and atmospheric and oceanic data and models of the coupled system are used to perform systematic analyses of hydrological processes and their role in system interaction. The analysis is extended to consider the role of hydrological processes in the basic dynamics and thermodynamicsmore » of oceanic and atmospheric systems. The role hydrological processes play in determining the scale of the major atmospheric circulation patterns is investigated. Explanations are offered as to why large-scale convection in the tropical atmosphere is constrained to lie within the 28{degrees}C sea surface temperature contour and how hydrological processes are involved in interannual climate variability. The relative roles of thermal and haline forcing of the oceanic thermohaline circulation are discussed. Hydrological processes are considered in a global context by the development of a conceptual model of a simple planetary system. 94 refs., 38 figs., 5 tabs.« less

294 citations


Journal ArticleDOI
TL;DR: In this article, the authors focus on the development of data assimilation techniques to incorporate radar and satellite observations to address the implications of modeling a multiscale problem at restricted spatial and temporal resolutions.
Abstract: Local orography governs the triggering of cloud formation and the enhancement of processes such as condensation and hydrometeor nucleation and growth in mountainous regions. Intense, lengthy precipitation events are typical upwind of the topographic divide, with sharply decreasing magnitude and duration on the lee side. Differences in mean annual precipitation of several hundred percent between windward slopes of orographic barriers and adjacent valleys or lee side slopes are not unusual. Because much of the streamflow in areas such as the western United States is derived from mountainous areas that are remote and often poorly instrumented, modeling of orographic precipitation has important implications for water resources management. Models of orographically induced precipitation differ by their treatment of atmospheric dynamics and by the extent to which they rely on bulk parameterization of cloud and precipitation physics. Adiabatic ascent and a direct proportionality between efficiency and orographically magnified updrafts are the most frequent assumptions in orographic precipitation modeling. Space-time discretization (i.e., resolution) is a major issue because of the high spatial variability of orographic precipitation. For a specific storm, relative errors as large as 50 to 100% are common in the forecast/hindcast of precipitation intensity and can be even larger in the case of catastrophic storms. When monthly or seasonal timescales are used to evaluate model performance, the magnitude of such errors decreases dramatically, reaching values as low as 10 to 15%. Current research is focusing on the development of data assimilation techniques to incorporate radar and satellite observations, and on the development of aggregation and disaggregation methodologies to address the implications of modeling a multiscale problem at restricted spatial and temporal resolutions.

216 citations


Journal ArticleDOI
TL;DR: A review of the major aspects associated with the transport of reactive contaminants in heterogeneous subsurface environments can be found in this paper, followed by a discussion of the results obtained from some of the few well-controlled field experiments designed to investigate transport of the reactive contaminants.
Abstract: The potential for human activities to adversely affect the environment has become of increasing concern during the past two decades. Concomitantly, the transport and fate of contaminants in subsurface systems has become one of the major research areas in the environmental, hydrological, and Earth sciences. An understanding of how contaminants move in the subsurface is needed to evaluate the probability of contaminants associated with a chemical spill reaching an aquifer and contaminating groundwater. This knowledge is also required to develop and evaluate methods for cleaning up contaminated soils and aquifers. Just as importantly, knowledge of contaminant transport and fate is necessary to design “pollution prevention” strategies. A tremendous body of literature on contaminant transport has been generated in response to these needs. This literature consists primarily of results obtained by theoretical, experimental, and mathematical modeling based investigations and, to a much lesser extent, field experiments. This paper consists of a brief review of some of the major aspects associated with the transport of reactive contaminants in heterogeneous subsurface environments. It begins with a review of basic concepts related to contaminant transport, followed by a discussion of the results obtained from some of the few well-controlled field experiments designed to investigate transport of reactive contaminants in the subsurface. Some of the major factors controlling contaminant transport will then be discussed, followed by a review of conceptual and mathematical approaches used to represent those factors in mathematical models. A brief overview of future needs and opportunities in contaminant transport will close the discussion.

