Rheologica Acta 

Abstract: Emulsions of incompressible viscoelastic materials are considered, in which the addition of an interfacial agent causes the interfacial tension to depend on shear deformation and variation of area. The average complex shear modulus of the medium accounts for the mechanical interactions between inclusions by a self consistent treatment similar to the Lorentz sphere method in electricity. The resulting expression of the average modulus includes as special cases the Kerner formula for incompressible elastic materials and the Oldroyd expression of the complex viscosity of emulsions of Newtonian liquids in time-dependent flow.

Abstract: Viscoelastic instabilities are of practical importance, and are the subject of growing interest. Reviewed here are the fresh developments as well as earlier work in this area, organized into the following categories: instabilities in Taylor-Couette flows, instabilities in cone-and-plate and plate-and-plate flows, instabilities in parallel shear flows, extrudate distortions and fracture, instabilities in shear flows with interfaces, instabilities in extensional flows, instabilities in multidimensional flows, and thermohydrodynamic instabilities. Emphasized in the review are comparisons between theory and experiment and suggested directions for future work.

Abstract: We obtain the linear viscoelastic shear moduli of complex fluids from the time-dependent mean square displacement, , of thermally-driven colloidal spheres suspended in the fluid using a generalized Stokes–Einstein (GSE) equation. Different representations of the GSE equation can be used to obtain the viscoelastic spectrum, G˜(s), in the Laplace frequency domain, the complex shear modulus, G*(ω), in the Fourier frequency domain, and the stress relaxation modulus, Gr(t), in the time domain. Because trapezoid integration (s domain) or the Fast Fourier Transform (ω domain) of known only over a finite temporal interval can lead to errors which result in unphysical behavior of the moduli near the frequency extremes, we estimate the transforms algebraically by describing as a local power law. If the logarithmic slope of can be accurately determined, these estimates generally perform well at the frequency extremes.

Abstract: New experimental data obtained from constant stress rheometers are used to show that the yield stress concept is an idealization, and that, given accurate measurements, no yield stress exists. The simple Cross model is shown to be a useful empiricism for many non-Newtonian fluids, including those which have hitherto been thought to possess a yield stress.

Abstract: The linear viscoelastic and viscometric functions have been determined for solutions of wellcharacterized monodisperse linear and star-branched polystyrenes and for commercial, polydisperse polystyrene. The value of the product c\(\bar M_w \) for these solutions was large and was obtained by using both high and low\(\bar M_w \)