151 citations


Journal ArticleDOI
TL;DR: In this paper, a simple flow pattern with two upgoing and two downgoing large-scale flows can be invoked to simply explain the predominance of degrees 2 and 6 for seismic velocity and degree 4 for radial anisotropy.
Abstract: The understanding of mantle convection is one of the most puzzling problems of modern geophysics. Among the different approaches used by geophysicists to investigate mantle convection, seismic tomography is the only one able to visualize, at the same time, temperature, petrological anomalies, and flow directions from seismic velocity and anisotropy heterogeneities. In order to enable a comparison with other geophysical observables, tomographic models are expanded into spherical harmonics. Most tomographic models agree that down to 300–400 km, deep structure is closely related to plate tectonics and continental distribution. Its corresponding spectral content regularly decreases with decreasing wavelength. At greater depths in the transition zone, degree 2 and (to a lesser extent) degree 6 distributions become predominant. A degree 2 pattern is also present in the lower mantle and is strongly correlated with the geoid but offset with respect to the degree 2 pattern of the transition zone. A simple flow pattern with two upgoing and two downgoing large-scale flows can be invoked to simply explain the predominance of degrees 2 and 6 for seismic velocity and degree 4 for radial anisotropy. Therefore below the apparent complexity of plate tectonics, it turns out that mantle convection is surprisingly simply organized in the transition zone. Between 400 and 1000 km, these large-scale flows are not independent from the circulation in the first 400 km but are connected to some of the most tectonically active zones (fast ridges and slabs). It is also suggested that the degree 6 which seems to be a marker of the hotspot distribution is not independent of the deep degree 2 but might be the consequence of this simple flow pattern. The good correlation between seismic tomography degree 6 and hotspot degree 6 favors an origin at depth of hotspots in the transition zone. Generally, the mantle cannot be divided into independent convecting cells but is characterized by imbricated convection, where different scales coexist and where exchange of matter is possible. Therefore seismic tomography is able to provide very strong constraints on possible models of mantle convection, but many features are still unexplained. Only very long spatial wavelengths are well resolved so far, and a complete understanding of mantle dynamics necessitates relating the different scales present in convective processes.

140 citations


Journal ArticleDOI
TL;DR: Parkfield has experienced six moderate earthquakes since 1857 at average intervals of 22 years, the most recent a magnitude 6 event in 1966 as discussed by the authors, but studies assigning it a 95% chance of occurring before 1993 now appear to have been over-simplified The identification of Parkfield fault segments was initially based on geometric features in the surface trace of the San Andreas fault, but more recent microearthquake studies have demonstrated that those features do not extend to seismogenic depths.
Abstract: Since 1985, a focused earthquake prediction experiment has been in progress along the San Andreas fault near the town of Parkfield in central California Parkfield has experienced six moderate earthquakes since 1857 at average intervals of 22 years, the most recent a magnitude 6 event in 1966 The probability of another moderate earthquake soon appears high, but studies assigning it a 95% chance of occurring before 1993 now appear to have been over-simplified The identification of a Parkfield fault “segment” was initially based on geometric features in the surface trace of the San Andreas fault, but more recent microearthquake studies have demonstrated that those features do not extend to seismogenic depths On the other hand, geodetic measurements are consistent with the existence of a “locked” patch on the fault beneath Parkfield that has presently accumulated a slip deficit equal to the slip in the 1966 earthquake A magnitude 47 earthquake in October 1992 brought the Parkfield experiment to its highest level of alert, with a 72-hour public warning that there was a 37% chance of a magnitude 6 event However, this warning proved to be a false alarm Most data collected at Parkfield indicate that strain is accumulating at a constant rate on this part of the San Andreas fault, but some interesting departures from this behavior have been recorded Here we outline the scientific arguments bearing on when the next Parkfield earthquake is likely to occur and summarize geophysical observations to date

91 citations


Journal ArticleDOI
TL;DR: In this paper, a simple theory is proposed relating changes in the core field to apparent transition paths measured at the Earth's surface, and if substantiated, the result would provide the first definitive evidence of long-term mantle control of the geomagnetic field.
Abstract: Geomagnetic polarity reversal remains one of Nature's most enigmatic phenomena. Dynamo theory admits solutions in pairs with reversed magnetic fields B and −B, but detailed calculations are required to understand how the field can change sign. Theory also admits separate solutions with different symmetry across the equatorial plane, the symmetric (ES) “quadrupole” and the antisymmetric (EA) “dipole” solutions, which may be important in the reversal process and which offer a simple framework for interpreting small paleomagnetic data sets. Ordinary secular variation leads to very large changes in the magnetic field over several centuries and could easily develop into full reversal; the theory of secular variation, which is relatively well developed, may therefore help in understanding reversals. Other clues to geomagnetic reversals come from the Sun, whose magnetic field reverses every 11 years. Paleomagnetic data show the Earth’s magnetic field reverses every million years or so, with each transition taking about a thousand years, during which the intensity may fall by as much as 1 order of magnitude. Reversal frequency undergoes a modulation on the long timescale (107 years) of mantle convection, and there have been two long intervals in the past with no reversals. Such behavior is typical of a highly nonlinear dynamical system, but the very long timescale of changes in reversal frequency, and its close proximity to the overturn time of mantle convection, suggests some control of the dynamo by the mantle. Short-term phenomena, such as change in the length of day and secular variation, have been studied extensively for evidence of core-mantle interactions, and we may draw on this body of evidence in order to understand long-term effects. Three physical mechanisms have been proposed: topographic, electromagnetic, and thermal, with the last two being most significant for long-term effects. Symmetries allow the dynamo to generate an EA field, with the major component a dipole, but lateral variations on the core-mantle boundary may lead to magnetic fields with no symmetry, reflecting the structure of the boundary anomalies. Changes in reversal frequency on the mantle convection timescale could arise either from changes in total heat flux from the core to the mantle or from instabilities associated with lateral variations at the core-mantle boundary. Neither mechanism is well understood, but the former involves significant changes to the Earth's overall heat budget, whereas the latter must always arise as a natural consequence of deep-mantle convection. Recent measurements of transition fields show pole paths that lie close to two preferred longitudes near 90°W and 90°E; if substantiated, the result would provide the first definitive evidence of long-term mantle control of the geomagnetic field. Further evidence suggests that the geomagnetic pole during stable polarity also lies along these two longitudes and that magnetic flux at the core surface tends to concentrate along the same longitudes, as does the present field. A simple theory is proposed relating changes in the core field to apparent transition paths measured at the Earth's surface. The model shows that longitude confinement of the transition paths can occur for quite complicated core fields and that surface intensities can drop by 1 order of magnitude, on average, simply because of the reduction in length scale of the transitional field. Simple transition paths may be an indication of some organization of flux at the core surface but not of large-scale or small-amplitude core fields.

Journal ArticleDOI
TL;DR: For example, the Earth's mantle is much less differentiated chemically compared to the mantle of the Moon and perhaps Mars as mentioned in this paper, which may explain the relatively undifferentiated nature of the Earth mantle.
Abstract: Compared to the mantles of the Moon and perhaps Mars, the Earth's mantle is much less differentiated chemically. Both the Moon and Mars appear to have undergone a major differentiation accompanying planet formation. The only clear signature of a similar event on the Earth is core formation. While this might imply that the Earth did not experience extensive melting and differentiation during planet formation, the higher pressures and temperatures present in the Earth could have led to a distinctly different chemical evolution for this initial differentiation. The most significant potential outcome of early differentiation on the Earth's mantle is formation of chemically distinct upper and lower mantles distinguished by Mg/Si higher and lower than chondritic, respectively. Plate tectonics on Earth provides a continuing mechanism for planet differentiation that forms crust at the expense of chemical differentiation of the mantle. Plate tectonics, however, also offers a mechanism to return the chemically distinct materials of the crust back into the mantle. Mixing of subducted crustal material into the mantle through the stirring provided by mantle convection can serve to negate the effects of crust formation on the chemical composition of the mantle. Similarly, mixing within the mantle could serve to destroy evidence of early differentiation, if such differentiation occurred on Earth. Completely efficient operation of the plate tectonic cycle would result in remixing of crust and differentiated mantle, with the end result being a homogenous mantle with composition identical to that of the bulk earth minus the materials segregated into the core. In part, this may explain the relatively undifferentiated nature of the Earth's mantle. Plate tectonics has not been completely efficient on Earth, however. Both oceanic and continental crust exist, and there is widespread evidence for chemical variability in the mantle. At least four chemically and isotopically distinct components are observed in mantle-derived rocks. The nature of these components points to the importance of crust formation and recycling in determining the chemical variability of the mantle. Mapping of the surface expression of chemical heterogeneity in the mantle is providing new views of the chemical structure of the mantle and the geodynamic processes that operate in the Earth's interior.

Journal ArticleDOI
TL;DR: In this paper, the authors interpreted seismic reflection data, coupled with a variety of ancillary geological and geophysical data, to provide images of fault zones that tend to form moderately dipping ramp structures in mechanically rigid layers, and flat detachments in mechanically weak layers.
Abstract: The continental lithosphere responds to stress by deforming as a generally layered medium Deep seismic reflection data, coupled with a variety of ancillary geological and geophysical data, are interpreted to provide images of fault zones that tend to form moderately dipping ramp structures in mechanically rigid layers, and flat detachments in mechanically weak layers This geometry is similar to ramp and flat structures observed at smaller scales in thrust and fold belts and leads to the interpretation that most orogens are underlain by orogen-scale decollements in a manner that is analogous to so-called “thin skin” deformation in sedimentary rocks Decollements may occur within the crust (for example, near the base of a sedimentary section or in the middle crust), near the Moho, in the subcrustal lithosphere, or in the asthenosphere Even intracratonic basement-cored (“thick skin”) uplifts that occasionally occur in foreland regions such as the Wyoming province are probably large (crustal) scale versions of ramp/flat features observed in supracrustal rocks and are thus likely caused by the same fundamental tectonic processes

Journal ArticleDOI
TL;DR: In this article, the authors presented a best estimate of the mantle noble gas state using mantle derived materials such as mid-ocean ridge basalt (MORB), hotspot volcanics, diamonds, and mantle xenoliths.
Abstract: Noble gas elemental and isotopic data on mantle-derived materials such as mid-ocean ridge basalt (MORB), hotspot volcanics, diamonds, and mantle xenoliths published up to August 1993 are reviewed critically. Characteristic features of the mantle-derived materials, which are important in evaluating the significance of the data, are discussed. We choose MORB glasses, hotspot volcanics, mantle xenoliths, and diamonds as the sources to infer the noble gas state in the mantle: MORB and hotspot volcanics to represent the modern depleted and the less degassed mantle, and diamonds to represent the ancient mantle. Because of various fractionation processes, the elemental abundance data obtained from the mantle-derived materials is unlikely to constrain the noble gas composition of the mantle, except for the systematic enrichment of the heavier noble gases relative to air. On the other hand, apart from the secondary addition of radiogenic components such as 4He, 21Ne, 40Ar, 129Xe, and 131–136Xe, the noble gas isotopic compositions deduced from the mantle-derived materials can provide useful information as to the values in the mantle; a best estimate of the mantle noble gas state is presented.

Journal ArticleDOI
TL;DR: A general overview of magnetospheric modeling is given in this article along with a more detailed discussion of several empirical models which are widely used, including the Mead-Fairfield, Olsen-Pfitzer tilt-dependent, Tsyganenko-Usamo and Hilmer-Voight models.
Abstract: A general overview of magnetospheric modeling is given, along with a more detailed discussion of several empirical models which are widely used. These models are composed of representations of the Earth's main internal field (basically a bipolar field), plus external field contributions due to ring currents (carried by the particles in the Van Allen radiation belts), magnetopause currents (the boundary surface between the Earth's magnetic field and interplanetary magnetic field carried by the solar wind), and tail currents (carried by particles in the neutral sheet of the magnetotail). The empirical models presented here are the Mead-Fairfield, Olsen-Pfitzer tilt-dependent (1977), Tsyganenko-Usamo, Tsyganenko (1987), Olsen-Pfitzer dynamic (1988), Tsyganenko (1989), and Hilmer-Voight models. The derivations, agreement with quiet time and storm time data from the two satellite programs, Spacecraft Charging at High Altitudes (SCATHA) and Combined Release Radiation Effects Satellite (CRRES), and computational requirements of these models are compared.

Journal ArticleDOI
TL;DR: Secondary ion mass spectrometers (SIMS) have been applied to a wide variety of surface analytical problems and can be used to analyze reacted glass and mineral surfaces which have been exposed to weathering solutions as discussed by the authors.
Abstract: Secondary ion mass spectrometry (SIMS) is the mass spectrometry of atomic species which are emitted when a solid surface is bombarded by an energetic primary ion beam. By continually bombard- ing the surface of the sample with the ion beam, the atoms making up the material being studied are sput- tered away. The secondary ions emitted from the sur- face are continually analyzed and their intensities re- corded over time. The secondary ion intensities are proportional to the concentration of elements in the sample, thereby producing a semiquantitative concen- tration depth profile. The depth profile provides an illustration of the chemical composition of a sample as a function of depth through the surface. The SIMS technique has been applied to a wide variety of surface analytical problems and can easily be used to analyze reacted glass and mineral surfaces which have been exposed to weathering solutions. Traditional experi- mental studies of chemical weathering were based primarily on the analyses of aqueous solutions gener- ated during leaching experiments. Such studies have provided valuable information concerning rates and stoichiometry of mineral dissolution reactions but have led to some confusion and much speculation regarding the mechanisms of surface processes. SIMS analyses of the surfaces of dissolving glasses and pla- gioclase feldspars have recently been used to help resolve a number of unanswered questions. For exam- ple, SIMS analyses of dissolving feldspars have shown how the chemical composition of reacted surfaces and depth of attack vary, depending on the composition of the mineral, the p H of the leaching solution, and the presence of dissolved salts and complex-forming or- ganic ligands.